A profound problem in modern condensed matter physics is discovering and understanding the nature of the fluctuations and their coupling to fermions in cuprates which lead to high temperature superconductivity and the invariably associated strange metal state. Here we report the quantitative determination of the normal and pairing self-energies, made possible by laser-based angle-resolved photoemission measurements with unprecedented accuracy and stability. Through a precise inversion procedure, both the effective interactions in the attractive d-wave symmetry and the repulsive part in the full symmetry are determined. The latter are nearly angle independent. Near Tc both interactions are nearly independent of frequency, and have almost the same magnitude, over the complete energy range of up to about 0.4 eV except for a low energy feature around 50 meV present only in the repulsive part which has less than 10% of the total spectral weight. Well below Tc, they both change similarly by superconductivity induced features at low energies. Besides finding the pairing self-energy and the attractive interactions for the first time, these results expose a central paradox of the high Tc problem: how the same frequency independent fluctuations can dominantly scatter at angles +-pi/2 in the attractive channel as well as lead to angle-independent repulsive scattering. The experimental results are compared with the available theoretical calculations based on antiferromagnetic fluctuations, Hubbard model and the quantum-critical fluctuations of loop-current order.
The disclosure of spinon superconductivity and superconductivity mediated by spin-waves in hole-doped Bi2212 cuprate raises the question about the origin of the superconductivity in other cuprates and specially in an electron-doped NCCO cuprate.
We discuss the evolution of high-order Van Hove singularities (hoVHSs) that carry faster-than logarithmic divergences over a wide range of parameters in cuprate-like electronic band dispersions. Numerical analysis gives insight into the quantization of the VHS power-law-exponent pV and into transitions between hoVHSs with different values of pV. The cuprates are found to lie in the parameter regime where the amplitude of the hoVHS is not too large. Our study indicates that the occurrence of high-temperature superconductivity requires simultaneous tuning of two different competing orders (antif…
In this Letter, we develop a microscopic theory to describe the close proximity between the insulating antiferromagnetic (AF) order and the d-wave superconducting (dSC) order in cuprates. We show that the cuprate ground states form a configuration of coherent pairing states consisting of extended singlet Cooper pairs and triplet $π$ pairs, which can simultaneously describe AF and dSC orders.
There is a clear discrepancy among the energy-gap values for different 90 K cuprates, inferred from tunneling measurements. By using the phase diagram for hole-doped cuprates we show that tunneling measurements performed on 90 K cuprates, simply, detect two different energy gaps: the pairing gap and the coherent gap, which are identical in conventional superconductors. We find that there are two reasons why tunneling measurements show in one cuprate exclusively the coherent gap while, in another cuprate, they show the pairing gap: (i) the number of CuO2 planes per unit cell in the cuprate, and…
The symmetries of the order parameter (OP) responsible for pairing and the OP responsible for phase coherence in hole-doped cuprates are discussed. We analyze angle-resolved tunneling, ARPES, Raman scattering and torque measurements performed on hole-doped cuprates. We conclude that, most likely, the OP responsible for phase coherence has the d-wave symmetry whereas the OP responsible for pairing has an anisotropic s-wave symmetry.
The asymmetry between electron and hole doping remains one of the central issues in high-temperature cuprate superconductivity, but our understanding of the electron-doped cuprates has been hampered by apparent discrepancies between the only two known families: Re2-xCexCuO4 and A1-xLaxCuO2. Here we report in situ angle-resolved photoemission spectroscopy measurements of epitaxially-stabilized films of Sr1-xLaxCuO2 synthesized by oxide molecular-beam epitaxy. Our results reveal a strong coupling between electrons and (pi,pi) antiferromagnetism that induces a Fermi surface reconstruction which p…
The symmetries and origins of the order parameters (OPs) for pairing and long-range phase coherence in hole-doped cuprates are discussed. By analyzing tunneling, inelastic neutron scattering and torque measurements we conclude that the Cooper pairs in cuprates consist of spinons, and the pairing OP has an anisotropic s-wave symmetry, whereas the OP for long-range phase coherence has the magnetic origin due to spin fluctuations and, has the d-wave symmetry. All conclusions are based exclusively on experimental facts.
