The present paper seeks to determine the mechanism of flame acceleration and transition to detonation when a turbulent flame preceded by a shock interacts with a single obstruction in its path, taken as a cylindrical obstacle or a wall in the present study. The problem is addressed experimentally in a mixture of propane-oxygen at sub-atmospheric conditions. The turbulent flame was generated by passing a detonation wave through a perforated plate, yielding flames with turbulent burning velocities 10 to 20 larger than the laminar values and incident shock Mach numbers ranging between 2 and 2.5. Time resolved schlieren videos recorded at approximately 100 kHz and numerical reconstruction of the flow field permitted to determine the mechanism of flame acceleration and transition to detonation. It was found to be the enhancement of the turbulent burning rate of the flame through its interaction with the shock reflection on the obstacle. The amplification of the burning rate was found to drive the flame burning velocity close to the speed of sound with respect to the fresh gases, resulting in the amplification of a shock in front of the flame. The acceleration through this regime resulted in the strengthening of this shock. Detonation was observed in regions of non-planarity of this internal shock, inherited by the irregular shape of the turbulent flame itself. Auto-ignition at early times of this process was found to be negligibly slow compared with the flow evolution time scale in the problem investigated, suggesting that the relevant time scale is primarily associated with the increase in turbulent burning rate by the interaction with reflected shocks.
The problem of deflagration-to-detonation transition in an unconfined environment is revisited. With a freely expanding self-accelerating hydrogen-oxygen flame as an example, it is shown that deflagration-to-detonation transition is indeed possible provided the flame is large enough. The transition occurs prior to merging of the flame with the flame-supported precursor shock. The pre-transition flame does not reach the threshold of CJ-deflagration. Numerical simulations employed are based on the recently developed pseudo-spectral method with time and space adaptation.
The effect of gas compression at the developed stages of flame acceleration in smooth-wall and obstructed channels is studied. We demonstrate analytically that gas compression moderates the acceleration rate and perform numerical simulations within the problem of flame transition to detonation. It is shown that flame acceleration undergoes three distinctive stages: 1) initial exponential acceleration in the incompressible regime, 2) moderation of the acceleration process due to gas compression, so that the exponential acceleration state goes over to a much slower one, 3) eventual saturation to…
In this study we examine influence of the radiation heat transfer on the combustion regimes in the mixture, formed by suspension of fine inert particles in hydrogen gas. The gaseous phase is assumed to be transparent for the thermal radiation, while the radiant heat absorbed by the particles is then lost by conduction to the surrounding gas. The particles and gas ahead of the flame is assumed to be heated by radiation from the original flame. It is shown that the maximum temperature increase due to the radiation preheating becomes larger for a flame with lower velocity. For a flame with small …
One of the most important and difficult parts of constructing a multidimensional numerical simulation of flame acceleration and deflagration-to-detonation transition (DDT) in a reacting flow is finding a reliable and affordable model of the chemical and diffusive properties. For simulations of realistic scenarios, full detailed chemical models are computationally prohibitive. In addition, they are usually inaccurate for high-temperature and high-pressure shock-laden flows. This paper presents a general approach for developing an automated procedure to determine the reaction parameters for a si…
The current work examines regimes of the hydrogen-oxygen flame propagation and ignition of mixtures heated by radiation emitted from the flame. The gaseous phase is assumed to be transparent for the radiation, while the suspended particles of the dust cloud ahead of the flame absorb and reemit the radiation. The radiant heat absorbed by the particles is then lost by conduction to the surrounding unreacted gaseous phase so that the gas phase temperature lags that of the particles. The direct numerical simulations solve the full system of two phase gas dynamic time-dependent equations with a det…
Multidimensional numerical simulations of a homogeneous, chemically reactive gas were used to study ignition, flame stability, and deflagration-to-detonation transition (DDT) in a supersonic combustor. The configuration studied was a rectangular channel with a supersonic inflow of stoichiometric ethylene-oxygen and a transimissive outflow boundary. The calculation is initialized with a velocity in the computational domain equal to that of the inflow, which is held constant for the duration of the calculation. The compressible reactive Navier-Stokes equations were solved by a high-order numeric…
The role of viscous stress in heating of the fuel mixture in deflagration-to-detonation transition in tubes is studied both analytically and numerically. The analytical theory is developed in the limit of low Mach number; it determines temperature distribution ahead of an accelerating flame with maximum achieved at the walls. The heating effects of viscous stress and the compression wave become comparable at sufficiently high values of the Mach number. In the case of relatively large Mach number, viscous heating is investigated by direct numerical simulations. The simulations were performed on…
