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arXiv 1012.4431cond-mat.stat-mech
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再论Smoluchowski凝并方程中的瞬时Gln

Instantaneous Gelation in Smoluchowski's Coagulation Equation Revisited

Robin C. Ball, Colm Connaughton, Thorwald H. M. Stein, Oleg Zaboronski

摘要:

我们研究的Smoluchowski凝聚方程的解决方案与正规化项,从系统中删除集群时,他们的质量超过一个指定的截止尺寸,M。我们主要集中在碰撞内核,这将表现出在没有任何正规化的瞬时凝胶化过渡。数值模拟表明,对于这样的内核与单分散的初始数据,正规化的凝胶化时间随着M的增加而减少,与预期的凝胶化时间为零的非正规化系统一致。这种减少似乎是一个magnimically缓慢的函数M,表明即时凝胶内核可能仍然是合理的物理模型,尽管事实上,他们是高度奇异的情况下,一个截止。我们还研究的情况下,当一个源的单体引入正则化系统。在这种情况下,达到稳定状态。我们提出了一个完整的解析描述,这个正则化的定态的模型内核,K(m_1,m_2)=max{m_1,m_2}^v,凝胶瞬间当M趋于无穷大,如果v>1。稳定的集群大小分布衰减为拉伸指数为小集群大小和跨越到一个幂律衰减指数为大集群大小。当M变大时,稳态下的总粒子密度以(Log M^(v-1))^-1/2的形式缓慢地消失。稳态的方法是不平凡的:关于稳态的振荡来自单体注入和截止值M之间的相互作用,当M很大时,振荡衰减得非常缓慢。这些振荡的定量分析提供了描述的情况下,簇只能通过吸收单体的加成模型。

英文摘要:

We study the solutions of the Smoluchowski coagulation equation with a regularisation term which removes clusters from the system when their mass exceeds a specified cut-off size, M. We focus primarily on collision kernels which would exhibit an instantaneous gelation transition in the absence of any regularisation. Numerical simulations demonstrate that for such kernels with monodisperse initial data, the regularised gelation time decreases as M increases, consistent with the expectation that the gelation time is zero in the unregularised system. This decrease appears to be a logarithmically slow function of M, indicating that instantaneously gelling kernels may still be justifiable as physical models despite the fact that they are highly singular in the absence of a cut-off. We also study the case when a source of monomers is introduced in the regularised system. In this case a stationary state is reached. We present a complete analytic description of this regularised stationary state for the model kernel, K(m_1,m_2)=max{m_1,m_2}^v, which gels instantaneously when M tends to infinity if v>1. The stationary cluster size distribution decays as a stretched exponential for small cluster sizes and crosses over to a power law decay with exponent v for large cluster sizes. The total particle density in the stationary state slowly vanishes as (Log M^(v-1))^-1/2 when M gets large. The approach to the stationary state is non-trivial : oscillations about the stationary state emerge from the interplay between the monomer injection and the cut-off, M, which decay very slowly when M is large. A quantitative analysis of these oscillations is provided for the addition model which describes the situation in which clusters can only grow by absorbing monomers.

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