In this work, average Hamiltonian theory is used to study selective excitation in a spin-1/2 system evolving under a series of small flip-angle $θ-$pulses $(θ\ll 1)$ that are applied either periodically [which corresponds to the DANTE pulse sequence] or aperiodically. First, an average Hamiltonian description of the DANTE pulse sequence is developed; such a description is determined to be valid either at or very far from the DANTE resonance frequencies, which are simply integer multiples of the inverse of the interpulse delay. For aperiodic excitation schemes where the interpulse delays are chosen pseudorandomly, a single resonance can be selectively excited if the $θ$-pulses' phases are modulated in concert with the time delays. Such a selective pulse is termed a pseudorandom-DANTE or p-DANTE sequence, and the conditions in which an average Hamiltonian description of p-DANTE is found to be similar to that found for the DANTE sequence. It is also shown that averaging over different p-DANTE sequences that are selective for the same resonance can help reduce excitations at frequencies away from the resonance frequency, thereby improving the apparent selectivity of the p-DANTE sequences. Finally, experimental demonstrations of p-DANTE sequences and comparisons with theory are presented.
We demonstrate experimentally the usefulness of selective pulses in NMR to perform quantum computation. Three different techniques based on selective pulse excitations have been proposed to prepare a spin system in a pseudo-pure state. We describe the design of novel ``portmanteau'' gates using the selective manipulation of level populations. A selective pulse implementation of the Deutsch-Jozsa algorithm for a two-qubit and a three-qubit quantum computer is demonstrated.
Experimental realization of quantum information processing in the field of nuclear magnetic resonance (NMR) has been well established. Implementation of conditional phase shift gate has been a significant step, which has lead to realization of important algorithms such as Grover's search algorithm and quantum Fourier transform. This gate has so far been implemented in NMR by using coupling evolution method. We demonstrate here the implementation of the conditional phase shift gate using transition selective pulses. As an application of the gate, we demonstrate Grover's search algorithm and qua…
Quantum computing using two-dimensional NMR has recently been described using scalar coupling evolution technique [J. Chem. Phys.,109,10603 (1998)]. In the present paper, we describe two-dimensional NMR quantum computing with the help of selective pulses. A number of logic gates are implemented using two and three qubits with one extra observer spin. Some many-in-one gates (or Portmanteau gates) are implemented. Toffoli gate (or AND/NAND gate) and OR/NOR gates are implemented on three qubits. Deutsch-Jozsa quantum algorithm for one and two qubits, using one extra work qubit, has also been impl…
We present the first NMR implementation of a scheme for selective and efficient quantum process tomography without ancilla. We generalize this scheme such that it can be implemented efficiently using only a set of measurements involving product operators. The method allows us to estimate any element of the quantum process matrix to a desired precision, provided a set of quantum states can be prepared efficiently. Our modified technique requires fewer experimental resources as compared to the standard implementation of selective and efficient quantum process tomography, as it exploits the speci…
A scheme for decoupling and selectively recoupling large networks of dipolar-coupled spins is proposed. The scheme relies on a combination of broadband, decoupling pulse sequences applied to all the nuclear spins with a band-selective pulse sequence for single spin rotations or recoupling. The evolution-time overhead required for selective coupling is independent of the number of spins, subject to time-scale constraints, for which we discuss the feasibility. This scheme may improve the scalability of solid-state-NMR quantum computing architectures.
We consider the problem of time-optimal control of quadrupole nucleus with the spin I=1 by NMR. In contrast to the conventional methods based on selective pulses, the control is implemented using nonselective pulses separated by free evolution intervals. Using the Cartan decomposition, the system of equations is obtained for finding parameters of a control field. Partial time-optimal solutions for the important single-qutrit gates (selective rotations and quantum Fourier transform) are found. The strong dependence of minimum gate implementation times on global phase of the gate is observed. Th…
A three-qubit 13C solid-state nuclear magnetic resonance (NMR) system for quantum information processing, based on the malonic acid molecule, is used to demonstrate high-fidelity universal quantum control via strongly-modulating radio-frequency pulses. This control is achieved in the strong-coupling regime, in which the timescales of selective qubit addressing and of two-qubit interactions are comparable.