The paper is concerned with identification of the key mechanisms controlling deflagration-to-detonation transition in stellar medium. The issue of thermal runaway triggered by positive feedback between the advancing flame and the flame-driven precompression is discussed in the framework of a one-dimensional flame-folding model. The paper is an extension of the authors' previous study dealing with the non-stoichiometric fusion, $fuel \to products$, kinetics (Phys.Rev.E, 103(2021)) over physically more relevant, $fuel+fuel \to products$, kinetics. Despite this change the runaway effect endures. …
We study a flame propagating in the gaseous combustible mixture with suspended inert particles. The gas is assumed to be transparent for the radiation emitted by the combustion products, while particles absorb and re-emit the radiation. Thermal radiation heats the particles, which in turn transfer the heat to the surrounding gaseous mixture by means of heat conduction, so that the gas temperature lags that of the particles. We consider different scenarios depending on the spatial distribution of the particles, their size and the number density. In the case of uniform distribution of the partic…
The present study investigates the spatio-temporal variability in the dynamics of self-sustained supersonic reaction waves propagating through an excitable medium. The model is an extension of Fickett's detonation model with a state dependent energy addition term. Stable and pulsating supersonic waves are predicted. With increasing sensitivity of the reaction rate, the reaction wave transits from steady propagation to stable limit cycles and eventually to chaos through the classical Feigenbaum route. The physical pulsation mechanism is explained by the coherence between internal wave motion an…
Deflagration-to-detonation transition (DDT) can occur in environments ranging from experimental and industrial systems to astrophysical thermonuclear (type Ia) supernovae explosions. Substantial progress has been made in explaining the nature of DDT in confined systems with walls, internal obstacles, or pre-existing shocks. It remains unclear, however, whether DDT can occur in unconfined media. Here we use direct numerical simulations (DNS) to show that for high enough turbulent intensities unconfined, subsonic, premixed, turbulent flames are inherently unstable to DDT. The associated mechanis…
It was demonstrated recently in Bychkov et al., Phys. Rev. Lett. 101 (2008) 164501, that the physical mechanism of flame acceleration in channels with obstacles is qualitatively different from the classical Shelkin mechanism. The new mechanism is much stronger, and is independent of the Reynolds number. The present study provides details of the theory and numerical modeling of the flame acceleration. It is shown theoretically and computationally that flame acceleration progresses noticeably faster in the axisymmetric cylindrical geometry as compared to the planar one, and that the acceleration…
The Multiple Mapping Conditioning / Large Eddy Simulation (MMC-LES) approach is used to simulate a supersonic lifted hydrogen jet flame, which features shock-induced autoignition, shock-flame interaction, lifted flame stabilization, and finite-rate chemistry effects. The shocks and expansion waves, shock-reaction interactions and overall flame characteristics are accurately reproduced by the model. Predictions are compared with the detailed experimental data for the mean axial velocity, mean and root-mean-square temperature, species mole fractions, and mixture fraction at various locations. Th…
Large Eddy Simulation with a Perfectly Stirred Reactor model (LES-PSR) is developed to simulate supersonic combustion with high-enthalpy flow conditions. The PSR model considers the viscous heating and compressibility effects on the thermo-chemical state, through correcting the chemical source term for progress variable and incorporating absolute enthalpy as the control variable for the look-up table. It is firstly validated by using a priori analysis of the viscous heating and compressibility effects. Then an auto-igniting hydrogen flame stabilized in supersonic vitiated co-flowing jet is sim…
The present work investigates the structure of fast supersonic turbulent flames typically observed as precursors to the onset of detonation. These high speed deflagrations are obtained after the interaction of a detonation wave with cylindrical obstacles. Two mixtures having the same propensity for local hot spot formation were considered, namely hydrogen-oxygen and methane-oxygen. It was shown that the methane mixture sustained turbulent fast flames, while the hydrogen mixture did not. Detailed high speed visualizations of nearly two-dimensional flow fields permitted to identify the key mecha…
In the current study, the influence of turbulent mixing and local reaction rates on deflagration to detonation transition (DDT) was investigated using a state-of-the-art large eddy simulation (LES) strategy. Specifically, detonation attenuation by a porous medium, and the subsequent re-initiation for methane-oxygen, a moderately unstable mixture, was considered. The purpose of the investigation was to validate the numerical strategy with previous experimental observations, and to determine what specific roles turbulent mixing and shock compression have on flame acceleration during the final st…
We show experimentally and numerically that when a weak shock interacts with a finger flame in a narrow channel, an extremely efficient mechanism for deflagration to detonation transition occurs. This is demonstrated in a 19-mm-thick channel in hydrogen-air mixtures at pressures below 0.2 atm and weak shocks of Mach numbers 1.5 to 2. The mechanism relies primarily on the straining of the flame shape into an elongated alligator flame maintained by the anchoring mechanism of Gamezo in a bifurcated lambda shock due to boundary layers. The mechanism can increase the flame surface area by more than…
