Broadband near-infrared astronomical spectrometer calibration and on-sky validation with an electro-optic laser frequency comb
Ewelina Obrzud, Monica Rainer, Avet Harutyunyan, Bruno Chazelas, Massimo Cecconi, Adriano Ghedina, Emilio Molinari, Stefan Kundermann, Steve Lecomte, Francesco … 展开作者
Ewelina Obrzud, Monica Rainer, Avet Harutyunyan, Bruno Chazelas, Massimo Cecconi, Adriano Ghedina, Emilio Molinari, Stefan Kundermann, Steve Lecomte, Francesco Pepe, François Wildi, François Bouchy, Tobias Herr
The quest for extrasolar planets and their characterisation as well as studies of fundamental physics on cosmological scales rely on capabilities of high-resolution astronomical spectroscopy. A central requirement is a precise wavelength calibration of astronomical spectrographs allowing for extraction of subtle wavelength shifts from the spectra of stars and quasars. Here, we present an all-fibre, 400 nm wide near-infrared frequency comb based on electro-optic modulation with 14.5 GHz comb line spacing. Tests on the high-resolution, near-infrared spectrometer GIANO-B show a photon-noise limited calibration precision of <10 cm/s as required for Earth-like planet detection. Moreover, the presented comb provides detailed insight into particularities of the spectrograph such as detector inhomogeneities and differential spectrograph drifts. The system is validated in on-sky observations of a radial velocity standard star (HD221354) and telluric atmospheric absorption features. The advantages of the system include simplicity, robustness and turn-key operation, features that are valuable at the observation sites.
We performed extreme ultraviolet spectroscopy using an 80 lines/mm TEM mesh as dispersive element. We present the usefulness of this instrument for dispersing a high harmonic spectrum from the 13th to the 29th harmonic of a Ti:Sapph laser, corresponding to a wavelength range from 60 to 27 nm. The resolution of the instrument is limited by the image size of the high harmonic generation region on the detector. The best resolution in first order diffraction is under 2 nm over the entire spectral range.
We present a directly generated on-chip dual-comb source at THz frequencies. The multi-heterodyne beating signal of two free-running THz quantum cascade laser frequency combs is measured electrically using one of the combs as a detector, fully exploiting the unique characteristics of quantum cascade active regions. Up to 30 modes can be detected corresponding to a spectral bandwidth of 630 GHz, being the available bandwidth of the dual comb configuration. The multi-heterodyne signal is used to investigate the equidistance of the comb modes showing an accuracy of $10^{-12}$ at the carrier frequ…
We present a dual-comb spectrometer based on two passively mode-locked waveguide lasers integrated in a single Er-doped ZBLAN chip. This original design yields two free-running frequency combs having a high level of mutual stability. We developed in parallel a self-correction algorithm that compensates residual relative fluctuations and yields mode-resolved spectra without the help of any reference laser or control system. Fluctuations are extracted directly from the interferograms using the concept of ambiguity function, which leads to a significant simplification of the instrument that will …
Fourier transform spectroscopy based on incoherent light sources is a well-established tool in research fields from molecular spectroscopy and atmospheric monitoring to material science and biophysics. It provides broadband molecular spectra and information about the molecular structure and composition of absorptive media. However, the spectral resolution is fundamentally limited by the maximum delay range (Δ$_{max}$) of the interferometer, so acquisition of high-resolution spectra implies long measurement times and large instrument size. We overcome this limit by combining the Fourier transfo…
We demonstrate the use of dual-comb spectroscopy for isotope ratio measurements. We show that the analysis spectral range of a free-running near-infrared dual-comb spectrometer can be extended to the mid-infrared by difference frequency generation to target specific spectral regions suitable for such measurements, and especially the relative isotopic ratio $δ{}^{13}$C. The measurements performed present a very good repeatability over several days with a standard deviation below 2$\unicode{x2030}$ for a recording time of a few tens of seconds, and the results are compatible with measurements ob…
Robust, frequency-stable and accurate mid-IR laser spectrometer based on frequency comb metrology of quantum cascade lasers up-converted in orientation-patterned GaAs
