We calibrate the integrated luminosity from the polycyclic aromatic hydrocarbon (PAH) features at 6.2\micron, 7.7\micron\ and 11.3\micron\ in galaxies as a measure of the star-formation rate (SFR). These features are strong (containing as much as 5-10\% of the total infrared luminosity) and suffer minimal extinction. Our calibration uses \spitzer\ Infrared Spectrograph (IRS) measurements of 105 galaxies at $0 < z < 0.4$, infrared (IR) luminosities of $10^9 - 10^{12} \lsol$, combined with other well-calibrated SFR indicators. The PAH luminosity correlates linearly with the SFR as measured by the extinction-corrected \ha\ luminosity over the range of luminosities in our calibration sample. The scatter is 0.14 dex comparable to that between SFRs derived from the \paa\ and extinction-corrected \ha\ emission lines, implying the PAH features may be as accurate a SFR indicator as hydrogen recombination lines. The PAH SFR relation depends on gas-phase metallicity, for which we supply an empirical correction for galaxies with $0.2 < \mathrm{Z} \lsim 0.7$~\zsol. We present a case study in advance of the \textit{James Webb Space Telescope} (\jwst), which will be capable of measuring SFRs from PAHs in distant galaxies at the peak of the SFR density in the universe ($z\sim2$) with SFRs as low as $\sim$~10~\sfrunits. We use \spitzer/IRS observations of the PAH features and \paa\ emission plus \ha\ measurements in lensed star-forming galaxies at $1 < z < 3$ to demonstrate the ability of the PAHs to derive accurate SFRs. We also demonstrate that because the PAH features dominate the mid-IR fluxes, broad-band mid-IR photometric measurements from \jwst\ will trace both the SFR and provide a way to exclude galaxies dominated by an AGN.
Ubiquitous unidentified infrared emission bands are seen in many astronomical sources. Although these bands are widely, if not unanimously, attributed to the collective emission from polycyclic aromatic hydrocarbons, no single species from this class has been detected in space. We present the discovery of two -CN functionalized polycyclic aromatic hydrocarbons, 1- and 2-cyanonaphthalene, in the interstellar medium aided by spectral matched filtering. Using radio observations with the Green Bank Telescope, we observe both bi-cyclic ring molecules in the molecular cloud TMC-1. We discuss potenti…
Polycyclic Aromatic Hydrocarbons (PAHs) have long been invoked in the study of interstellar and protostellar sources, but the unambiguous identification of any individual PAH has proven elusive until very recently. As a result, the formation mechanisms for this important class of molecules remain poorly constrained. Here we report the first interstellar detection of a pure hydrocarbon PAH, indene (C$_9$H$_8$), as part of the GBT Observations of TMC-1: Hunting for Aromatic Molecules (GOTHAM) survey. This detection provides a new avenue for chemical inquiry, complementing the existing detections…
Polycyclic aromatic hydrocarbon (PAH) emission has long been proposed to be a potential star formation rate indicator, as it arises from the photodissociation region bordering the Strömgren sphere of young, massive stars. We apply a recently developed technique of mid-infrared spectral decomposition to obtain a uniform set of PAH measurements from Spitzer low-resolution spectra of a large sample of star-forming galaxies spanning a wide range in stellar mass ($M_\star \approx 10^6-10^{11.4}\,M_{\odot}$) and star formation rate ($\sim 0.1- 2000\,M_{\odot}\rm\,yr^{-1}$). High-resolution spectra a…
Using new large area maps of the cold neutral medium (CNM) fraction, $f_{\rm CNM}$, we investigate the relationship between the CNM, the abundance of polycyclic aromatic hydrocarbons (PAHs), and the anomalous microwave emission (AME). We first present our $f_{\rm CNM}$ map based on full-sky HI4PI data, using a convolutional neural network to covert the spectroscopic HI data to $f_{\rm CNM}$. We demonstrate that $f_{\rm CNM}$ is strongly correlated with the fraction of dust in PAHs as estimated from mid- and far-infrared dust emission. In contrast, we find no correlation between $f_{\rm CNM}$ a…
