Adhesive forces are capable of deforming a soft elastic object when it comes in contact with a flat rigid substrate. The contact is in stable equilibrium if the total energy of the system arising from the elastic and surface forces exhibits a minimum at a zero or at a slightly negative load. However, as the system is continually unloaded, the energy barrier decreases and it eventually disappears, thus leading to a ballistic separation of the contact. While this type of contact splitting has received wide recognition, what has not been much appreciated with these types of soft adhesion problems is that rupture of a contact can also occur at any finite sub critical load in the presence of a noise. The soft contact problems are unique in that the noise can be a-thermal, whereas the metastable and stable states of the thermodynamic potential can arise from the competition of the elastic and the inter-facial energies of the system. Analysis based on activated rate theory and simulations based on stochastic dynamics show that the contact rupture dynamics is amenable to a force and noise induced escape of a particle from a potential well that is generic to various types of colloidal and macromolecular processes. These ideas are useful in understanding the results of a recent experiment involving the noise activated rolling dynamics of a rigid sphere on a surface, where it is pinned by soft micro-fibrils.
Elastically Collective Nonlinear Langevin Equation Theory of Dynamics in Glass-Forming Liquids: Transient Localization, Thermodynamic Mapping and Cooperativity