The resolution function of a spectrometer based on a strongly bent single crystal (bending radius of 10 cm or less) is evaluated. It is shown that the resolution is controlled by two parameters, (i) the ratio of the lattice spacing of the chosen reflection to the crystal thickness and (ii) a single parameter comprising crystal thickness, its bending radius, and anisotropic elastic constants of the chosen crystal. Diamond, due to its unique elastic properties, can provide notably higher resolution than silicon. The results allow to optimize the parameters of bent crystal spectrometers for the h…
Dual Comb Spectroscopy proved its versatile capabilities in molecular fingerprinting in different spectral regions, but not yet in the ultraviolet (UV). Unlocking this spectral window would expand fingerprinting to the electronic energy structure of matter.This will access the prime triggers of photo-chemical reactions with unprecedented spectral resolution. In this research article, we discuss the milestones marking the way to the first UV dual comb spectrometer. We present experimental and simulated studies towards UV dual comb spectroscopy, directly applied to planned absorption measurement…
As a potent greenhouse gas and ozone depleting agent, nitrous oxide (N$_2$O) plays a critical role in the global climate. Effective mitigation relies on understanding global sources and sinks which can be supported through isotopic analysis. We present a cross-dispersed spectrometer, coupled with a mid-infrared frequency comb, capable of simultaneously monitoring all singly substituted, stable isotopic variants of N$_2$O. Rigorous evaluation of the instrument lineshape function and data treatment are discussed. Laboratory characterization of the spectrometer demonstrates sub-GHz spectral resol…
Four-wave-mixing-based quantum cascade laser frequency combs (QCL-FC) are a powerful photonic tool, driving a recent revolution in major molecular fingerprint regions, i.e. mid- and far-infrared domains. Their compact and frequency-agile design, together with their high optical power and spectral purity, promise to deliver an all-in-one source for the most challenging spectroscopic applications. Here, we demonstrate a metrological-grade hybrid dual comb spectrometer, combining the advantages of a THz QCL-FC with the accuracy and absolute frequency referencing provided by a free-standing, optic…
Dual comb spectroscopy (DCS) is a broadband technique offering high resolution and fast data acquisition. We describe a hybrid dual comb spectrometer comprising a broadband commercial fiber laser system offering a wide range of sample interrogation, and an actively mode locked semiconductor laser (MLL) having a widely tunable, relatively narrow spectrum. The mutual coherence over 100 seconds has been realized between the two combs. We employed the DCS system to characterize the absorption spectrum of rubidium atoms at 313 K with a high signal to noise ratio. The broadband laser is directly loc…
Dual-frequency comb spectroscopy has emerged as a disruptive technique for measuring wide-spanning spectra with high resolution, yielding a particularly powerful technique for sensitive multi-component gas analysis. We present a spectrometer system based on dual electro-optical combs with subsequent conversion to the mid-infrared via tunable difference frequency generation, operating in the range from 3 to 4.7 $μ$m. The simultaneously recorded bandwidth is up to 454(1) GHz and a signal-to-noise ratio of 7.3(2) x 10$^2$ Hz$^{-1/2}$ can be reached. The conversion preserves the coherence of the d…
We have developed a dispersive spectrometer using a compact immersion grating for direct frequency comb spectroscopy in the long-wave infrared region of 8-10 μm. A frequency resolution of 463 MHz is achieved, which is the highest reported in this wavelength region with a dispersive direct frequency comb spectrometer. We also demonstrate individual mode-resolved imaging of the frequency comb spectrum by Vernier cavity filtering and apply this to obtain both simple and complex molecular spectra. These results indicate that the immersion grating spectrometer offers the next advancement for sensit…
Fully stabilized 25 GHz frequency comb for frequency calibration of optical spectrum analyzer
Korea Research Institute of Standards and Science (KRISS)（韩国计量科学研究院）；University of Science and Technology (UST)（韩国科学技术院）；Chungnam National University（忠南国立大学）；Chung-Ang University（中央大学）
