一种零、超低磁场下的核磁共振仪器
Instrumentation for nuclear magnetic resonance in zero and ultralow magnetic field
摘要:
我们审查仪器核磁共振(NMR)在零和超低磁场(ZULF,低于0.1 $μ$ T)的检测是基于一个低成本,非低温,自旋交换弛豫(SERF)$^{87}$ Rb原子磁力计。对于低于1 kHz的信号频率,典型的灵敏度为20-30 fT/Hz $^{1/2}$,NMR线宽范围从Hz一直到几十mHz。这些特性使得能够精确测量化学信息的核自旋-自旋耦合以及超低磁场中的核自旋进动。
英文摘要:
We review instrumentation for nuclear magnetic resonance (NMR) in zero and ultra-low magnetic field (ZULF, below 0.1 $μ$T) where detection is based on a low-cost, non-cryogenic, spin-exchange relaxation free (SERF) $^{87}$Rb atomic magnetometer. The typical sensitivity is 20-30 fT/Hz$^{1/2}$ for signal frequencies below 1 kHz and NMR linewidths range from Hz all the way down to tens of mHz. These features enable precision measurements of chemically informative nuclear spin-spin couplings as well as nuclear spin precession in ultra-low magnetic fields.
机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。