The possibility of kinetic energy driven superconductivity in cuprates as was recently found in the $tJ$ model is discussed. We argue that the violation of the virial theorem implied by this result is serious and means that the description of superconductivity within the $tJ$ model is pathological.
Pairing Correlations are studied numerically in the hole-doped spin-fermion model for cuprates. Simulations performed on up to 12x12 clusters provide robust indications of D-wave superconductivity away from half-filling. The pairing correlations are the strongest in the direction perpendicular to the dynamic stripe-like inhomogeneities that appear in the ground state at some densities. An optimal doping, where the correlations reach a maximum value, was observed at about 25% doping, in qualitative agreement with hight T_{c} cuprates' experiments. On the other hand, pairing correlations are sup…
Kinematic constraint arising in the case of superconducting pairing with large momentum results in a cutoff of the screened Coulomb potential excluding large momentum transfers. This leads to a pairing potential oscillating in the real space that ensures a rise of bound singlet pairs. In multilayer cuprates, there is strong Coulomb interaction between particles composing the pair not only in the same cuprate layer but in the neighboring layers as well. In the framework of such a scenario, we explain a universal dependence of the superconducting transition temperature on the number of layers in…
We compare the one-loop functional renormalization group results for the cuprates and the iron pnictides. Interestingly a coherent picture suggesting that antiferromagnetic correlation causes pairing for both materials emerges.
One of the central questions in the cuprate research is the nature of the "normal state" which develops into high temperature superconductivity (HTSC). In the normal state of hole-doped cuprates, the existence of charge density wave (CDW) is expected to shed light on the mechanism of HTSC. With evidence emerging for CDW order in the electron-doped cuprates, the CDW would be thought to be a universal phenomenon in high-$T_c$ cuprates. However, the CDW phenomena in electron-doped cuprate are quite different than those in hole-doped cuprates. Here we study the nature of the putative CDW in an ele…
Tunneling and inelastic neutron scattering (INS) measurements in cuprates are discussed. There is a clear discrepancy among energy-gap values for different 90 K cuprates, inferred from tunneling measurements. By using the phase diagram of hole-doped cuprates we interpret tunneling measurements in 90 K cuprates and INS data in YBCO.
Effective models are constructed for a newly discovered superconductor (Nd,Sr)NiO2, which has been considered as a possible nickelate analogue of the cuprates owing to the d9 electron configuration. Estimation of the effective interaction, which turns out to require a multiorbital model that takes account of all the orbitals involved on the Fermi surface, shows that the effective interactions are significantly larger than in the cuprates. A fluctuation exchange study for the model indicates that dx2-y2-wave superconductivity is likely to occur as in the cuprates, where the transition temperatu…
We utilize a 1d Hubbard model to show that the superconductivity in cuprate superconductors likely arises due to the orbital entanglement between holes in the copper oxide plane mediated by orbitally-selective charge hopping. The main role of doping required to achieve superconductivity in cuprates is to suppress the Mott correlations and orbital ordering. The proposed mechanism explains superconductivity in other unconventional superconductors, and provides guidance in the search for new high-temperature superconductors.
Recent experiments on Bi-based cuprate superconductors have revealed an unexpected enhancement of the pairing correlations near the interstitial oxygen dopant ions. Here we propose a possible mechanism -- based on local screening effects -- by which the oxygen dopants do modify the electronic parameters within the CuO_2 planes and strongly increase the superexchange coupling J. This enhances the spin pairing effects locally and may explain the observed spatial variations of the density of states and the pairing gap.
A fundamental connection between superconductivity and quantum spin fluctuations in underdoped cuprates, is revealed. A variational calculation shows that {\em Cooper pair hopping} strongly reduces the local magnetization $m_0$. This effect pertains to recent neutron scattering and muon spin rotation measurements in which $m_0$ varies weakly with hole doping in the poorly conducting regime, but drops precipitously above the onset of superconductivity.
We report a scaling relation between $ρ_s(0)$ and the product of the pseudogap temperature $T^{*}$, $σ_{\rm DC}$ and $T_c$, with $T^{*}$ rescaled by the maximum transition temperature $T_c^{\max}$, which holds universally in the entire doping range for the hole-doped cuprates.
