H $_2^+$的振转态。变分计算
Ro-vibrational states of H$_2^+$. Variational calculations
摘要:
本文用非相对论变分法计算了在$1sσ$绝热基态支持下H $_2^+$分子离子的一整套振转态。它包括位于$n=1$阈值以上的束缚态和共振态。在后一种情况下,我们也评估一个状态的predissociation宽度,无论它是显着的。讨论了相对论修正和辐射修正,并将这些修正的有效绝热势作为补充文件。
英文摘要:
The nonrelativistic variational calculation of a complete set of ro-vibrational states in the H$_2^+$ molecular ion supported by the ground $1sσ$ adiabatic potential is presented. It includes both bound states and resonances located above the $n=1$ threshold. In the latter case we also evaluate a predissociation width of a state wherever it is significant. Relativistic and radiative corrections are discussed and effective adiabatic potentials of these corrections are included as supplementary files.
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