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arXiv 1709.01038cond-mat.softcond-mat.mtrl-sci
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球形晶体团簇中的拓扑空位

Topological vacancies in spherical crystal clusters

Zhenwei Yao

摘要:

曲面上二维凝聚态有序相的几何阻挫与凝聚态物理和材料科学中的许多科学问题密切相关。在这里,我们展示了如何二维Lennard-Jones晶体团簇限制在一个球体上解决几何挫折,并导致五边形空位结构。这些空位来源于曲率和物理相互作用的结合,是拓扑缺陷,并可进一步分为位错型和向错型。我们分析了这些晶体学缺陷作为空位和拓扑缺陷的双重作用,阐明了它们的形成机制,并给出了相图。所揭示的拓扑空位的双重作用可能会在制造坚固的纳米孔中找到应用。这项工作还表明,利用物理相互作用和衬底几何形状的丰富性来创造新类型的晶体缺陷,这与晶体材料的设计有很强的联系,具有很大的潜力。

英文摘要:

Understanding geometric frustration of ordered phases in two-dimensional condensed matters on curved surfaces is closely related to a host of scientific problems in condensed matter physics and materials science. Here we show how two-dimensional Lennard-Jones crystal clusters confined on a sphere resolve the geometric frustration and lead to pentagonal vacancy structures. These vacancies, originated from the combination of curvature and physical interaction, are found to be topological defects and they can be further classified into dislocational and disclinational types. We analyze the dual role of these crystallographic defects as both vacancies and topological defects, illustrate their formation mechanism, and present the phase diagram. The revealed dual role of the topological vacancies may find applications in the fabrication of robust nanopores. This work also suggests the promising potential of exploiting the richness in both physical interactions and substrate geometries to create new types of crystallographic defects, which have strong connections with the design of crystalline materials.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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