Beyond the conventional Emery model: crucial role of long-range hopping for cuprate superconductivity
TU Wien（维也纳工业大学）；Max-Planck-Institut für Festkörperforschung（马克斯·普朗克固体研究所）；Northwest University（西北大学）；Friedrich-Alexander-Universität Erlangen/Nürnberg（埃尔朗根-纽伦堡大学）；University of Iceland（冰岛大学）；Università di Trieste（的里雅斯特大学）
The phase diagram of order parameters for pairing and phase coherence in hole-doped cuprates is discussed. By examining carefully some recent inelastic neutron scattering data obtained on hole-doped cuprates and heavy fermion compound UPd2Al3 in which the superconductivity is mediated by spin fluctuations, we conclude that the coherent gap in hole-doped cuprates has most likely the magnetic origin and scales with Tc, on average, as 2Dc/kBTc = 5.4. We discuss a model of the superconductivity in hole-doped cuprates and the symmetries of two order parameters.
The relevance of magnetism for the mechanism responsible for high-temperature superconductivity remains an open and still interesting issue. The observation by inelastic neutron scattering of strong antiferromagnetic dynamical correlations in superconducting cuprates is discussed in relation to the unusual physical properties of the cuprates as well as in relation to the superconducting pairing.
The real-space localized hole pair is constructed in the Cu-O plane of the hole-doped cuprate superconductors. We prove analytically and numerically that two electrons, due to the nearest-neighbor Coulomb repulsive confinement effect, can be in pairing inside a single plaquette with the d-wave symmetry. The scenario supports the `no glue' pairing picture for the cuprates. Based on the scenarios, the physical origin of the Fermi pocket (or Fermi arc) and the two pseudogap behavior are provided. Our framework leads directly to a unified linear relationship between the pseudogap temperature T* an…
We utilize the Hubbard model to demonstrate that doping of the antiferromagnetic parent compounds of cuprate superconductors stabilizes a spin liquid state. Superconductivity in such a state emerges due to the spin-orbit coupling between charge current and superfluidity of spinon condensate, resulting in a chiral relation between the order parameter phase gradient and supercurrent. We propose simple experimental tests for the presented mechanism.
Giant and nil proximity effects and unconventional symmetry of cuprate superconductors are explained as a result of the strong Froehlich interaction of holes with c-axis polarised optical phonons acting together with an anisotropic nonlocal deformation potential.
A comparison of pairing properties in cuprates and nuclear matter is briefly discussed. Quartet (alpha-particle) condensation is a very important aspect of nuclear physics. The physics of the Hoyle state in 12 C will be outlined and its crucial role for the existence of life on earth explained.
Within the t-t'-J model, the charge asymmetry in superconductivity of hole- and electron-doped cuprates is studied based on the kinetic energy driven superconducting mechanism. It is shown that superconductivity appears over a narrow range of doping in electron-doped cuprates, and the superconducting transition temperature displays the same kind of the doping controlled behavior that is observed in the hole-doped case. However, the maximum achievable superconducting transition temperature in the optimal doping in electron-doped cuprates is much lower than that of the hole-doped case due to the…
Scanning tunneling spectroscopy has recently discovered a positive correlation between the magnitude of the superconducting gap and positions of dopant oxygen atoms in Bi-based cuprates. We propose a microscopic mechanism that could be responsible for this effect. In particular, we demonstrate that the dopant-induced spatial variation of the atomic levels always enhances the superexchange interaction.
We present experimental data obtained by different techniques. Some of them are not easy to explain by any theoretical model presented in the literature. However, a MCS model of the superconductivity in hole-doped cuprates, proposed in our previous work, is capable to explain them. Thus, we present an evidence in favor of the MCS model.
On the basis of an analysis of theoretical and numerical studies of model systems, and of experiments on superconductivity in doped C$_{60}$, polyacenes, and the cuprate high temperature superconductors, we propose that a purely electronic mechanism of superconductivity requires structures at an intermediate or mesoscale. Specifically, we address the crucial question of how high temperature superconducting pairing on the mesoscale can arise from purely repulsive electronic interactions.
A simple microscopic principle of `Valence bond (nearest neighbor singlet) amplitude maximization '(VBAM) is shown to be present in undoped and optimally doped cuprates and unify the very different orderings such as antiferromagnetism in the Mott insulator and the robust superconductivity accompanied by an enhanced charge and stripe correlations in the optimally doped cuprates. VBAM is nearly synonymous with the energy minimization principle. It is implicit in the RVB theory and thereby makes the predictions of RVB mean field theory of superconductivity qualitatively correct.
