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arXiv 1104.4027cond-mat.str-el
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利用μ子注入观测分子纳米磁体中的能级交叉

Observation of a level crossing in a molecular nanomagnet using implanted muons

T. Lancaster, J. S. Moeller, S. J. Blundell, F. L. Pratt, P. J. Baker, T. Guidi, G. A. Timco, R. E. P. Winpenny

摘要:

利用μ子自旋弛豫,我们在分子纳米磁体(MNM)中观察到了电子能级交叉。这种效应,以前没有观察到,尽管几个μ子的MNM系统的研究,提供了进一步的证据表明,注入μ子的自旋弛豫是敏感的电子自旋的动力学。我们对含有8个Cr离子的开环MNM [ H_{2} N^{t}Bu^{is}Pr][ Cr_{8} CdF_{9}(O_{2} CC(CH_{3})_{3})_{18}](以下简称Cr_{8} Cd)的测量表明,在B_{c} =2.3 T时发生S=0到S=1的跃迁。交叉观察到的平均正电子不对称性,也在μ子自旋弛豫率,这表明在过渡和S=1制度内的峰值为中心的幅度急剧增加的共振状下降。

英文摘要:

We have observed an electronic energy level crossing in a molecular nanomagnet (MNM) using muon-spin relaxation. This effect, not observed previously despite several muon studies of MNM systems, provides further evidence that the spin relaxation of the implanted muon is sensistive to the dynamics of the electronic spin. Our measurements on a broken ring MNM [H_{2}N^{t}Bu^{is}Pr][Cr_{8}CdF_{9}(O_{2}CC(CH_{3})_{3})_{18}] (hereafter Cr_{8}Cd), which contains eight Cr ions, show clear evidence for the S=0 to S=1 transition that takes place at B_{c}=2.3 T. The crossing is observed as a resonance-like dip in the average positron asymmetry and also in the muon-spin relaxation rate, which shows a sharp increase in magnitude at the transition and a peak centred within the S=1 regime.

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