We propose two possible new compounds, Ba$_2$CuO$_2$Fe$_2$As$_2$ and K$_2$CuO$_2$Fe$_2$Se$_2$, which hybridize the building blocks of two high temperature superconductors, cuprates and iron-based superconductors. These compounds consist of square CuO$_2$ layers and antifluorite-type Fe$_2$X$_2$ (X=As,Se) layers separated by Ba/K. The calculations of binding energies and phonon spectrums indicate that they are dynamically stable, which ensures that they may be experimentally synthesized. The Fermi surfaces and electronic structures of the two compounds inherit the characteristics of both cuprates and iron-based superconductors. These compounds can be superconductors with intriguing physical properties to help to determine pairing mechanisms of high $T_c$ superconductivity.
A theoretical overview of the classes of superconductors encompassing (a) high-Tc cuprate, (b) iron-based and (c) aromatic superconductors is given. Emphasis is put on the multiband natures of all the three classes, where the differences in the multiorbits and their manifestations in the electronic structures and pairing are clarified. From these, future directions and prospects are discussed.
We propose a unified description of cuprate and iron-based superconductivity. Consistency with magnetic structure inferred from neutron scattering implies significant constraints on the symmetry of the pairing gap for the iron-based superconductors. We find that this unification requires the orbital pairing formfactors for the iron arsenides to differ fundamentally from those for cuprates at the microscopic level.
Both families of high $T_c$ superconductors, iron pnictides and cuprates, exhibit material dependence of superconductivity. Here, we study its origin within the spin fluctuation pairing theory based on multiorbital models that take into account realistic band structures. For pnictides, we show that the presence and absence of Fermi surface pockets is sensitive to the pnictogen height measured from the iron plane due to the multiorbital nature of the system, which is reflected to the nodeless/nodal form of the superconducting gap and $T_c$. Surprisingly, even for the cuprates, which is conventi…
A key question in the theory of high-temperature superconductivity is whether Off-diagonal Long-Range Order (ODLRO) can be induced wholly or in large part by repulsive electronic correlations. Electron pairs on Cuprate and the iron-based pnictide and chalcogenide alternant lattices may interact with a strong short-range Coulomb repulsion and much weaker longer range attractive tail. Here we show that such interacting electrons can cooperate to produce a superconducting state in which time-reversed electron pairs effectively avoid the repulsive part but reside predominantly in the attractive re…
Within the framework of the kinetic energy driven superconducting mechanism, the doping dependence of the electromagnetic response in the electron-doped cuprate superconductors is studied. It is shown that although there is an electron-hole asymmetry in the phase diagram, the electromagnetic response in the electron-doped cuprate superconductors is similar to that observed in the hole-doped cuprate superconductors. The superfluid density depends linearly on temperature, except for the strong deviation from the linear characteristics at the extremely low temperatures.
The order parameter in superconductivity of cuprates is investigated in the framework of the Bogoliubov theory. By using a simplifying assumption about the electronic states, it is predicted an effective critical temperature Tc* > Tc associated to the coherent gap D0. A connection between D0 and the antinodal pseudogap DPG is proposed allowing for a comprehensive picture of the main experimental features of cuprate superconductors.
Recent development in the physics of high-temperature superconductivity is reviewed, with special emphasis on the studies of the low-energy excitations of cuprate and iron-based superconductors. For cuprate superconductors, a phenomenology based on coexisting competing orders with superconductivity in the ground state of these doped Mott insulators is shown to provide a consistent account for a wide range of experimental findings. In the case of iron-based superconductors, studies of the low-energy excitations reveal interesting similarities and differences when compared with cuprate supercond…
The vortex transport entropy in the mixed state of the cuprate superconductors YBa$_2$Cu$_3$O$_{7-δ}$ and Bi$_2$Sr$_2$CaCu$_2$O$_{8+x}$ at the maximum Nernst or Ettingshausen signal below $T_c$ is discussed. The vortex transport entropy per CuO$_2$ double layer in the cuprate epitaxial films is found to be close to the Boltzmann constant.
We study the lowest energy state in the CuO$_2$ plane of cuprate superconductors, related to the vibration that does not involve distortions of constituent units of the plane, the Rigid Unit Mode (RUM). We discuss the correlated motion in the plane due to RUM on temperature decrease, and possible relevance of this phonon for superconductivity.
