综述了以无孔AAO为模板制备形貌和性能可控的polymer纳米结构的研究进展
A review on the progress of polymer nanostructures with modulated morphologies and properties, using nonporous AAO templates
摘要:
具有相同化学组成的聚合物可以通过减小尺寸或简单地通过改变其纳米结构来提供不同的性质。最近的文献报道了数百个例子的进展方法在聚合物纳米结构的制造完成以下不同的方法,软光刻,自组装路线,模板辅助的方法,等聚合物纳米结构的调制形态和性能可以很容易地实现从阳极氧化铝(AAO)模板辅助的方法。在过去的十年中,在AAO纳米腔中制造聚合物纳米结构引起了极大的兴趣,因为它允许控制和定制大量聚合物和聚合物基复合材料的尺寸。事实上,聚合物的尺寸可以调整允许的尺寸依赖性的性质的研究。此外,调制的聚合物纳米结构可以从AAO模板方法设计用于特定的应用。考虑到最后的考虑,本文综述了最近的和新的见解,在制造聚合物纳米结构的方法从硬质多孔阳极氧化铝(AAO)模板的重点是在纳米尺度上的聚合物结构/性能关系的研究,并强调在特定的应用中的潜在利益。
英文摘要:
Polymers with the same chemical composition can provide different properties by reducing the dimension or simply by altering their nanostructure. Recent literature works report hundreds of examples of advances methods in the fabrication of polymer nanostructures accomplished following different approaches, soft lithography, self-assembly routes, template assisted methods, etc. Polymer nanostructures with modulated morphologies and properties can be easily achieved from anodized aluminum oxide (AAO) templates assisted methods. In the last decade, fabrication of polymer nanostructures in the nanocavities of AAO has raised a great interest since allows the control and tailoring of dimension of a huge number of polymer and polymer-based composites materials. The fact that polymer dimension can be adjusted allow the study of size-dependency properties. Moreover, modulated polymer nanostructures can be designed for specific applications from AAO templates methods. Taking into account the last considerations, this review present an overview of recent and new insights in the fabrication methods of polymer nanostructures from hard porous Anodic Aluminum Oxide (AAO) templates with emphasis on the study of polymer structure/property relationship at nanometric scale and stressing the potential interest in particular applications.
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