Discontinuous shear thickening (DST) observed in many dense athermal suspensions has proven difficult to understand and to reproduce by numerical simulation. By introducing a numerical scheme including both relevant hydrodynamic interactions and granularlike contacts, we show that contact friction is essential for having DST. Above a critical volume fraction, we observe the existence of two states: a low viscosity, contactless (hence, frictionless) state, and a high viscosity frictional shear jammed state. These two states are separated by a critical shear stress, associated with a critical shear rate where DST occurs. The shear jammed state is reminiscent of the jamming phase of granular matter. Continuous shear thickening is seen as a lower volume fraction vestige of the jamming transition.
Colloidal shear thickening presents a significant challenge because the macroscopic rheology becomes increasingly controlled by the microscopic details of short ranged particle interactions in the shear thickening regime. Our measurements here of the first normal stress difference over a wide range of particle volume fraction elucidate the relative contributions from hydrodynamic lubrication and frictional contact forces, which have been debated. At moderate volume fractions we find $N_1<0$, consistent with hydrodynamic models, however at higher volume fractions and shear stresses these models…
Aqueous and brine suspensions of corn starch show striking discontinuous shear thickening. We have found that a suspension shear-thickened throughout may remain in the jammed thickened state as the strain rate is reduced, but an unjamming front may propagate from any unjammed regions. Transient shear thickening is observed at strain rates below the thickening threshold, and above it the stress fluctuates. The jammed shear-thickened state may persist to low strain rates, with stresses resembling sliding friction and effective viscosity inversely proportional to the strain rate. At the thickenin…
Colloidal suspensions in industrial processes often exhibit shear thickening that is difficult to control actively. Here, we use piezoelectric transducers to apply acoustic perturbations to dynamically tune the suspension viscosity in the shear-thickening regime. We attribute the mechanism of dethickening to the disruption of shear-induced force chains via perturbations that are large relative to the particle roughness scale. The ease with which this technique can be adapted to various flow geometries makes it a powerful tool for actively controlling suspension flow properties and investigatin…
We develop a tensorial constitutive model for dense, shear-thickening particle suspensions subjected to time-dependent flow. Our model combines a recently proposed evolution equation for the suspension microstructure in rate-independent materials with ideas developed previously to explain the steady flow of shear-thickening ones, whereby friction proliferates among compressive contacts at large particle stresses. We apply our model to shear reversal, and find good qualitative agreement with particle-level, discrete-element simulations whose results we also present.
We study the rheological behaviour of a dense bidispersed suspension varying the relative size of the two dispersed phases. The main outcome of our analysis is that an enhanced flowability (reduced relative viscosity) of the suspension can be achieved by increasing the dispersion ratio of the phases. We explain the observed result by showing that the presence of large particles increases the packing efficiency of the suspension, leading to a reduction of the contribution of the contacts on the overall viscosity of the suspension in the shear-thickening regime, i.e. where the contacts are the d…
Shear thickening is a widespread phenomenon in suspension flow that, despite sustained study, is still the subject of much debate. The longstanding view that shear thickening is due to hydrodynamic clusters has been challenged by recent theory and simulations suggesting that contact forces dominate, not only in discontinuous, but also in continuous shear thickening. Here, we settle this dispute using shear reversal experiments on micron-sized silica and latex colloidal particles to measure directly the hydrodynamic and contact force contributions to shear thickening. We find that contact force…
To elucidate the key factor for the quantitative prediction of the shear-thickening in suspensions in viscoelastic fluids, direct numerical simulations of many-particle suspensions in a multi-mode Oldroyd-B fluid are performed using the smoothed profile method. Suspension flow under simple shear flow is solved under periodic boundary conditions by using Lees--Edwards boundary conditions for particle dynamics and a time-dependent oblique coordinate system that evolves with mean shear flow for fluid dynamics. Semi-dilute many-particle suspensions up to a particle volume fraction of 0.1 are inves…
