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arXiv 1203.0551math-phmath.MPquant-ph
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薛定谔方程的解、原点边界条件和分布理论

Solutions of the Schrödinger equation, boundary condition at the origin, and theory of distributions

Y. C. Cantelaube

摘要:

在中心势中,球坐标系中薛定谔方程的通常解在于确定径向方程的解R(r)或u(r),这些径向方程被认为是薛定谔方程的径向部分。然而,为了排除奇异解,必须用边界条件u(0)= 0来补充解。对于这一条件的合理性,仍然没有达成共识。它是基于一个误解,这个误解来自于这样一个事实,即用R(r)表示的径向方程是从薛定谔方程导出的,而用u(r)表示的径向方程是从前者导出的,通过在函数的意义上取拉普拉斯算子。通过在分布的意义上取这些拉普拉斯算子,我们证明了当径向方程的解是正则的而不是奇异的时,径向方程是从薛定谔方程导出的,因此方程不需要补充任何补充条件,例如u(0)= 0。

英文摘要:

In a central potential the usual resolution of the Schrödinger equation in spherical coordinates consists in determining the solutions R(r) or u(r) of the radial equations considered as the radial parts of the Schrödinger equation. However, the solutions must be supplemented with the boundary condition u(0) = 0 in order to rule out singular solutions. There is still no consensus to justify this condition, with good reason. It is based on a misunderstanding that comes from the fact that the radial equation in terms of R(r) is derived from the Schrödinger equation, and the radial equation in terms of u(r) from the former, by taking the Laplacians in the sense of the functions. By taking these Laplacians in the sense of the distributions, as it is required, we show that the radial equations are derived from the Schrodinger equation when their solutions are regular, but not when they are singular, so that the equations need not be supplemented with any supplementary condition such as u(0) = 0.

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