《物理化学》的失落章节意味着费歇尔-柯尔莫哥洛夫方程与隧道效应的收敛
Lost chapter of Physical Chemistry means convergence between Fisher Kolmogorov equation and tunnel effect
摘要：
在这项工作中，我们表明，动力学的化学反应的顺序为零，一，二有一个表示通过物流概率。该概率是稳健的、稳定的，并且系统地符合Fisher Kolmogorov（FK）的微分方程。它是鲁棒的，因为在定理1和定理3中，得到了扩散和传热的微分方程，其中温度起着关键作用。另外，利用波动力学的程函方程，我们可以构造热方程。在引理2中，证明了Fick扩散方程。它是稳定的，因为当t无穷大收敛时，概率收敛给了我们新的方法来整体分析反应动力学，在推论5中。最后，理论和实验获得的算法和结果支持量子隧道效应和化学反应的概率收敛：在超低温下制氢和在高温下催化裂化沥青。
英文摘要：
In this work we show that the dynamics of chemical reactions of order zero, one and two have a representation through logistics probability. This probability is robust, stable and complies systemically with the differential equation of Fisher Kolmogorov (F K). It is robust, because in theorem 1 and theorem 3 differential equations of diffusion and heat transfer are obtained, where the temperature plays a key role. Also, the Eikonal equation of wave mechanics allows us to construct the heat equation. In Lemma 2, Fick diffusion equation is demonstrated. It is stable, because probability convergence when t converge infinitum, gives us new ways to analyze the kinetics of a reaction integrally, in Corollary 5. Finally, the theoretically and experimentally obtained algorithms and results support the convergence in probability of the quantum tunnel effect and chemical reactions for: hydrogen production at ultra low temperature and catalytic cracking of asphalt at high temperature.
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