This experimental study addresses the re-initiation mechanism of detonation waves following the Mach reflection of a shock-flame complex. The detonation diffraction around a cylinder is used to reproducibly generate the shock-flame complex of interest. The experiments are performed in methane-oxygen. We use a novel experimental technique of coupling a two-in-line-spark flash system with a double-frame camera in order to obtain microsecond time resolution permitting accurate schlieren velocimetry. The first series of experiments compares the non-reactive sequence of shock reflections with the r…
We study experimentally fast flames and their transition to detonation in mixtures of methane, ethane, ethylene, acetylene, and propane mixtures with oxygen. Following the interaction of a detonation wave with a column of cylinders of varying blockage ratio, the experiments demonstrate that the fast flames established are Chapman-Jouguet deflagrations, in excellent agreement with the self-similar model of Radulescu et al. (2015). The experiments indicate that these Chapman-Jouguet deflagrations dynamically restructure and amplify into fewer stronger modes until the eventual transition to deton…
In this fluid dynamic video we present simulations of converging two-dimensional detonation in a radially expanding supersonic flow of ideal reactive gas. The detonation is found to be unstable and leads to formation of characteristic cellular patterns. Without any obstacles in the flow, the detonation keeps expanding radially. To retain the wave within a bounded region, we place a number of rigid obstacles in the flow so that the detonation shock stands some distance toward the center from the obstacles. This leads to generation of reflected shock waves from the obstacles which help the deton…
This paper describes the numerical simulation of the NASA Langley Research Center supersonic H2 -Air combustion chamber performed using two approaches to model the presumed probability density function (PDF) in the flamelet progress variable (FPV) framework. The first one is a standard FPV model, built presuming the functional shape of the PDFs of the mixture fraction, Z, and of the progress parameter, Λ. In order to enhance the prediction capabilities of such a model in high-speed reacting flows, a second approach is proposed employing the statistically most likely distribution (SMLD) techcni…
The deflagration-to-detonation transition (DDT) process is of great importance to both combustion theory and industry safety. In this study, the propagating mechanism of Chapman-Jouguet (C-J) deflagration is studied. Firstly, three models are put forth to decouple the C-J detonation front. These three models are (a) to introduce an expansion parameter into the one-dimensional energy equation, (b) to increase the activation energy of the chemical reaction model and (c) to decouple the shock wave from the flame front by artificial method. The C-J deflagration is obtained after the C-J detonation…
The present study addresses the reaction zone structure and burning mechanism of unstable detonations. Experiments investigated mainly two-dimensional methane-oxygen cellular detonations in a thin channel geometry. The sufficiently high temporal resolution permitted to determine the PDF of the shock distribution, a power-law with an exponent of -3, and the burning rate of unreacted pockets from their edges - through surface turbulent flames with a speed approximately 3-7 times larger than the laminar one at the local conditions. Numerical simulations were performed using a novel Large Eddy Sim…
The nature of type Ia supernovae (SNIa) - thermonuclear explosions of white dwarf stars - is an open question in astrophysics. Virtually all existing theoretical models of normal, bright SNIa require the explosion to produce a detonation in order to consume all of stellar material, but the mechanism for the deflagration-to-detonation transition (DDT) remains unclear. We present a unified theory of turbulence-induced DDT that describes the mechanism and conditions for initiating detonation both in unconfined chemical and thermonuclear explosions. The model is validated using experiments with ch…
In this article effect of radiation preheating of unburnt mixture by propagating deflagration front is studied from the viewpoint of its ability to form a promoting temperature gradient and trigger transition to detonation. First, we investigate the effect of radiation preheating of the unburnt mixtures, when they are traveling through the wrinkles on the flame surface, in order to estimate a possibility of significant temperature rise. Subsequently, numerical simulations of a simplified mathematical model are carried out. They demonstrate plausibility of the proposed mechanism of the deflagra…
The present work examines the role of instability and diffusive phenomena in controlling the limits of detonations subject to lateral strain rates. Experiments were conducted in hydrocarbon-oxygen mixtures with varying levels of cellular instability. These detonations were propagated in channels with exponentially enlarging cross-sections, following the recent works of Radulescu \& Borzou (2018) and Xiao \& Radulescu (2020). Steady detonation waves were obtained at the macro-scale, with the near-limit reaction zone structures characterized by significant unreacted gas pockets. The turbulent fl…
Since detonation is the only established theory that allows rapid burning producing a high pressure that can be sustained in open areas, the generally accepted opinion was that the mechanism explaining the high rate of combustion in dust explosions is deflagration-to-detonation transition. We propose a theoretical substantiation of an alternative mechanism explaining the origin of the secondary explosion producing high speeds of combustion and high overpressures in unconfined dust explosions. We show that the clustering of dust particles in a turbulent flow ahead of the advancing flame gives r…