We carried out a principal component analysis (PCA) of the fluxes of five polycyclic aromatic hydrocarbon (PAH) bands at 6.2, 7.7, 8.6, 11.0, and 11.2 $μ$m in the reflection nebula NGC 7023 comprising of the photodissociation region (PDR) and a cavity. We find that only two principal components (PCs) are required to explain the majority of the observed variance in PAH fluxes (98 %). The first PC ($PC_{1}$), which is the primary driver of the variance, represents the total PAH emission. The second PC ($PC_{2}$) is related to the ionization state of PAHs across the nebula. This is consistent wit…
The cosmic-ray ionization rate ($ζ$, s$^{-1}$) plays an important role in the interstellar medium. It controls ion-molecular chemistry and provides a source of heating. Here we perform a grid of calculations using the spectral synthesis code CLOUDY along nine sightlines towards, HD 169454, HD 110432, HD 204827, $λ$ Cep, X Per, HD 73882, HD 154368, Cyg OB2 5, Cyg OB2 12. The value of $ζ$ is determined by matching the observed column densities of H$_3^+$ and H$_2$. The presence of polycyclic aromatic hydrocarbons (PAHs) affects the free electron density, which changes the H$_3^+$ density and the…
We use the measured fluxes of polycyclic aromatic hydrocarbon (PAH) emission features at 6.2, 7.7, 8.6, 11.0 and 11.2 $μ$m in the reflection nebula NGC 2023 to carry out a principal component analysis (PCA) as a means to study previously reported variations in the PAH emission. We find that almost all of the variations (99%) can be explained with just two parameters -- the first two principal components (PCs). We explore the characteristics of these PCs and show that the first PC ($PC_{1}$), which is the primary driver of the variation, represents the amount of emission of a mixture of PAHs wi…
We study the environmental dependence of the strength of polycyclic aromatic hydrocarbon (PAH) emission by AKARI observations of RX J0152.7-1357, a galaxy cluster at z=0.84. PAH emission reflects the physical conditions of galaxies and dominates 8 um luminosity (L8), which can directly be measured with the L15 band of AKARI. L8 to infrared luminosity (LIR) ratio is used as a tracer of the PAH strength. Both photometric and spectroscopic redshifts are applied to identify the cluster members. The L15-band-detected galaxies tend to reside in the outskirt of the cluster and have optically green co…
[Abridged] The ionization of polycyclic aromatic hydrocarbons (PAHs), by ultraviolet (UV) photons from massive stars is expected to account for a large fraction of the heating of neutral gas in galaxies. Evaluation of this proposal, however, has been limited by our ability to directly compare observational diagnostics to the results of a molecular model describing PAH ionization. The objective of this article is to take advantage of the most recent values of molecular parameters derived from laboratory experiments and quantum chemical calculations on PAHs and provide a detailed comparison betw…
The mid-infrared spectrum contains rich diagnostics to probe the physical properties of galaxies, among which the pervasive emission features from polycyclic aromatic hydrocarbons (PAHs) offer a promising means of estimating the star formation rate (SFR) relatively immune from dust extinction. This paper investigates the effectiveness of PAH emission as a SFR indicator on sub-kpc scales by studying the Spitzer/IRS mapping-mode observations of the nearby grand-design spiral galaxy M51. We present a new approach of analyzing the spatial elements of the spectral datacube that simultaneously maxim…
Polycyclic Aromatic Hydrocarbons (PAHs) are carbon-based molecules resulting from the union of aromatic rings and related species, which are likely responsible for strong infrared emission features (3.3, 6.2, 7.7, 8.6, 11.3 and 12.7 microns). In this work, using a sample of 50 Seyfert galaxies (DL<100 Mpc) we compare the circumnuclear (inner kpc) PAH emission of AGN to that of a control sample of star-forming galaxies (22 luminous infrared galaxies and 30 HII galaxies), and investigate the differences between central and extended PAH emission. Using Spitzer/InfraRed Spectrograph spectral data …