In order to explore the reason why the single-layered cuprates, La$_{2-x}$(Sr/Ba)$_x$CuO$_4$ ($T_c\simeq$ 40K) and HgBa$_2$CuO$_{4+δ}$ ($T_c\simeq$ 90K), have such a significant difference in $T_c$, we study a two-orbital model that incorporates the $d_{z^2}$ orbital on top of the $d_{x^2-y^2}$ orbital. It is found, with the fluctuation exchange approximation, that the $d_{z^2}$ orbital contribution to the Fermi surface, which is stronger in the La system, works against d-wave superconductivity, thereby dominating over the effect of the Fermi surface shape. The result resolves the long-standin…
Short review of the topical comprehension of Cuprate High-Temperature Superconductors, featuring structural and metallurgical aspects that optimize their superconducting properties with respect to technical applications.
The formula frequently used to describe the c-axis infrared response of the coupled electron-phonon system of bilayer cuprate superconductors and providing important insights into the physics of these materials has been originally obtained at the level of the phenomenological multilayer model. Here we derive it using diagrammatic perturbation theory.
We propose a microscopic explanation of the pseudogap features discovered in the normal state specific heat and magnetic susceptibility of cuprates. In the framework of the bipolaron theory of high-Tc superconductors we explain the magnitude of the carrier specific heat and susceptibility as well as their universal scaling with temperature over a wide range of doping.
Anisotropy, thermal and quantum fluctuations and their dependence on dopant concentration appear to be present in all cuprate superconductors, interwoven with the microscopic mechanisms responsible for superconductivity. Here we review anisotropy, in-plane and c-axis penetration depths, isotope effect and conductivity measurements to reassess the universal behavior of cuprates as revealed by the doping dependence of these phenomena and of the transition temperature.
We critically review recent and earlier results on isotope effects in cuprate superconductors and emphasize that the sample preparation and the isotope exchange and back exchange are crucial in understanding and interpreting the data. Only extremely careful preparation techniques yield reliable results and permit differentiation between real isotope effects and marginal ones. The former are substantial and highlight the lattice vibrational importance in cuprate superconductors.
When combining the BCS expression of Tc with a shear modulus constant model, we can demonstrate that Tc oscillates depending on the number of the cuprate planes and that it reaches its first maximum for three planes. This is in good agreement with experimental data and suggests that the electron- phonon coupling is essential to the superconductivity of the cuprates.
Phase-sensitive tests of pairing symmetry have provided strong evidence for predominantly d-wave pairing symmetry in both hole- and electron-doped high-Tc cuprate superconductors. Temperature dependent measurements in YBCO indicate that the d-wave pairing dominates, with little if any imaginary component, at all temperatures from 0.5K through Tc. In this article we review some of this evidence and discuss the implications of the universal d-wave pairing symmetry in the cuprates.
Using the scaling theory of quantum critical phenomena we present a detailed analysis of various superconducting properties of La$_{2-x}$Sr$_{x}$CuO$_{4}$, Y$_{0.8}$Ca$_{0.2}$-123, Tl-1212 and Tl-2201. Our results include: the experimental data are fully consistent with a 2D insulator to superconductor (ISQ) transition in the underdoped limit. The quantum critical properties appear to be equivalent to those of a dirty 2D bosonic system with long range Coulomb interaction. Together with previous evidence, this transition appears to be a generic feature of cuprate superconductors. The 3D superco…
The electronic Raman response in the electron-doped cuprate superconductors is studied based on the $t$-$t'$-$J$ model. It is shown that although the domelike shape of the doping dependent peak energy in the $B_{2g}$ symmetry is a common feature for both electron-doped and hole-doped cuprate superconductors, there are pronounced deviations from a cubic response in the $B_{1g}$ channel and a linear response in the $B_{2g}$ channel for the electron-doped case in the low energy limit. It is also shown that these pronounced deviations are mainly caused by a nonmonotonic d-wave gap in the electron-…
The orbital component of the order parameter in the cuprate high-Tc cuprate superconductors is now well established, in large part because of phase sensitive tests. Although it would be desirable to use such tests on other unconventional superconductors, there are a number of favorable factors associated with the properties of the cuprates, and a number of technical advances, that were required for these tests to be successful. In this review I will describe the development of phase sensitive pairing symmetry tests using SQUID microscopy, underlining the factors favoring these experiments in t…
It is conjectured that the anomalous spin dynamics observed in the normal state of cuprate superconductors might find its origin in a nearly ordered spin system which is kept in motion by thermally meandering charged domain walls. `Temperature sets the scale' finds a natural explanation, while a crossover to a low temperature quantum domain wall fluid is implied.