We present design and realization of an ultra-broadband optical spectrometer capable of measuring the spectral intensity of multi-octave-spanning light sources on a single-pulse basis with a dynamic range of up to 8 orders of magnitude. The instrument is optimized for the characterization of the temporal structure of femtosecond long electron bunches by analyzing the emitted coherent transition radiation (CTR) spectra. The spectrometer operates within the spectral range of 250nm to 11.35$μ$m, corresponding to 5.5 optical octaves. This is achieved by dividing the signal beam into three spectral…
We demonstrate the performance of a dual frequency comb QCL spectrometer for the application of vibrational Stark spectroscopy. Measurements performed on fluorobenzene with the dual-comb spectrometer (DCS) were compared to results obtained using a conventional Fourier transform infrared (FTIR) instrument in terms of spectral response, parameter estimation, and signal-to-noise ratio. The dual-comb spectrometer provided similar qualitative and quantitative data as the FTIR setup in 250 times shorter acquisition time. For fluorobenzene, the DCS measurement resulted in a more precise estimation of…
Dual comb spectroscopy (DCS) is a powerful technique for broadband spectroscopy with high precision and fast data acquisition. High-frequency resolution requires long data acquisition times, limiting the temporal resolution in time-resolved measurements. Here we overcome this limitation by engineering the DCS pulse train that interacts with the sample. The measurement is performed in steps where the number of pulses interacting with the sample varies in each step. The DCS spectrum is recorded in each stage, and a multi-dimensional spectrum is generated from which the system time evolution is d…
In the current study, a quantum-cascade-laser-based dual-comb spectrometer (DCS) was used to paint a detailed picture of a 1.0 ms high-temperature reaction between propyne and oxygen. The DCS interfaced with a shock tube to provide pre-ignition conditions of 1225 K, 2.8 atm, and 2% p-C3H4/18% O2/Ar. The spectrometer consisted of two free-running, non-stabilized frequency combs each emitting at 179 wavelengths between 1174 and 1233 cm-1. A free spectral range, f_r, of 9.86 GHz and a difference in comb spacing, Δf_r, of 5 MHz, enabled a theoretical time resolution of 0.2 us but the data was time…
Compact spectrometers based on disordered planar waveguides exhibit a rather high resolution with a relatively small footprint as compared to conventional spectrometers. This is achieved by multiple scattering of light which - if properly engineered - significantly enhances the effective optical path length. Here a design study of random spectrometers for TE- and TM-polarized light is presented that combines the results of Mie theory, multiple-scattering theory and full electromagnetic simulations. It is shown that the performance of such random spectrometers depends on single scattering quant…
The optical design of a novel spectrometer is present, combining a cylindrically convex pre-mirror with a cylindrically concave VLS grating (both in meridional) to deliver a resolving power of 100,000-200,000 in 'water window' (2-5nm). More remarkably, unlike a typical RIXS spectrometer to obtain such high resolution by tight focusing or tiny confinement slit (<1μm), here the resolution could be achieved for an effective meridional source size of 50μm (r.m.s.). The overall optical aberrations of the system are well analysed and compensated, providing an excellent flat field at the detector dom…
The impact of photodetector nonlinearity on dual-comb spectrometers is described and compared to that of Michelson-based Fourier transform spectrometers (FTS). The optical sampling occurring in the dual-comb approach, being the key difference with FTS, causes optical aliasing of the nonlinear spectral artifacts. Measured linear and nonlinear interferograms are presented to validate the model. Absorption lines of H$^{13}$CN are provided to understand the impact of nonlinearity on spectroscopic measurements.
Fast (sub-second) spectroscopy with high spectral resolution is of vital importance for revealing quantum chemistry kinetics of complex chemical and biological reactions. Fourier transform (FT) spectrometers can achieve high spectral resolution and operate at hundreds of ms time scales in rapid-scan mode. However, the linear translation of a scanning mirror imposes stringent time-resolution limitations to these systems, which makes simultaneous high spectral and temporal resolution impossible. Here, we demonstrate an FT spectrometer whose operational principle is based on continuous rotational…
