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arXiv 1111.2930cond-mat.stat-mech
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成核理论的物理簇:广义Hill簇

On the Physical Cluster of Nucleation Theory: Generalized Hill Cluster

Rasmus A. X. Persson

摘要:

Hill(J.Chem.Phys,23,617)最初设想的物理簇以一种新的方式推广到$N > 2$的情况。与希尔的成对推广相反,这个定义确保了簇的所有组成分子都没有足够的动能来逃逸,并避免了希尔推广的错误含义,即分子速度越来越相等。

英文摘要:

The physical cluster originally conceived by Hill (J. Chem. Phys, 23, 617) is generalized for the case $N > 2$ in a novel way. Contrary to Hill's pairwise generalization, this definition assures that all constituent molecules of the cluster have insufficient kinetic energy to escape, and avoids the spurious implication of Hill's generalization that the molecular velocities are to be increasingly equal.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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