Dynamic particle-scale numerical simulations are used to show that the shear thickening observed in dense colloidal, or Brownian, suspensions is of a similar nature to that observed in non-colloidal suspensions, i.e., a stress-induced transition from a flow of lubricated near-contacting particles to a flow of a frictionally contacting network of particles. Abrupt (or discontinuous) shear thickening is found to be a geometric rather than hydrodynamic phenomenon; it stems from the strong sensitivity of the jamming volume fraction to the nature of contact forces between suspended particles. The t…
Particles suspended in a Newtonian fluid raise the viscosity and also generally give rise to a shear-rate dependent rheology. In particular, pronounced shear thickening may be observed at large solid volume fractions. In a recent article (R. Seto, R. Mari, J. F. Morris, and M. M. Denn., Phys. Rev. Lett., 111:218301, 2013) we have considered the minimum set of components to reproduce the experimentally observed shear thickening behavior, including Discontinuous Shear Thickening (DST). We have found frictional contact forces to be essential, and were able to reproduce the experimental behavior b…
We extend a recent theory for the rheology of frictionless granular materials [K. Suzuki and H. Hayakawa, Phys. Rev. Lett. 2015, 115, 098001] to the case of frictional disks in two dimensions. Employing a frictional contact model for molecular dynamics simulations, we derive difference equations of the shear stress, the granular temperature, and the spin temperature from the generalized Green-Kubo formula, where all the terms are given by microscopic expressions. The numerical solutions of the difference equations not only describe the flow curve, but also reproduce the hysteresis of shear str…
It has recently been argued that steady-state vorticity bands cannot arise in shear thickening suspensions, because the normal stress imbalance across the interface between the bands will set up particle migrations. In this Letter, we develop a simple continuum model that couples shear thickening to particle migration. We show by linear stability analysis that homogeneous flow is unstable towards vorticity banding, as expected, in the regime of negative constitutive slope. In full nonlinear computations, we show however that the resulting vorticity bands are unsteady, with spatiotemporal patte…
Dense suspensions are non-Newtonian fluids which exhibit strong shear thickening and normal stress differences. Using numerical simulation of extensional and shear flows, we investigate how rheological properties are determined by the microstructure which is built under flows and by the interactions between particles. By imposing extensional and shear flows, we can assess the degree of flow-type dependence in regimes below and above thickening. Even when the flow-type dependence is hindered, nondissipative responses, such as normal stress differences, are present and characterise the non-Newto…
We experimentally investigate the rheology and stress fluctuations of granules densely suspended in silicone oil. We find that both thickening strength and stress fluctuations significantly weaken with oil viscosity $η_0$. Comparison of our rheological results to the Wyart-Cates model for describing different dynamic jamming states suggests a transition from frictional contacts to lubrication interactions as $η_0$ increases. To clarify the contribution from viscous interactions to the rheology, we systematically measure stress fluctuations in various flow states. Reduction of stress fluctuatio…
Particle-based simulations of discontinuous shear thickening (DST) and shear jamming (SJ) suspensions are used to study the role of stress-activated constraints, with an emphasis on resistance to gear-like rolling. Rolling friction decreases the volume fraction required for DST and SJ, in quantitative agreement with real-life suspensions with adhesive surface chemistries and "rough" particle shapes. It sets a distinct structure of the frictional force network compared to only sliding friction, and from a dynamical perspective leads to an increase in the velocity correlation length, in part res…
We experimentally and theoretically study impacts into dense cornstarch and water suspensions. We vary impact speed as well as intruder size, shape, and mass, and we characterize the resulting dynamics using high-speed video and an onboard accelerometer. We numerically solve previously proposed models, most notably the added-mass model as well as a class of {viscous-like} models. In the {viscous-like models}, the intruder dynamics are dominated by {large, viscous-like forces} at the boundary of the jammed front {where large shear rates and accompanying large viscosities are present.} We find t…
A model of shear thickening in dense suspensions of Brownian soft sphere colloidal particles is established. It suggests that shear thickening in soft sphere suspensions can be interpreted as a shear induced phase transition. Based on a Landau model of the coagulation transition of stabilized colloidal particles, taking the coupling between order parameter fluctuations and the local strain-field into account, the model suggests the occurrence of clusters of coagulated particles (subcritical bubbles) by applying a continuous shear perturbation.The critical shear stress of shear thickening in so…
