高温下部分电离碳氧混合物的状态方程
Equation of state for partially ionized carbon and oxygen mixtures at high temperatures
摘要：
在等离子体化学图像的框架下，用自由能最小化方法计算了部分电离的碳、氧和碳氧混合物在3 \times 10^5 K <~ T <~ 3 \times 10^6 K范围内的物态方程.自由能模型是我们以前为纯碳开发的模型的改进扩展（Phys. Rev. E，72，046402; arXiv：physics/0510006）。结合物种的内部配分函数的计算通过在考虑压力电离的等离子体环境中的每个电离阶段的自洽处理。长程库仑离子之间的相互作用和筛选的离子由自由电子包括使用我们以前发表的分析模型，最近改进，特别是对于混合物的情况下。我们还提出了一个简单而准确的方法计算的部分电离的二元混合物的状态方程的基础上详细的电离平衡计算纯物质。
英文摘要：
The equation of state (EOS) for partially ionized carbon, oxygen, and carbon-oxygen mixtures at temperatures 3\times10^5 K <~ T <~ 3\times10^6 K is calculated over a wide range of densities, using the method of free energy minimization in the framework of the chemical picture of plasmas. The free energy model is an improved extension of our model previously developed for pure carbon (Phys. Rev. E, 72, 046402; arXiv:physics/0510006). The internal partition functions of bound species are calculated by a self-consistent treatment of each ionization stage in the plasma environment taking into account pressure ionization. The long-range Coulomb interactions between ions and screening of the ions by free electrons are included using our previously published analytical model, recently improved, in particular for the case of mixtures. We also propose a simple but accurate method of calculation of the EOS of partially ionized binary mixtures based on detailed ionization balance calculations for pure substances.
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