Supervised machine learning models are trained with various molecular descriptors to predict infrared emission spectra of interstellar polycyclic aromatic hydrocarbons. We demonstrate that a feature importance analysis based on the random forest algorithm can be utilized to explore the physical correlation between emission features. Astronomical correlations between infrared bands are analyzed as examples of demonstration by finding the common molecular fragments responsible for different bands, which improves the current understanding of the long-observed correlations. We propose a way to qua…
Polycyclic aromatic hydrocarbons (PAHs) are of great astrochemical and astrobiological interest due to their potential to form prebiotic molecules. We analyse the 7.7 and 8.6 $μ$m PAH bands in 126 predominantly starburst-dominated galaxies extracted from the Spitzer/IRS ATLAS project. Based on the peak positions of these bands, we classify them into the different A, B, and C Peeters' classes, which allows us to address the potential characteristics of the PAH emitting population. We compare this analysis with previous work focused on the 6.2 $μ$m PAH band for the same sample. For the first tim…
Variations in the 6.2 $μ$m polycyclic aromatic hydrocarbon band in Active Galactic Nuclei- and Starburst-dominated galaxies
Universidade Federal do Rio Grande（里奥格兰德联邦大学）；Leiden University（莱顿大学）；Universidade Federal do Rio Grande do Sul（南里奥格兰德联邦大学）；Universidade de São Paulo（圣保罗大学）
We have examined polycyclic aromatic hydrocarbon (PAH) excitation in a sample of 25 nearby face-on spiral galaxies using the ratio of mid-infrared PAH emission to dust mass. Within 11 of the galaxies, we found that the PAH excitation was straightforwardly linked to ultraviolet or mid-infrared star formation tracers, which, along with other results studying the relation of PAH emission to star formation, indicates that the PAHs are most strongly excited in dusty shells around the star forming regions. Within another 5 galaxies, the PAH emission is enhanced around star forming regions only at sp…
We present maps of the dust properties in the Small and Large Magellanic Clouds (SMC, LMC) from fitting Spitzer and Herschel observations with the \citet{DL07} dust model. We derive the abundance of the small carbonaceous grain (or polycyclic aromatic hydrocarbon; PAH) component. The global PAH fraction (q_pah, the fraction of the dust mass in the form of PAHs) is smaller in the SMC (1.0$^{+0.3}_{-0.3}$%) than in the LMC (3.3$^{+1.4}_{-1.3}$%). We measure the PAH fraction in different gas phases (H II regions, ionized gas outside of H II regions, molecular gas, and diffuse neutral gas). H II r…
The Influence of Aliphatic Components on the Aromatic Emission Characteristics of Polycyclic Aromatic Hydrocarbons
School of Physics and Astronomy, Sun Yat-sen University（中山大学物理学院）；CSST Science Center for the Guangdong-Hong Kong-Macau Greater Bay Area, Sun Yat-Sen University（中山大学粤港澳大湾区空间望远镜科学中心）
We extend the prediction of vibrational spectra to large sized polycyclic aromatic hydrocarbon (PAH) molecules comprising up to \sim 1500 carbon atoms by evaluating the efficiency of several computational chemistry methodologies. We employ classical mechanics methods (Amber and Gaff) with improved atomic point charges, semi-empirical (PM3, and density functional tight binding), and density functional theory (B3LYP) and conduct global optimizations and frequency calculations in order to investigate the impact of PAH size on the vibrational band positions. We primarily focus on the following mid…
This joint theoretical and experimental study establishes that the adsorption of polycyclic aromatic hydrocarbons (PAHs) onto the amorphous ice surface provokes a broadening and redshift of the "dangling" OH (dOH) ice spectral feature, the redshift increasing with PAH size up to $\sim$ 85~cm$^{-1}$. It also reveals that, in certain interaction configurations, adsorption induces substantial reorganisation of the hydrogen-bonding network at the ice surface. Comparison with experiments validates the novel theoretical methodology relying on the density functional based tight binding approach, whic…