Shear thickening appears as an increase of the viscosity of a dense suspension with the shear rate, sometimes sudden and violent at high volume fraction. Its origin for noncolloidal suspension with non-negligible inertial effects is still debated. Here we consider a simple shear flow and demonstrate that fluid inertia causes a strong microstructure anisotropy that results in the formation of a shadow region with no relative flux of particles. We show that shear thickening at finite inertia can be explained as an increase of the effective volume fraction when considering the dynamically exclude…
We study the rheological behavior of concentrated granular suspensions of simple spherical particles. Under controlled stress, the system exhibits an S-shaped flow curve (stress vs. shear rate) with a negative slope in between the low-viscosity Newtonian regime and the shear thickened regime. Under controlled shear rate, a discontinuous transition between the two states is observed. Stress visualization experiments with a novel fluorescent probe suggest that friction is at the origin of shear thickening. Stress visualization shows that the stress in the system remains homogeneous (no shear ban…
In a recent Nature Materials article, Brown et al. reported a generality of shear thickening in dense suspensions and demonstrated that shear thickening can be masked by a yield stress and can be recovered when the yield stress is decreased to below a threshold. However, the generality of the shear thickening reported in the article may not be necessary true when a high electric/magnetic field is applied on an ER/MR fluid. Shear thickening of ER fluid and MR fluid under high electric/magnetic fields at low shear rates, indicating an obvious phase change inside the dense suspensions has been ob…
Dense suspensions that exhibit discontinuous shear thickening (DST) undergo complex stress relaxation when the flow abruptly stops. Using rotational rheometry, we study the two-step relaxation of aqueous cornstarch suspensions out of the DST state upon flow cessation and show that the DST fluid retains the memory of its shear-thickening state until the shear stress reaches a constant value at late times. We find that this residual stress at the end of the relaxation increases with the steady-state viscosity before the cessation. Furthermore, the timescales that characterize the two-step expone…
We investigate previously unclarified effects of fluid elasticity on shear-thickening in dilute suspensions in an Oldroyd-B viscoelastic fluid using a novel direct numerical simulation based on the smoothed profile method. Fluid elasticity is determined by the Weissenberg number Wi and by viscosity ratio $1-β=η_p/(η_s+η_p)$ which measures the coupling between the polymer stress and flow: $η_p$ and $η_s$ are the polymer and solvent viscosity, respectively.As $1-β$ increases, while the stresslet does not change significantly compared to that in the $β\to 1$ limit, the growth rate of the normaliz…
We experimentally investigate shear thickening in dense granular suspensions under oscillatory shear. Directly imaging the suspension-air interface, we observe dilation beyond a critical strain $γ_c$ and the end of shear thickening as the maximum confining stress is reached and the contact line moves. Analyzing the shear profile, we extract the viscosity contributions due to hydrodynamics $η_μ$, dilation $η_c$ and sedimentation $η_g$. While $η_g$ governs the shear thinning regime, $η_μ$ and $η_c$ together determine the shear thickening behavior. As the suspending liquid's viscosity varies from…
We report on rheometry measurements to characterize critical behavior in two model shear thickening suspensions: cornstarch in water and glass spheres in oil. The slope of the shear thickening part of the viscosity curve is found to increase dramatically with packing fraction and diverge at a critical packing fraction phi_c. The magnitude of the viscosity and the yield stress are also found to have scalings that diverge at phi_c. We observe shear thickening as long as the yield stress is less than the stress at the viscosity maximum. Above this point the suspensions transition to purely shear …
The discontinuous shear thickening (DST) of dense suspensions is a remarkable phenomenon in which the viscosity can increase by several orders of magnitude at a critical shear rate. It has the appearance of a first order phase transition between two hypothetical "states" that we have recently identified as Stokes flows with lubricated or frictional contacts, respectively. Here we extend the analogy further by means of novel stress-controlled simulations and show the existence of a non-monotonic steady-state flow curve analogous to a non-monotonic equation of state. While we associate DST with …
Shear thickening of particle suspensions is characterized by a transition between lubricated and frictional contacts between the particles. Using 3D numerical simulations, we study how the inter-particle friction coefficient influences the effective macroscopic friction coefficient and hence the microstructure and rheology of dense shear thickening suspensions. We propose expressions for effective friction coefficient in terms of distance to jamming for varying shear stresses and particle friction coefficient values. We find effective friction coefficient to be rather insensitive to interparti…
