arXivDaily arXiv每日学术速递 周一至周五更新
arXiv 1302.1385cond-mat.mes-hallcond-mat.mtrl-scicond-mat.soft
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石墨烯作为原型结晶膜

Graphene as a Prototype Crystalline Membrane

Mikhail I. Katsnelson, Annalisa Fasolino

摘要:

从弦论到化学和生物学,许多领域都在追求对膜(高维空间中的低维柔性系统)的结构和热性质的理解。三维中的二维(2D)膜的情况是处理真实材料的相关情况。传统上,膜主要在生物膜和一般软物质的背景下讨论。这些系统的复杂性阻碍了基于真正微观方法的原子间结构的现实描述。因此,膜的理论主要是在唯象模型中发展的。从统计力学的观点来看,有限温度下的膜是由相互作用的长程涨落控制的系统。石墨烯是第一个真正的二维系统,仅由一层碳原子组成,为开发膜的微观描述提供了模型系统。在这个帐户中,我们回顾了石墨烯的结构和热性质的微观理论的关键结果,并将它们与唯象理论的预测进行比较。这两种方法对于原子位移的关联函数的各种标度性质都有很好的一致性。然而,其他一些性质,如弯曲刚度的温度依赖性,不能基于唯象方法来理解。我们还考虑了石墨烯在非常高的温度和比较的结果与现有的二维熔化模型。石墨烯的熔化呈现出不同的情况,我们将该过程描述为石墨烯层分解成纠缠的碳链。

英文摘要:

The understanding of the structural and thermal properties of membranes, low-dimensional flexible systems in a space of higher dimension, is pursued in many fields from string theory to chemistry and biology. The case of a two-dimensional (2D) membrane in three dimensions is the relevant one for dealing with real materials. Traditionally, membranes are primarily discussed in the context of biological membranes and soft matter in general. The complexity of these systems hindered a realistic description of their interatomic structures based on a truly microscopic approach. Therefore, theories of membranes were developed mostly within phenomenological models. From the point of view of statistical mechanics, membranes at finite temperature are systems governed by interacting long-range fluctuations. Graphene, the first truly two-dimensional system consisting of just one layer of carbon atoms, provides a model system for the development of a microscopic description of membranes. In this Account, we review key results in the microscopic theory of structural and thermal properties of graphene and compare them with the predictions of phenomenological theories. The two approaches are in good agreement for the various scaling properties of correlation functions of atomic displacements. However, some other properties, such as the temperature dependence of the bending rigidity, cannot be understood based on phenomenological approaches. We also consider graphene at very high temperature and compare the results with existing models for two-dimensional melting. The melting of graphene presents a different scenario, and we describe that process as the decomposition of the graphene layer into entangled carbon chains.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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