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arXiv 1906.09441cond-mat.mtrl-sci
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BiFeO3-TbMnO3复合材料的能带结构、输运和磁性研究

Study of Band structure, Transport and magnetic properties of BiFeO3-TbMnO3 composite

Prince Kr. Gupta, Surajit Ghosh, Arkadeb Pal, Somnath Roy, Amish G Joshi, A. K. Ghosh, Sandip Chatterjee

摘要:

研究了由BiFeO_3和TbMnO_3组成的两种类型的多铁性(I型和II型)磁电多铁性复合材料的磁性能和输运性能。从BiFeO 3和TbMnO 3的紫外-可见吸收光谱估计较窄的带隙。在带隙已知的情况下,利用价带X射线光电子能谱(XPS)和紫外光电子能谱(UPS)估算了其能带结构。价带和导带分别位于费米能级上下1.0eV和0.45eV处。因此,系统的绝缘行为可以从界面处的能带重构来理解,这是由于两种材料的晶格失配而发生的。大的矫顽力和磁化强度值的增加被理解为是由于不同Mn离子(Mn 2+、Mn 3+和Mn 4+)之间的超交换相互作用。从EDXA和芯能级X射线光电子能谱的组成研究发现,氧空位,这反过来又创造了锰的混合价态,以保持电荷中性。

英文摘要:

Magnetoelectric multiferroic composite of two types of multiferroic (Type I and II) consisting BiFeO3 and TbMnO3 is studied for enhanced magnetic and transport properties. A narrower band gap is estimated from the UV-visible absorption spectrum from that of BiFeO3 and TbMnO3. With known value of band gap, the band structure was estimated from the valence band x-ray photoemission spectra (XPS) and ultra violet photoemission spectra (UPS). The valence and conduction band was found at 1.0 eV and 0.45 eV above and below the Fermi level respectively. Thus the insulating behavior of the system is understood from the reconstruction of the energy bands at the interface which happens due to lattice mismatch of the two materials. The large coercivity and the increase on the magnetization value are understood to be due to superexchange interaction between different Mn ions (Mn2+, Mn3+ and Mn4+). From the composition study of EDXA and core level x-ray photoemission spectra oxygen vacancy was found which in turn creates the mixed valence state of Mn to maintain the charge neutrality.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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