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arXiv 1409.6852cond-mat.mtrl-sci
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HOPG机械剥离石墨片中机械屈曲诱导的周期性扭折/条纹微结构

Mechanical buckling induced periodic kinking/stripe microstructures in mechanically peeled graphite flakes from HOPG

Manrui Ren, Ze Liu, Quan-shui Zheng, Jefferson Zhe Liu

摘要:

机械剥离是从块状石墨中分离高质量石墨烯层的广泛使用的方法。在我们最近的实验中,一些有序的微观结构,包括周期性交替的扭结和条纹,观察到在薄石墨片,机械剥离高度取向的热解石墨(HOPG)。本文提出了一个理论模型来理解这种有序的微观结构的形成,基于弹性屈曲的石墨薄片受到弯矩。从这个模型预测的条纹的宽度与我们的实验测量相当吻合。

英文摘要:

Mechanical exfoliation is a widely used method to isolate high quality graphene layers from bulk graphite. In our recent experiments, some ordered microstructures, consisting of a periodic alternation of kinks and stripes, were observed in thin graphite flakes that were mechanically peeled from highly oriented pyrolytic graphite (HOPG). A theoretical model is presented in this paper to understand the formation of such ordered microstructures, based on elastic buckling of a graphite flake being subjected to a bending moment. The width of the stripes predicted from this model agrees reasonably well with our experimental measurements.

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