We compare the one-loop functional renormalization group results for the cuprates and the iron pnictides. Interestingly a coherent picture suggesting that antiferromagnetic correlation causes pairing for both materials emerges.
We study the effects of quantum vortex fluctuations in two-dimensional superconductors using a dual theory of vortices, and investigate the relevance to underdoped cuprates where the superconductor-insulator transition (SIT) is possibly driven by quantum vortex proliferation. We find that a broad enough phase fluctuation regime may exist for experimental observation of the quantum vortex fluctuations near SIT in underdoped cuprates. We propose that this scenario can be tested via pair-tunneling experiments which measure the characteristic resonances in the zero-temperature pair-field susceptib…
We present macroscopic experimental evidence for field-induced microscopic quantum fluctuations in different hole- and electron-type cuprate superconductors with varying doping levels and numbers of CuO$_2$ layers per unit cell. The significant suppression of the zero-temperature in-plane magnetic irreversibility field relative to the paramagnetic field in all cuprate superconductors suggests strong quantum fluctuations due to the proximity of the cuprates to quantum criticality.
We show by means of the theory of the order parameter phase fluctuations that the temperature of "closing" (or "opening") of the gap (and pseudogap) in the electron spectra of superconductors with anisotropic order parameter takes place within a finite temperature range. Every Fourier-component of the order parameter has its own critical temperature.
Since their experimental discovery in 1989, the electron-doped cuprate superconductors have presented both a major challenge and a major opportunity. The major challenge has been to determine whether these materials are fundamentally different from or essentially similar to their hole-doped counterparts; a major opportunity because answering this question would strongly constrain the possible explanations for what is the essential physics that leads to high temperature superconductivity in the cuprates, which is still not agreed upon. Here we argue that experimental results over the past 30 ye…
We outline the universal and finite temperature critical properties of the 3D-XY model, extended to anisotropic extreme type-II superconductors, as well as the universal quantum critical properties in 2D. On this basis we review: (i) the mounting evidence for 3D-XY behavior in optimally doped cuprate superconductors and the 3D to 2D crossover in the underdoped regime; (ii) the finite size limitations imposed by inhomogeneities; (iii) the experimental evidence for a 2D-XY quantum critical point in the underdoped limit, where the superconductor to insulator transition occurs; (iv) the emerging i…
A theory for electronic Raman scattering in the cuprate superconductors is presented with a specific emphasis on the polarization dependence of the spectra which can infer the symmetry of the energy gap. Signatures of the effects of disorder on the low frequency and low temperature behavior of the Raman spectra for different symmetry channels provide detailed information about the magnitude and the phase of the energy gap. Properties of the theory for finite T are discussed and compared to recent data concerning the doping dependence of the Raman spectra in cuprate superconductors, and remaini…
We have calculated the tunneling conductance of a superconductor-insulator-superconductor junction based on the polaron-bipolaron theory of superconductivity. The predicted incoherent hump features are in quantitative agreement with tunneling spectra of optimally doped Bi2Sr2CaCu2O8+y and Bi2Sr2Ca2Cu3O10+y. We further show that angle-resolved photoemission spectra of underdoped cuprates are consistent with the Bose-Einstein condensation of inter-site bipolarons and that the superconducting gap symmetry is d-wave, which is determined by the anomalous kinetic process rather than by the pairing i…
Impurity doping like Zn atoms in cuprates were systematically studied to provide important information on the pseudogap phase because this process substantially reduces $T_c$ without effect $T^*$. Despite many important results and advances, the normal phase of these superconductors is still subject of a great debate. We show that the observed Zn-doped data can be reproduced by constructing a nanoscale granular superconductor whose resistivity transition is achieved by Josephson coupling, what provides also a simple interpretation to the pseudogap phase.
