Highly reproducible superconductivity in potassium-doped triphenylbismuth

英文摘要：

Using a new two-step synthesis method - ultrasound treatment and low temperature annealing, we explore superconductivity in potassium-doped triphenylbismuth, which is composed of one bismuth atom and three phenyl rings. The combination of dc and ac magnetic measurements reveals that one hundred percent of synthesized samples exhibit superconductivity at 3.5 K and/or 7.2 K at ambient pressure. The magnetization hysteresis loops provide a strong evidence of type-II superconductor, with the upper critical magnetic field up to 1.0 Tesla. Both calculated electronic structure and measured Raman spectra indicate that superconductivity is realized by transferring electron from potassium to carbon atom. Our study opens an encouraging window for the search of organic superconductors in organometallic molecules.