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arXiv 1709.01435cond-mat.str-el
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50%电子掺杂铑酸盐Sr $_{1.5}$ La $_{0.5}$ RhO $_{4}$的单晶生长和物理性质

Single crystal growth and physical properties of 50% electron doped rhodate Sr$_{1.5}$La$_{0.5}$RhO$_{4}$

Z. W. Li, H. Guo, Z. Hu, T. S. Chan, K. Nemkovski, A. C. Komarek

摘要:

在氧压为20 bar的条件下,采用浮区法生长了厘米级的Sr $_{1.5}$ La $_{0.5}$ RhO $_{4}$单晶。我们的单晶的质量通过X射线劳厄,粉末和单晶X射线衍射,中子和X射线吸收光谱测量确认。在$\sim$ 50%电子掺杂时,我们观察到$\sim$ 8.2 $^{\circ}$在八面体基面内的RhO $_3$八面体旋转,其与空间群I4/mmm不相容。我们的单晶进一步表征了磁化率,电输运,最后,比热测量显示出温度依赖性德拜温度。

英文摘要:

Centimeter-sized single crystals of Sr$_{1.5}$La$_{0.5}$RhO$_{4}$ were grown by the floating zone method at oxygen pressures of 20~bar. The quality of our single crystals was confirmed by X-ray Laue, powder and single crystal X-ray diffraction, neutron and X-ray absorbtion spectroscopy measurements. At $\sim$50% electron doping we observe RhO$_3$ octahedral rotations of $\sim$8.2$^{\circ}$ within the octahedral basal plane which are incompatible with space group I4/mmm. Our single crystal was further characterized by susceptibility, electrical transport and, finally, specific heat measurements showing a temperature dependent Debye temperature.

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