Recent advances in the development of Josephson scanning tunneling spectroscopy (JSTS) have opened a new path for the exploration of unconventional superconductors. We demonstrate that the critical current, $I_c$, measured via JSTS, images the spatial form of the superconducting order parameter in $d_{x^2-y^2}$-wave superconductors around defects and in the Fulde-Ferrell-Larkin-Ovchinnikov state. Moreover, we show that $I_c$ probes the existence of phase-incoherent superconducting correlations in the pseudo-gap region of the cuprate superconductors, thus providing unprecedented insight into it…
We investigate the issues of competing orders and quantum criticality in cuprate superconductors via experimental studies of the high-field thermodynamic phase diagrams and the quasiparticle tunneling spectroscopy. Our results suggest substantial field-induced quantum fluctuations in all cuprates investigated, and their correlation with quasiparticle spectra implies that both electron- (n-type) and hole-doped (p-type) cuprate superconductors are in close proximity to a quantum critical point that separates a pure superconducting (SC) phase from a phase consisting of coexisting SC and a competi…
We review the field of high temperature cuprate superconductors, with an emphasis on the nature of their electronic properties. After a general overview of experiment and theory, we concentrate on recent results obtained by angle resolved photoemission, inelastic neutron scattering, and optical conductivity, along with various proposed explanations for these results. We conclude by reviewing efforts which attempt to identify the energy savings involved in the formation of the superconducting ground state.
Enhancing the temperature at which superconductivity is observed is a long-standing objective for materials scientists. Recent tantalizing experiments suggest a possible route for achieving this.
The correlation between the charge-order wave vector Q_{CD} and second-neighbor hopping t' in cuprate superconductors is studied based on the t-t'-J model. It is shown that the magnitude of the charge-order wave vector Q_{CD} increases with the increase of t', and then the experimentally observed differences of the magnitudes of the charge-order wave vector Q_{CD} among the different families of cuprate superconductors at the same doping concentration can be attributed to the different values of t'.
The transport of heat and charge in the overdoped cuprate superconductor Tl_2Ba_2CuO_(6+delta) was measured down to low temperature. In the normal state, obtained by applying a magnetic field greater than the upper critical field, the Wiedemann-Franz law is verified to hold perfectly. In the superconducting state, a large residual linear term is observed in the thermal conductivity, in quantitative agreement with BCS theory for a d-wave superconductor. This is compelling evidence that the electrons in overdoped cuprates form a Fermi liquid, with no indication of spin-charge separation.
Within the spin-fermion model for cuprate superconductors, the influence of the intersite Coulomb interactions $V_2$ and $V_2'$ between holes located at the next-nearest-neighbor oxygen ions of CuO$_2$ plane on the implementation of the d_{x^2-y^2}-wave pairing is studied. It is shown that d-wave pairing can be suppressed only for unphysically large values of $V_2$ and $V_2'$.
We study a simple BCS-like model which describes unconventional superconductivity on the basis of an electron-electron attraction corresponding to the delta-shell potential: $U(r) = -g δ(r-r_0)$. It predicts a $T_c$ vs. doping behavior similar to that characteristic of the High-$T_c$ cuprates.
Quasiparticle tunneling spectra of both hole-doped (p-type) and electron-doped (n-type) cuprates are studied using a low-temperature scanning tunneling microscope. The results reveal that neither the pairing symmetry nor the pseudogap phenomenon is universal among all cuprates, and that the response of n-type cuprates to quantum impurities is drastically different from that of the p-type cuprates. The only ubiquitous features among all cuprates appear to be the strong electronic correlation and the nearest-neighbor antiferromagnetic Cu^{2+}-Cu^{2+} coupling in the CuO_2 planes.
The observation of the characteristic Kosterlitz-Thouless behavior requires the attaintment of the two dimensional limit where the correlation-length anisotropy, gamma=gsiab/gsic, diverges. Our findings strongly suggest that the failure of several experiments on films and single crystals to observe any trace of KT-behavior is attributable either to inhomogeneities or doping by means of chemical substitution.