In NMR (Nuclear Magnetic Resonance) quantum computation, the selective control of multiple homonuclear spins is usually slow because their resonance frequencies are very close to each other. To quickly implement controls against decoherence effects, this paper presents an efficient numerical algorithm fordesigning minimum-time local transformations in two homonuclear spins. We obtain an accurate minimum-time estimation via geometric analysis on the two-timescale decomposition of the dynamics. Such estimation narrows down the range of search for the minimum-time control with a gradient-type opt…
Nuclear magnetic resonance (NMR) schemes can be applied to micron-, and nanometer-sized samples by the aid of quantum sensors such as nitrogen-vacancy (NV) color centers in diamond. These minute devices allow for magnetometry of nuclear spin ensembles with high spatial and frequency resolution at ambient conditions, thus having a clear impact in different areas such as chemistry, biology, medicine, and material sciences. In practice, NV quantum sensors are driven by microwave (MW) control fields with a twofold objective: On the one hand, MW fields bridge the energy gap between NV and nearby nu…
The paper describes the design of band selective excitation and rotation pulses in high resolution NMR by method of double sweep. We first show the design of a pulse sequence that produces band selective excitation to the equator of Bloch sphere with phase linearly dispersed as frequency. We show how this linear dispersion can then be refocused by nesting free evolution between two adiabatic inversions (sweeps). We then show how this construction can be generalized to give a band selective $x$ rotation over desired frequency band. Experimental excitation profiles for the residual HDO signal in…
We discuss the implementation of frequency selective rotations using sequences of hard pulses and delays. These rotations are suitable for implementing single qubit gates in Nuclear Magnetic Resonance (NMR) quantum computers, but can also be used in other related implementations of quantum computing. We also derive methods for implementing hard pulses in the presence of moderate off-resonance effects, and describe a simple procedure for implementing a hard 180 degree rotation in a two spin system. Finally we show how these two approaches can be combined to produce more accurate frequency selec…
It is possible, for homogeneously broadened lines, to excite selectively the response signals, which are orders of magnitude narrower than the original lines. The new type of echo, which allows detecting such signals, and the formalism, useful for understanding the phenomenon, as well as the experimental examples from NMR spectroscopy are presented.
We demonstrate a synchronized readout (SR) technique for spectrally selective detection of oscillating magnetic fields with sub-millihertz resolution, using coherent manipulation of solid state spins. The SR technique is implemented in a sensitive magnetometer (~50 picotesla/Hz^(1/2)) based on nitrogen vacancy (NV) centers in diamond, and used to detect nuclear magnetic resonance (NMR) signals from liquid-state samples. We obtain NMR spectral resolution ~3 Hz, which is nearly two orders of magnitude narrower than previously demonstrated with NV based techniques, using a sample volume of ~1 pic…
In creating a large-scale quantum information processor, the ability to construct control pulses for implementing an arbitrary quantum circuit in a scalable manner is an important requirement. For liquid-state nuclear magnetic resonance (NMR) quantum computing, a circuit is generally realized through a sequence of selective soft pulses, in which various control imperfections exist and are to be corrected. In this work, we present a comprehensive analysis of the errors arisen in a selective pulse network by using the zeroth and first order average Hamiltonian theory. Effective correction rules …
A new method of preparing the pseudo-pure state of a spin system for quantum computation in liquid nuclear magnetic resonance (NMR) was put forward and demonstrated experimentally. Applying appropriately connected line-selective pulses simultaneously and a field gradient pulse techniques we acquired straightforwardly all pseudo-pure states for two qubits in a single experiment much efficiently. The signal intensity with the pseudo-pure state prepared in this way is the same as that of temporal averaging. Our method is suitable for the system with arbitrary numbers of qubits. As an example of a…
During recent years, dynamical decoupling (DD) has gained relevance as a tool for manipulating quantum systems and extracting information from them. This is particularly relevant for spins involved in nuclear magnetic resonance (NMR), where DD sequences can be used to prolong quantum coherences, or for selectively couple/decouple the effects imposed by random environmental fluctuations. In this Letter, we show that one can exploit these concepts in order to selectively recouple diffusion processes in restricted spaces. The ensuing method provides a novel tool to measure restriction lengths in …
The nitrogen-vacancy (NV) centre in diamond is a leading platform for nanoscale sensing and imaging, as well as quantum information processing in the solid state. To date, individual control of two NV electronic spins at the nanoscale has been demonstrated. However, a key challenge is to scale up such control to arrays of NV spins. Here we apply nanoscale magnetic resonance frequency encoding to realize site-selective addressing and coherent control of a four-site array of NV spins. Sites in the array are separated by 100 nm, with each site containing multiple NVs separated by ~15 nm. Microcoi…
For the implementation of a quantum computer it is necessary to exercise complete control over the Hamiltonian of the used physical system. For NMR quantum computing the effectively acting Hamiltonian can be manipulated via pulse sequences. Here we examine a register consisting of N selectively addressable spins with pairwise coupling between each spin pair. We show that complete decoupling of the spins is possible independent of the particular form of the spin-spin interaction. The proposed method based on orthogonal arrays is efficient in the sense that the effort regarding time and amount o…
We describe a method for improving coherent control through the use of detailed knowledge of the system's Hamiltonian. Precise unitary transformations were obtained by strongly modulating the system's dynamics to average out unwanted evolution. With the aid of numerical search methods, pulsed irradiation schemes are obtained that perform accurate, arbitrary, selective gates on multi-qubit systems. Compared to low power selective pulses, which cannot average out all unwanted evolution, these pulses are substantially shorter in time, thereby reducing the effects of relaxation. Liquid-state NMR t…
