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arXiv 1502.06816cond-mat.str-elcond-mat.mtrl-sci
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由NbSe $_2$证明的轨道依赖耦合的电荷序

Charge Order from Orbital-dependent Coupling Evidenced by NbSe$_2$

Felix Flicker, Jasper van Wezel

摘要:

二硒化铌长期以来一直是二维电荷有序的原型,被认为是由类似于一维佩尔斯机制的电子结构的不稳定性引起的。尽管如此,各种异常的性质最近已被确定的实验不能解释的佩尔斯弱耦合理论。相反,我们考虑一个模型与强的电子-声子耦合,同时考虑到完整的动量和轨道依赖的耦合矩阵元素。我们表明,这两个是必要的一致的描述的全方位的实验观察。我们认为,NbSe $_2$是典型的在这个意义上,任何电荷有序的材料在一个以上的维度将一般由其电子-声子耦合的动量和轨道依赖性,以及它的电子结构。其结果将在许多电荷有序材料中观察到,包括铜氧化物超导体。

英文摘要:

Niobium diselenide has long served as a prototype of two-dimensional charge ordering, believed to arise from an instability of the electronic structure analogous to the one-dimensional Peierls mechanism. Despite this, various anomalous properties have recently been identified experimentally which cannot be explained by Peierls-like weak-coupling theories. We consider instead a model with strong electron-phonon coupling, taking into account both the full momentum and orbital dependence of the coupling matrix elements. We show that both are necessary for a consistent description of the full range of experimental observations. We argue that NbSe$_2$ is typical in this sense, and that any charge-ordered material in more than one dimension will generically be shaped by the momentum and orbital dependence of its electron-phonon coupling as well as its electronic structure. The consequences will be observable in many charge-ordered materials, including cuprate superconductors.

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