We propose a weakly coupled two-band model with $d_{x^2-y^2}$ pairing symmetry to account for the anomalous temperature dependence of superfluid density $ρ_s$ in electron-doped cuprate superconductors. This model gives a unified explanation to the presence of a upward curvature in $ρ_s$ near $T_c$ and a weak temperature dependence of $ρ_s$ in low temperatures. Our work resolves a discrepancy in the interpretation of different experimental measurements and suggests that the pairing in electron-doped cuprates has predominately $d_{x^2-y^2}$ symmetry in the whole doping range.
We report the pressure effect in Bi2Sr2Ca2Cu3O10+δ (Bi-2223) single crystal with a small amount of intergrowth of Bi2Sr2CaCu2O8+δ (Bi-2212). Their superconducting transition temperatures Tcs showed a domelike shape as a function of pressure, which showed a good agreement with the general relation between the carrier concentration and Tc. Our experimental results indicate that high pressure can induce effective carrier doping into the multilayered high-Tc cuprate superconductor
Nature of extrinsic and intrinsic self-trapping (ST) of charge carriers in cuprates have been studied theoretically. The binding energies and radii of the extrinsic and intrinsic large polarons and bipolarons in cuprates are calculated variationally using the continuum model and adiabatic approximation. We have shown that the extrinsic and intrinsic three-dimensional (3D) large bipolarons exist in underdoped cuprates at $η=\varepsilon_{\infty}/\varepsilon_0<0.127$ and $η<0.138$, respectively [where $\varepsilon_{\infty}$ ($\varepsilon_0$) is the optic (static) dielectric constant].
The iron pnictides and the cuprates represent two families of materials, where strong antiferromagnetic correlation drives three other distinct ordering tendencies: (1) superconducting pairing, (2) Fermi surface distortion, and (3) orbital current order. We propose that (1)-(3) and the antiferromagnetic correlation are the hallmarks of a class of strongly correlated materials to which the cuprates and pnictides belong. In this paper we present the results of the functional renormalization group studies to support the above claim. In addition, we show that as a function of the interlayer hoppin…
We calculate angle-dependent magnetoresistance oscillations (AMRO) for interlayer transport of cuprate superconductors in the presence of ($π,π$) order. The order reconstructs the Fermi surface, creating magnetic breakdown junctions; we show how such magnetic breakdown effects can be incorporated into calculations of interlayer conductivity for this system. We successfully fit experimental data with our model, and these fits suggest a connection between ($π,π$) order and the anisotropic scattering observed in overdoped cuprates. This work paves the way for the use of AMRO as a tool to distingu…
Using a conventional BCS -- Fermi liquid model we calculate the c-axis optical reflectivity of the layered high temperature cuprate superconductors by obtaining the finite temperature dynamical dielectric function in a microscopic self-consistent gauge invariant formalism. We get good semi-quantitative agreement with all the existing experimental data by using the measured normal state $dc$ resistivities as the input parameters in obtaining the c-axis hopping amplitude and the normal state level broadening in our microscopic calculation.
Evidence from NMR of a two-component spin system in cuprate high-$T_c$ superconductors is shown to be paralleled by similar evidence from the electronic entropy so that a two-component quasiparticle fluid is implicated. We propose that this two-component scenario is restricted to the optimal and underdoped regimes and arises from the upper and lower branches of the reconstructed energy-momentum dispersion proposed by Yang, Rice and Zhang (YRZ) to describe the pseudogap. We calculate the spin susceptibility within the YRZ formalism and show that the doping and temperature dependence reproduces …
In the cuprate and iron-pnictide systems, valence changes induce high-temperature superconductivity while the local structural chemistry and local spin order both independently generate the attractive interactions responsible for the high transition temperature. We argue that together they favor d-wave singlet superconductivity in the cuprates but s-wave singlet in the pnictides. This difference arises from the existence of a large on-site repulsion between carriers in the cuprates largely absent in the pnictides. Fluorine is responsible for raising Tc significantly in some pnictides and in th…
The renormalization of the electrons in cuprate superconductors is characterized by the kink in the quasiparticle dispersion. Here the bilayer coupling effect on the quasiparticle dispersion kink in the electron-doped bilayer cuprate superconductors is studied based on the kinetic-energy-driven superconductivity. It is shown that the kink in the quasiparticle dispersion is present all around the electron Fermi surface, as the quasiparticle dispersion kink in the single-layer case. However, in comparison with the corresponding single-layer case, the kink effect in the quasiparticle dispersion a…
In this work, we generalize the theory of localized surface plasmons to the case of high-Tc cuprate superconductors, spatially confined in the form of small spherical particles. At variance from ordinary metals, cuprate superconductors are characterized by a low-energy bulk excitation known as the Josephson plasma wave (JPW), arising from interlayer tunneling of the condensate along the c-axis. The effect of the JPW is revealed in a characteristic spectrum of surface excitations, which we call Josephson surface plasmons. Our results, which apply to any material with a strongly anisotropic elec…
We study the order parameter phase fluctuation effects in cuprate superconductors near T=0, using a quasi-two-dimensional d-wave BCS model. An effective phason theory is obtained which is used to estimate the strength of the fluctuations, the fluctuation correction to the in-plane penetration depth, and the pair-field susceptibility. We find that while the phase fluctuation effects are difficult to observe in the renormalization of the superfluid phase stiffness, they may be observed in a pair tunneling experiment which measures the pair-field susceptibility.