The main purpose of this brief review is to present a sketch of the mechanism of high-Tc superconductivity based mainly on tunneling measurements in cuprates. In the review, we shall mostly discuss tunneling spectroscopy in Bi2212. Analysis of the data shows that the Cooper pairs in cuprates are topological excitations (e.g. quasi-one dimensional bisolitons, discrete breathers etc.), and the phase coherence among the Cooper pairs appears due to spin fluctuations.
Recently, scanning tunneling microscopy on Bi-2212 cuprate superconductor has revealed a spatial variation of the energy gap that is directly correlated with a modulation of the apical oxygen position. We identify two mechanisms by which out-of-plane oxygens can modulate the pairing interaction within the CuO_2 layer: a covalency between the x^2-y^2 band and apical p-orbital, and a screening of correlation U by apical oxygen polarization. Both effects strongly depend on the apical oxygen position and their cooperative action explains the experiment.
We have computed alpha^2F's for the hole-doped cuprates within the framework of the one-band Hubbard model, where the full magnetic response of the system is treated properly. The d-wave pairing weight alpha^2F_d is found to contain not only a low energy peak due to excitations near (pi,pi) expected from neutron scattering data, but to also display substantial spectral weight at higher energies due to contributions from other parts of the Brillouin zone as well as pairbreaking ferromagnetic excitations at low energies. The resulting solutions of the Eliashberg equations yield transition temper…
Superconductivity originates from the coupling between charge carriers and bosonic excitations of either phononic or electronic origin. Identifying the most relevant pairing glue is a key step towards a clear understanding of the unconventional superconductivity. Here, by applying the ultrafast optical spectroscopy on the electron-doped cuprates La$_{1.9}$Ce$_{0.1}$CuO$_{4\pmδ}$, we discern a bosonic mode of electronic origin that has the strongest coupling with the charge carriers near $T_c$. We argue that this mode is associated with the two-dimensional antiferromagnetic spin fluctuations, a…
It is found that the carriers of the high-T_c cuprates are polaron-like "stripons" carrying charge and located in stripe-like inhomogeneities, "quasi-electrons" carrying charge and spin, and "svivons" carrying spin and lattice distortion. This is shown to result in the observed anomalous spectroscopic properties of the cuprates. The AF/stripe-like inhomogeneities result from the Bose condensation of the svivon field, and the speed of their dynamics is determined by the width of the double-svivon neutron-resonance peak. Pairing results from transitions between pair states of stripons and quasi-…
Within the kinetic energy driven superconducting mechanism, the effect of the pressure on superconductivity in doped two-leg ladder cuprates is studied. It is shown that the superconducting transition temperature in doped two-leg ladder cuprate superconductors increases with increasing pressure in the underpressure regime, and reaches a maximum in the optimal pressure, then decreases in the overpressure regime. This domed shape of the pressure dependence of the superconducting transition temperature is similar to that of the pressure dependence of the longitudinal part of the superconducting g…
The nature of the effective interaction responsible for pairing in the high-temperature superconducting cuprates remains unsettled. This question has been studied extensively using the simplified single-band Hubbard model, which does not explicitly consider the orbital degrees of freedom of the relevant CuO$_2$ planes. Here, we use a dynamic cluster quantum Monte Carlo approximation to study the orbital structure of the pairing interaction in the three-band Hubbard model, which treats the orbital degrees of freedom explicitly. We find that the interaction predominately acts between neighboring…
Superconducting transition temperature is calculated for differently doped bilayer cuprates. Superexchange is assumed to be the dominating mechanism of high-temperature superconductivity, but the contribution from the phonon potential is not negligible, which qualitatively explains the observed weak isotopic effect. The calculated value 2$Δ_{max}/k_B T_C \simeq 4.5$ is close to the experiment in the case of optimum doping.
