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arXiv 1406.4565cond-mat.supr-con
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6 Li的高压超导phase diagram:致密锂中的反常同位素效应

High pressure superconducting phase diagram of 6Li: anomalous isotope effects in dense lithium

Anne Marie J. Schaeffer, Scott R. Temple, Jasmine K. Bishop, Shanti Deemyad

摘要:

我们报道了6Li的超导转变温度在16-26 GPa之间,这是迄今为止表现出超导性的最轻系统。通过在金刚石对顶砧单元(DAC)中的同时测量,比较了6Li的超导相图与7 Li的超导相图1、2。在21.5 GPa以下,锂表现出直接但异常大的同位素效应,而在21.5-26 GPa之间,锂表现出逆超导同位素效应。锂的超导相图对其原子质量的不寻常的依赖性提供了证据,证明量子固体效应主导了致密锂的低温性质,从而通过零点效应导致同位素的结构和/或电子性质的异常差异。

英文摘要:

We report the superconducting transition temperature of 6Li between 16-26 GPa, the lightest system to exhibit superconductivity to date. The superconducting phase diagram of 6Li is compared to that of 7Li through simultaneous measurement in a diamond anvil cell (DAC) 1, 2. Below 21.5 GPa, Li exhibits a direct, but unusually large isotope effect, while between 21.5-26 GPa, lithium shows an inverse superconducting isotope effect. The unusual dependence of the superconducting phase diagram of lithium on its atomic mass provides evidence that quantum solid effects dominate the low temperature properties of dense lithium leading to anomalous differences in the structures and/or in electronic properties of the isotopes through zero point effects.

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