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arXiv 1111.0509cond-mat.supr-conquant-ph
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使用连接有机分子邻近耦合到金纳米颗粒的铌薄膜的增加的超导性transition temperature

Increased superconducting transition temperature of a niobium thin-film proximity-coupled to gold nanoparticles using linking organic molecules

Eran Katzir, Shira Yochelis, Felix Zeides, Nadav Katz, Yoav Kalcheim, Oded Millo, Gregory Leitus, Yuri Myasodeyov, Boris Ya. Shapiro, Ron Naaman, Yossi Paltiel

摘要:

的超导临界温度,TC,薄Nb膜显着修改时,金纳米粒子(NPs)化学连接到Nb膜,与一致的增强时,使用3 nm长的乙硅烷连接分子。对于某些接头长度和NP大小,TC增加高达10%。当纳米颗粒与非连接分子物理吸附时,没有观察到变化。在低于TC的连接的NP上获得的电子隧穿光谱通常表现出零偏置峰。我们将这些结果归因于由有机连接体介导的Nb和NP中的电子耦合配对机制。

英文摘要:

The superconducting critical temperature, TC, of thin Nb films is significantly modified when gold nanoparticles (NPs) are chemically linked to the Nb film, with a consistent enhancement when using 3 nm long disilane linker molecules. The TC increases by up to 10% for certain linker length and NPs size. No change is observed when the nanoparticles are physisorbed with non-linking molecules. Electron tunneling spectra acquired on the linked NPs below TC typically exhibit zero-bias peaks. We attribute these results to a pairing mechanism coupling electrons in the Nb and the NPs, mediated by the organic linkers.

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