A more extended low density region of coexisting uniform antiferromagnetism and d-wave superconductivity has been reported in multilayer cuprates, when compared to single or bilayer cuprates. This coexistence could be due to the enhanced screening of random potential modulations in inner layers or to the interlayer Heisenberg and Josephson couplings. A theoretical analysis using a renormalized mean field theory, favors the former explanation. The potential for an improved determination of the antiferromagnetic and superconducting order parameters in an ideal single layer from zero field NMR an…
Within the t-J ladder model, superconductivity with a modified d-wave symmetry in doped two-leg ladder cuprates is investigated based on the kinetic energy driven superconducting mechanism. It is shown that the spin-liquid ground-state at the half-filling evolves into the superconducting ground-state upon doping. In analogy to the doping dependence of the superconducting transition temperature in the planar cuprate superconductors, the superconducting transition temperature in doped two-leg ladder cuprates increases with increasing doping in the underdoped regime, and reaches a maximum in the …
The normal and pairing self-energies are the microscopic quantities which reflect and characterize the underlying interaction in superconductors. The momentum and frequency dependence of the self-energies, therefore, provides the experimental criteria which can single out the long sought-after pairing interaction among many proposed ideas. This line of research to pin down the pairing interaction for the cuprate superconductors has been carried out with some success by analyzing the momentum distribution curves of laser angle-resolved photo-emission spectroscopy (ARPES) data. Some progress and…
The theory of hole superconductivity proposes that MgB_2, and the high Tc cuprates, and the 'conventional superconductors', and all other superconductors, are driven by the same physical mechanism, which is not the electron-phonon interaction. That mechanism, hole undressing, evidence supporting it, and predictions for MgB_2, are briefly reviewed.
A grand challenge in many-body quantum physics is to explain the apparent connection between quantum criticality and high-temperature superconductivity in the cuprates and similar systems, such as the iron pnictides and chalcogenides. Here we argue that the quantum-critical regime plays an essential role in activating a strong-pairing mechanism: although pairing bosons create a symmetry-breaking instability which suppresses pairing, the combination of these broken-symmetry states within the critical regime can restore this symmetry for the paired quasiparticles. This condition is shown to be m…
A strategy to enhance d-wave superconducting correlations is proposed based on our numerical study for correlated electron models for high-Tc cuprates. We observe that the pairing is enhanced when the single-electron level around (pi,0) is close to the Fermi level E_F, while the d-wave pairing interaction itself contains elements to disfavor the pairing due to shift of the (pi,0)-level. Angle-resolved photoemission results in the cuprates are consistently explained in the presence of the d-wave pairing interaction. Our proposal is the tuning of the (pi,0)-level under the many-body effects to E…
We make use of the S=1 pseudospin formalism to describe the charge degree of freedom in a model high-$T_c$ cuprate with the on-site Hilbert space reduced to the three effective valence centers, nominally Cu$^{1+,\,2+,\,3+}$. Starting with a parent cuprate as an analogue of the quantum paramagnet ground state and using the Schwinger boson technique we found the pseudospin spectrum and conditions for the pseudomagnon condensation with phase transition to a superconducting state.
We consider the evolution of d-wave pairing, mediated by nearly critical spin fluctuations, with the coupling strength. We show that the onset temperature for pairing, T*, smoothly evolves between weak and strong coupling, passing through a broad maximum at intermediate coupling. At strong coupling, T* is of order the magnetic exchange energy J. We argue that for all couplings, pairing is confined to the vicinity of the Fermi surface. We also find that thermal spin fluctuations only modestly reduce T*, even at criticality, but they substantially smooth the gap anisotropy. The latter evolves wi…
There is a multiplicity of charge ordered, pairing-based or pair density wave theories of the cuprate pseudogap, albeit arising from different microscopic mechanisms. For mean field schemes (of which there are many) we demonstrate here that they have precise implications for two body physics in the same way that they are able to address the one body physics of photoemission spectroscopy. This follows because the full vertex can be obtained exactly from the Ward-Takahashi identity. As an illustration, we present the spin response functions, finding that a recently proposed pair density wave (Am…
The nature of the normal state and the mechanism of superconductivity in two families of high-temperature superconductors, cuprates and pnictides, remain a matter of intense discussions. According to band-structure calculations, confirmed by ARPES data, the electronic structure of pnictides differs considerably from that of cuprates. However, in spite of these differences, it looks like in both cases there exists some general and fairly "coarse" mechanism independent of fine details of the band structure and responsible for superconductive pairing in these materials. Here, we suggest a qualita…
We report a tunneling study between Pr_2-xCe_xCuO_{4-delta} (PCCO) and Lead as a function of doping, temperature and magnetic field. The temperature dependence of the gap follows the BCS prediction. Our data fits a nonmonotonic d-wave order parameter for the whole doping range studied. From our data we are able to conclude that the electron-doped cuprate PCCO is a weak coupling, BCS, dirty superconductor.