There is now convincing evidence that inter-particle frictional contacts are essential for observing shear-thickening in concentrated suspensions of compact particles. While this has inspired many strategies to tailor the rheology in these systems, in the more general case, viz-a-viz suspensions of anisotropic particles, the mechanism of shear-thickening remains unclear. Here through simultaneous measurements of the bulk viscosity and the first Normal stress difference, we show that strong shear thickening in suspensions of colloidal rods is accompanied by large positive normal stresses, indic…
The impact of drops of concentrated non-Brownian suspensions (cornstarch and polystyrene spheres) onto a solid surface is investigated experimentally. The spreading dynamics and maxi- mal deformation of the droplet of such shear thickening liquids are found to be markedly different from the impact of Newtonian drops. A particularly striking observation is that the maximal de- formation is independent of the drop velocity and that the deformation suddenly stops during the impact phase. Both observations are due to the shear-thickening rheology of the suspensions, as is theoretically explained f…
We report direct measurements of spatially resolved stress at the boundary of a shear thickening cornstarch suspension revealing persistent regions of high local stress propagating in the flow direction at the speed of the top boundary. The persistence of these propagating fronts enables precise measurements of their structure, including the profile of boundary stress measured by Boundary Stress Microscopy (BSM) and the non-affine velocity of particles at the bottom boundary of the suspension measured by particle image velocimetry (PIV). In addition, we directly measure the relative flow betwe…
Shear thickening, an increase of viscosity with shear rate, is a ubiquitous phenomena in suspended materials that has implications for broad technological applications. Controlling this thickening behavior remains a major challenge and has led to empirical strategies ranging from altering the particle surfaces and shape to modifying the solvent properties. However, none of these methods allow for tuning of flow properties during shear itself. Here, we demonstrate that by strategic imposition of a high-frequency and low-amplitude shear perturbation orthogonal to the primary shearing flow, we ca…
We propose a simple model, supported by contact-dynamics simulations as well as rheology and friction measurements, that links the transition from continuous to discontinuous shear-thickening in dense granular pastes to distinct lubrication regimes in the particle contacts. We identify a local Sommerfeld number that determines the transition from Newtonian to shear-thickening flows, and then show that the suspension's volume fraction and the boundary lubrication friction coefficient control the nature of the shear-thickening transition, both in simulations and experiments.
A theory is presented for the onset of shear thickening in colloidal suspensions of particles, stabilized by an electrostatic repulsion. Based on an activation model a critical shear stress can be derived for the onset of shear thickening in dense suspensions for a constant potential and a constant charge approach of the spheres. Unlike previous models the total interaction potential is taken into account (sum of attraction and repulsion). The critical shear stress is related to the maximum of the total interaction potential scaled by the free volume per particle. A comparison with experimenta…
This paper exposes an extension of an activation model previously published by the authors. When particles arranged along the compression axis of a sheared suspension, they may overcome the electrostatic repulsion and form force chains associated with shear thickening. A percolation based consideration, allows an estimation of the impact of the force chains on a flowing suspension. It suggests that, similar to mode-coupling models, the suspension becomes unstable before the critical stress evaluated from the activation model is reached. The theory is applicable only to discontinuous shear thic…
Tuning the shear-thickening of suspensions through surface roughness and physico-chemical interactions
Hatsopoulos Microfluids Laboratory, Department of Mechanical Engineering, MIT（麻省理工学院机械工程系哈特索普斯微流体实验室）；MultiScale Material Science for Energy and Environment, UMI 3466, CNRS-MIT（中法纳米研究中心能源与环境多尺度材料科学）；ENSL, CNRS, Laboratoire de physique（里昂高等师范学院法国国家科学研究中心物理实验室）
We propose a unifying rheological framework for dense suspensions of non-Brownian spheres, predicting the onsets of particle friction and particle inertia as distinct shear thickening mechanisms, while capturing quasistatic and soft particle rheology at high volume fractions and shear rates respectively. Discrete element method simulations that take suitable account of hydrodynamic and particle-contact interactions corroborate the model predictions, demonstrating both mechanisms of shear thickening, and showing that they can occur concurrently with carefully selected particle surface propertie…
