Thermally or chemically active colloids generate thermodynamic gradients in the solution in which they are immersed and thereby induce hydrodynamic flows that affect their dynamical evolution. Here we study a mean-field model for the many-body dynamics of a monolayer of active particles located at a fluid-fluid interface. In this case, the activity of the particles creates long-ranged Marangoni flows due to the response of the interface, which compete with the direct interaction between the particles. For the most interesting case of a $r^{-3}$ soft repulsion that models the electrostatic or magnetic interparticle forces, we show that an "onion-like" density distribution will develop within the monolayer. For a sufficiently large average density, two-dimensional phase transitions (freezing from liquid to hexatic, and melting from solid to hexatic) should be observable in a radially stratified structure. Furthermore, the analysis allows us to conclude that, while the activity may be too weak to allow direct detection of such induced Marangoni flows, it is relevant as a collective effect in the emergence of the experimentally observable spatial structure of phase coexistences noted above. Finally, the relevance of these results for potential experimental realizations is critically discussed.
Active spheres induce Marangoni flows that drive collective dynamics
Martin Wittmann (contributed equally) Technical University Dresden, Zellescher Weg 19, DE-01069 Dresden, Germany Mihail N. Popescu (contributed equally) ORCID: 0000-0002-1102-7538 Max Planck Institute for Intelligent Systems, Heisenbergstr. 3, D-70569 Stuttgart, Germany Alvaro Dom \'i nguez (corresponding author) ORCID: 0000-0002-8529-9667 F \'i sica Te \'o rica, Universidad de Sevilla, Apdo. 1065, 41080 Sevilla, Spain Instituto Carlos I de F \'i sica Te \'o rica y Computacional, 18071 Granada, Spain Juliane Simmchen (corresponding author) ORCID: 0000-0001-9073-9770 Technical University Dresden, Zellescher Weg 19, DE-01069 Dresden, Germany Tel.: +49 351 463-37433 Fax: +49 351 463-37164