We develop Ginzburg-Landau approach to the problem of superconducting pairing with large momentum under screened Coulomb repulsion (eta_K-pairing). Two-component order parameter arising in this scheme can be associated with charge and orbital current degrees of freedom of the relative motion of eta_K-pair corresponding to superconducting and orbital antiferromagnetic ordered states, respectively. All basic features of the phase diagram of cuprate superconductors result directly from the eta_K-pairing concept.
Recent experiments in the cuprates have seen evidence of a transient superconducting state upon optical excitation polarized along the c-axis [R. Mankowsky et al., Nature 516, 71 (2014)]. Motivated by these experiments we propose an extension of the single-layer $t-J-V$ model of cuprates to three dimensions in order to study the effects of inter-plane tunneling on the competition between superconductivity and bond density wave order. We find that an optical pump can suppress the charge order and simultaneously enhance superconductivity, due to the inherent competition between the two. We also …
We study the three-band Hubbard model for the copper oxide plane of the high-temperature superconducting cuprates using determinant quantum Monte Carlo and the dynamical cluster approximation (DCA) and provide a comprehensive view of the pairing correlations in this model using these methods. Specifically, we compute the pair-field susceptibility and study its dependence on temperature, doping, interaction strength, and charge-transfer energy. Using the DCA, we also solve the Bethe-Salpeter equation for the two-particle Green's function in the particle-particle channel to determine the transit…
The properties of the superconducting ferromagnets RuSr2(Gd/Eu)Cu2O8 and RuSr2(Ln/Ce)2Cu2O10 are reviewed. The problem of coexistence and competition between magnetic and superconducting states is discussed. A model of phase separation into ferromagnetic and anti-ferromagnetic structures is proposed.
We apply the spin-fermion model to study the normal state and pairing instability in electron-doped cuprates near the antiferromagnetic QCP. Peculiar frequency dependencies of the normal state properties are shown to emerge from the self-consistent equations on the fermionic and bosonic self-energies, and are in agreement with experimentally observed ones. We argue that the pairing instability is in the $d_{x^{2}-y^{2}}$ channel, as in hole-doped cuprates, but theoretical $T_{c}$ is much lower than in the hole-doped case. For the same hopping integrals and the interaction strength as in hole-d…
The issues of single particle coherence and its interplay with singlet pairing are studied within the slave boson gauge theory of a doped Mott insulator. Prior work by one of us (T. Senthil, arXiv:0804.1555) showed that the coherence scale below which Landau quasiparticles emerge is parametrically lower than that identified in the slave boson mean field theory. Here we study the resulting new non-fermi liquid intermediate temperature regime characterized by a single particle scattering rate that is linear in temperature ($T$). In the presence of a d-wave pair amplitude this leads to a pseudoga…
A microscopic theory of superconductivity is formulated within an effective $p$-$d$ Hubbard model for a CuO2 plane. By applying the Mori-type projection technique, the Dyson equation is derived for the Green functions in terms of Hubbard operators. The antiferromagnetic exchange caused by interband hopping results in pairing of all carries in the conduction subband and high Tc proportional to the Fermi energy. Kinematic interaction in intraband hopping is responsible for the conventional spin-fluctuation pairing. Numerical solution of the gap equation proves the d-wave gap symmetry and defines…
The theory of hole superconductivity explains high temperature superconductivity in cuprates as driven by pairing of hole carriers in oxygen $pπ$ orbitals in the highly negatively charged $Cu-O$ planes. The pairing mechanism is hole undressing and is Coulomb-interaction driven. We propose that the planes of $B$ atoms in $Mg B_2$ are akin to the $Cu-O$ planes without $Cu$, and that the recently observed high temperature superconductivity in $Mg B_2$ arises similarly from undressing of hole carriers in the planar boron $p_{x,y}$ orbitals in the negatively charged $B^-$ planes. Doping $Mg B_2$ wi…