A highly sheared dense aqueous suspension of granular cornstarch particles displays rich nonlinear rheology. We had previously demonstrated the growth and onset of interfacial instabilities when shear-thinning cornstarch suspensions were displaced by a Newtonian fluid, and had suggested methods to maximise displacement efficiency [Palak, R. Sathayanath, S. K. Kalpathy and R. Bandyopadhyay, Colloids Surf. A Physicochem. Eng. Asp., 629 (2021) 127405]. In the present work, we explore the miscible displacement of a dense aqueous cornstarch suspension in its discontinuous shear-thickening regime in…
Dense particulate suspensions often become more dilute as they move downstream through a constriction. We find that as a shear-thickening suspension is extruded through a narrow die and undergoes such liquid migration, the extrudate maintains a steady concentration $ϕ_c$, independent of time or initial concentration. This concentration $ϕ_c$ varies with volumetric flow rate $Q$ and die radius $r_{\rm d}$, but at low $Q$ collapses onto a universal function of $Q/r_{\rm d}^3$, a characteristic shear rate in the die. We explain quantitatively the onset of liquid migration in extrusion by coupling…
We study the emergence of shear thickening in dense suspensions of non-Brownian particles. We combine local velocity and concentration measurements using Magnetic Resonance Imaging with macroscopic rheometry experiments. In steady state, we observe that the material is heterogeneous, and we find that that the local rheology presents a continuous transition at low shear rate from a viscous to a shear thickening, Bagnoldian, behavior with shear stresses proportional to the shear rate squared, as predicted by a scaling analysis. We show that the heterogeneity results from an unexpectedly fast mig…
Dense, stabilized, frictional particulate suspensions in a viscous liquid undergo increasingly strong continuous shear thickening (CST) as the solid packing fraction, $ϕ$, increases above a critical volume fraction, and discontinuous shear thickening (DST) is observed for even higher packing fractions. Recent studies have related shear thickening to a transition from mostly lubricated to predominantly frictional contacts with the increase in stress. The rheology and networks of frictional forces from two and three-dimensional simulations of shear-thickening suspensions are studied. These are a…
Discontinuous shear-thickening in dense suspensions naturally emerges from the activation of frictional forces by shear flow in non-Brownian systems close to jamming. Yet, this physical picture is incomplete as most experiments study soft colloidal particles subject to thermal fluctuations. To characterise discontinuous shear-thickening in colloidal suspensions we use computer simulations to provide a complete description of the competition between athermal jamming, frictional forces, thermal motion, particle softness, and shear flow. We intentionally neglect hydrodynamics, electrostatics, lub…
Colloidal suspensions have a rich rheology and can exhibit shear-thinning as well as shear-thickening. Numerical simulations recently suggested that shear-thickening may be attributed to the inertia of the colloids, besides the hydrodynamic interactions between them. Here, we consider the ideal limit of a dense bath of soft colloids following an underdamped Langevin dynamics. We use a mean-field equation for the colloidal density to get an analytical expression of the drag force felt by a probe pulled at constant velocity through the suspension. Our results show that inertia can indeed induce …
Suspensions are of wide interest and form the basis for many smart fluids. For most suspensions, the viscosity decreases with increasing shear rate, i.e. they shear thin. Few are reported to do the opposite, i.e. shear thicken, despite the longstanding expectation that shear thickening is a generic type of suspension behavior. Here we resolve this apparent contradiction. We demonstrate that shear thickening can be masked by a yield stress and can be recovered when the yield stress is decreased below a threshold. We show the generality of this argument and quantify the threshold in rheology exp…
This paper adopts a previously developed activation model of shear thickening, published by the authors, to sterically stabilized colloidal suspensions. When particles arranged along the compression axis of a sheared suspension, they may overcome the repulsive interaction and form hydroclusters associated with shear thickening. Taking advantage of the total interaction potential of polymeric brush coating and van der Waals attraction, the applicability of the activation model is shown within the validity range of a continuum theory. For the comparison with an extensive experimental investigati…
We use 2D numerical simulations to study dense suspensions of non-Brownian hard particles using the Critical Load Model (CLM) under constant confining pressures. This simple model shows discontinuous shear thickening (DST) as the tangential forces get activated upon increased shear stresses. By parameterizing a simple binary system of frictional and non-frictional particles of different proportions we show that the jamming packing fraction, at which the viscosity diverges, is controlled by the fraction of frictional contacts. The viscosity of dense suspensions can thereby be expressed as a fun…