Shock flame interactions are fundamental problems in many combustion applications ranging from flame acceleration to flame control in supersonic propulsion applications. The present paper seeks to quantify the rate of deformation of the flame surface and burning velocity caused by the interaction and to clarify the underlying mechanisms. The interaction of a single shock wave with a cellular flame in a Hele-Shaw shock tube configuration was studied experimentally, numerically, and theoretically. A mixture of stoichiometric hydrogen-air at sub-atmospheric pressure was chosen such that large cel…
Detonation of a three-dimensional reactive non-isotropic molecular crystal is modeled using molecular dynamics simulations. The detonation process is initiated by an impulse, followed by the creation of a stable fast reactive shock wave. The terminal shock velocity is independent of the initiation conditions. Further analysis shows supersonic propagation decoupled from the dynamics of the decomposed material left behind the shock front. The dependence of the shock velocity on crystal nonlinear compressibility resembles solitary behavior. These properties categorize the phenomena as a weak deto…
The present work reports new experiments of detonation diffraction in a 2D channel configuration in stoichiometric mixtures of ethylene, ethane, and methane with oxygen as oxidizer. The flow field details are obtained using high-speed schlieren near the critical conditions of diffraction. The critical initial pressure for successful diffraction is reported for the ethylene, ethane and methane mixtures. The flow field details revealed that the lateral portion of the wave results in a zone of quenched ignition. The dynamics of the laterally diffracting shock front are found in good agreement wit…
The problem of engine unstart of scramjets has not been resolved. In this paper, the mechanism of engine unstart is discussed from the point of view of shock/shock interaction and deflagration-to-detonation transition. The shock/shock interaction leads to the nonlinear, transient and discontinuous process of the supersonic combustion flow field. This process is similar to the deflagration-to-detonation transition process. If the velocity of pre-combustion shock wave is faster than the velocity in the isolator, it will propagate upstream and cause the engine unstart. The C-J detonation velocity…
The dynamic evolution of a highly underexpanded transient supersonic jet at the exit of a pulse detonation engine is investigated via high-resolution time-resolved schlieren and numerical simulations. Experimental evidence is provided for the presence of a second triple shock configuration along with a shocklet between the reflected shock and the slipstream, which has no analogue in a steady-state underexpanded jet. A pseudo-steady model is developed, which allows for the determination of the post-shock flow condition for a transient propagating oblique shock. This model is applied to the nume…
The origin of a vortex structure generated during the shock-plasma interaction is investigated. A two-dimensional model based on the shock refraction mechanism successfully unifies the vortex generation with major co-processes typical for the interaction and thus well fits in their cause-and-consequence relationship. Numerical simulations demonstrated the possibility of an intense vortex generation with a continuous positive dynamics as the shock crosses the interface. It was shown that while the vorticity is triggered by the shock refraction on the interface, it is the gas parameter distribut…
Type Ia supernovae (SNe Ia) play a critical role in astrophysics, yet their origin remains mysterious. A crucial physical mechanism in any SN Ia model is the initiation of the detonation front which ultimately unbinds the white dwarf progenitor and leads to the SN Ia. We demonstrate, for the first time, how a carbon detonation may arise in a realistic three-dimensional turbulent electron-degenerate flow, in a new mechanism we refer to as turbulently-driven detonation. Using both analytic estimates and three-dimensional numerical simulations, we show that strong turbulence in the distributed bu…
(Abridged) A series of three-dimensional numerical simulations is used to study the intrinsic stability of high-speed turbulent flames. Calculations model the interaction of a fully-resolved premixed flame with a highly subsonic, statistically steady, homogeneous, isotropic turbulence. We consider a wide range of turbulent intensities and system sizes, corresponding to the Damköhler numbers Da = 0.1-6.0. These calculations show that turbulent flames in the regimes considered are intrinsically unstable. In particular, we find three effects. 1) Turbulent flame speed develops pulsations with the …
It is known that unconfined dust explosions consist of a relatively weak primary (turbulent) deflagrations followed by a devastating secondary explosion. The secondary explosion may propagate with a speed of up to 1000 m/s producing overpressures of over 8-10 atm. Since detonation is the only established theory that allows a rapid burning producing a high pressure that can be sustained in open areas, the generally accepted view was that the mechanism explaining the high rate of combustion in dust explosions is deflagration to detonation transition. In the present work we propose a theoretical …
A recently proposed technique for improving ignition timing is investigated for real-gas effects. A correction to the model describing the cumulative energy effect in the presence of the shock-discontinuity interaction was done by re-considering the RH-relations and the shock refraction equations. Non-dissociating gas in thermal equilibrium state, with excited translational, rotational, vibrational, and electronic degrees of freedom is considered. When applied to N2 gas at T=3000 K, 11% density increase and 17% temperature and 7% pressure jump decrease were found, compared to that in ideal gas…
