超流~ 4 He纳米液滴中N2O的振转动力学
Ro-vibrational dynamics of N2O in superfluid 4He nano-droplets
摘要：
本文利用超流性宏观轨道理论中的重要干扰，考虑了几个能改变4 HeN-N_2 O团簇中N_2O的转动常数（B）和振动频率的因素，解释了最近报道的光谱研究结果，得出结论：（i）尽管4 He原子提供了相互作用介质，但团簇的转动光谱显示出尖锐的峰，类似于气态分子的峰，表明分子像自由转子一样旋转，（ii）B从N = 1到6单调减小，在N = 6至8时保持几乎恒定，在N = 9至10时增加，之后有小的振荡，以及（iii）振动频率在N = 6至8时表现出蓝移。1至5，并且对于更高的N具有红移。
英文摘要：
In this paper we use the important interferences of Macro-Orbital theory of superfluidity clubbed with several factors that can change the rotational constant (B) and vibrational frequency of N2O in 4HeN-N2O clusters with N to account for the results of their recently reported spectroscopic studies which conclude that: (i) in spite of the fact that 4He atoms provide an interactive medium, the rotational spectrum of the clusters shows sharp peaks, similar to that of the molecule in gaseous state, indicating that the molecule rotates like a free rotor, (ii) B decreases monotonically from N = 1 to 6, remains nearly constant for N = 6 to 8 and increases for N = 9 to 10 with small oscillations there after and (iii) vibrational frequency exhibits blue shift for N = 1 to 5 and a red shift for higher N.
机构、总结、中文摘要均由AI分析而来，可能存在错误，请以论文正文为准。