We study the rheology of cornstarch suspensions, a dense system of non-Brownian particles that exhibits shear thickening, i.e. a viscosity that increases with increasing shear rate. Using MRI velocimetry we show that the suspension has a yield stress. From classical rheology it follows that as a function of the applied stress the suspension is first solid (yield stress), then liquid and then solid again when it shear thickens. The onset shear rate for thickening is found to depend on the measurement geometry: the smaller the gap of the shear cell, the lower the shear rate at which thickening o…
The authors previously introduced an activation model for the onset of shear thickening in electrically stabilized colloidal suspensions. It predicts that shear thickening occurs, when particles arranged along the compression axis in a sheared suspension do overcome the electrostatic repulsion at a critical shear stress, and are captured in the primary minimum of the DLVO interaction potential. A comparison with an experimental investigation on non-aqueous silica suspensions, carried out by Maranzano and Wagner, is performed. For particle systems that fall into the applicability range of the t…
The shear rheology of dense colloidal and granular suspensions is strongly nonlinear, as these materials exhibit shear-thinning and shear-thickening, depending on multiple physical parameters. We numerically study the rheology of a simple model of soft repulsive particles at large densities, and show that nonlinear flow curves reminiscent of experiments on real suspensions can be obtained. By using dimensional analysis and basic elements of kinetic theory, we rationalize these multiple rheological regimes and disentangle the relative impact of thermal fluctuations, glass and jamming transition…
Contact-network organization and motion statistics in shear-thickening suspensions
Benjamin Levich Institute, CUNY City College of New York（本杰明·莱维希研究所，纽约市立大学）；Department of Applied Science and Technology, Politecnico di Torino（都灵理工大学应用科学与技术系）；Martin Fisher School of Physics, Brandeis University（布兰代斯大学马丁·费舍尔物理学院）；Department of Chemical Engineering, CUNY City College of New York（纽约市立大学化学工程系）
We consider the shear rheology of concentrated suspensions of non-Brownian frictional particles. The key result of our study is the emergence of a pronounced shear-thickening regime, where frictionless particles would normally undergo shear-thinning. We clarify that shear thickening in our simulations is due to enhanced energy dissipation via frictional inter-particle forces. Moreover, we evidence the formation of dynamically correlated particle-clusters of size $ξ$, which contribute to shear thickening via an increase in \emph{viscous} dissipation. A scaling argument gives $η\sim ξ^2$, which …
We investigate confined shear thickening suspensions for which the sample thickness is comparable to the particle dimensions. Rheometry measurements are presented for densely packed suspensions of spheres and rods with aspect ratios 6 and 9. By varying the suspension thickness in the direction of the shear gradient at constant shear rate, we find pronounced oscillations in the stress. These oscillations become stronger as the gap size is decreased, and the stress is minimized when the sample thickness becomes commensurate with an integer number of particle layers. Despite this confinement-indu…
We study the fronts that appear when a shear-thickening suspension is submitted to a sudden driving force at a boundary. Using a quasi-one-dimensional experimental geometry, we extract the front shape and the propagation speed from the suspension flow field and map out their dependence on applied shear. We find that the relation between stress and velocity is quadratic, as is generally true for inertial effects in liquids, but with a pre-factor that can be much larger than the material density. We show that these experimental findings can be explained by an extension of the Wyart-Cates model, …
There is a growing consensus that shear thickening of concentrated dispersions is driven by the formation of stress-induced frictional contacts. The Wyart-Cates (WC) model of this phenomenon, in which the microphysics of the contacts enters solely via the fraction $f$ of contacts that are frictional, can successfully fit flow curves for suspensions of weakly polydisperse spheres. However, its validity for "real-life", polydisperse suspensions has yet to be seriously tested. By performing systematic simulations on bidisperse mixtures of spheres, we show that the WC model applies only in the mon…
Shear thickening is a type of non-Newtonian behavior in which the stress required to shear a fluid increases faster than linearly with shear rate. Many concentrated suspensions of particles exhibit an especially dramatic version, known as Discontinuous Shear Thickening (DST), in which the stress suddenly jumps with increasing shear rate and produces solid-like behavior. The best known example of such counter-intuitive response to applied stresses occurs in mixtures of cornstarch in water. Over the last several years, this shear-induced solid-like behavior together with a variety of other unusu…
