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arXiv 1101.2698cond-mat.softcond-mat.stat-mech
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经典Batschinski定律的统一图象和分子流体的直线直径

The unified picture for the classical laws of Batschinski and the rectilinear diameter for molecular fluids

Leonid A. Bulavin, Vladimir L. Kulinskii

摘要:

在[V.L.]中提出的方法框架内,给出了格子气模型和流体热力学函数之间的显式关系。Kulinskii,J.Phys.Chem.B \textbf{114} 2852(2010)]。结果表明,Widom线作为天然边界之间的气体和液体的流体状态。对分子液体的整体立方型双结点结构给出了解释,并对双结点开口的幅度进行了估计。

英文摘要:

The explicit relations between the thermodynamic functions of the Lattice Gas model and the fluid within the framework of approach proposed earlier in [V. L. Kulinskii, J. Phys. Chem. B \textbf{114} 2852 (2010)] are derived. It is shown that the Widom line serves as the natural border between the gas-like and the liquid-like states of the fluid. The explanation of the global cubic form of the binodal for the molecular liquids is proposed and the estimate for the amplitude of the binodal opening is obtained.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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