利用AC斯塔克效应进行手性检测的设想
Proposal for Chiral Detection by the AC Stark-Effect
摘要：
最近，两个相关的三波混频实验已被证明，使用允许的旋转跃迁产生自由感应衰减信号的振幅线性成比例的手性分子的对映体过量。在目前的工作中，提出了一个正式的五波混频实验，将利用近共振AC斯塔克位移差分分裂一个分子的R和S版本的旋转过渡，从而将允许单独测量两个对映体的密度。
英文摘要：
Recently, two related three wave mixing experiments have been demonstrated that use allowed rotational transitions to produce a free induction decay signal with an amplitude linearly proportional to the enantiomeric excess of a chiral molecule. In the present work, a formally five wave mixing experiment is proposed that will exploit near-resonant AC Stark shifts to differentially split a rotational transition of R and S versions of a molecule and thus will allow for the separate measurement of the densities of both enantiomers.
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