We show that, by using unit-cell transformation between 1 Fe per unit cell to 2 Fe per unit cell, one can qualitatively understand the pairing symmetry of several families of iron-based superconductors. In iron-pnictides and iron-chalcogenides, the nodeless s+- pairing and the resulting magnetic resonance mode transform nicely between the two unit cells, while retaining all physical properties unchanged. However, when the electron-pocket disappears from the Fermi surface with complete doping in KFe2As2, we find that the unit-cell invariant requirement prohibits the occurrence of s+- pairing sy…
The effect of pressure on the magnetic penetration depth $λ$ was tested in the hole-doped superconductor YBa2Cu3O(7-d) and in the electron-doped one Sr0.9La0.1CuO2 by means of magnetization measurements. Whereas a large change of $λ$ was found in YBa2Cu3O(7-d), confirming the non-adiabatic character of the electron-phonon coupling in hole-doped superconductors, the same quantity is not affected by pressure in the electron-doped Sr0.9La0.1CuO2, suggesting a close similarity of the latter to conventional adiabatic BCS superconductors. The present results imply a remarkable difference between the…
The interplay between the superconducting gap and normal-state pseudogap in the bilayer cuprate superconductors is studied based on the kinetic energy driven superconducting mechanism. It is shown that the charge carrier interaction directly from the interlayer coherent hopping in the kinetic energy by exchanging spin excitations does not provide the contribution to the normal-state pseudogap in the particle-hole channel and superconducting gap in the particle-particle channel, while only the charge carrier interaction directly from the intralayer hopping in the kinetic energy by exchanging sp…
We present phase-sensitive evidence that the electron-doped cuprates Nd1.85Ce0.15CuO4-y (NCCO) and Pr1.85Ce0.15CuO4-y (PCCO) have d-wave pairing symmetry. This evidence was obtained by observing the half-flux quantum effect, using a scanning SQUID microscope, in c-axis oriented films of NCCO or PCCO epitaxially grown on tricrystal [100] SrTiO3 substrates designed to be frustrated for a d(x2-y2) order parameter. Samples with two other configurations, designed to b unfrustrated for a d-wave superconductor, do not show the half-flux quantum effect.
We derive a pair potential from tight binding further neighbours attraction that leads to superconducting gap symmetry similar to that of the phenomenological spin fluctuation theory of high temperature superconductors (Monthoux, Balatsky, Pines, Phys. Rev. Lett. {\bf 67}, 3448). We show that higher anisotropic d-wave than the simpliest d-wave symmetry is one of the important ingredients responsible for higher BCS characteristic ratio.
We have analyzed scanning tunneling spectra of two electron-doped cuprates Pr0.88LaCe0.12CuO4 (Tc = 21 K and 24 K) and compared them with tunneling spectrum of hole-doped La1.84Sr0.16CuO4 and effective electron-boson spectral function of hole-doped La1.97Sr0.03CuO4 (extracted from angle-resolved photoemission spectrum). We have also analyzed tunneling spectra and angle-resolved photoemission spectra for hole-doped Bi2Sr2CaCu2O8. These results unambiguously rule out magnetic pairing mechanism in both electron- and hole-doped cuprates and support polaronic/bipolaronic superconductivity in hole-d…
