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arXiv 1006.0897cond-mat.mes-hallquant-ph
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用跃迁电压谱揭示分子轨道门控

Revealing molecular orbital gating by transition-voltage spectroscopy

Ioan Baldea

摘要:

最近,Song等人[Nature 462,1039(2009)]采用跃迁电压谱来证明单分子晶体管的最高占据分子轨道(HOMO)的能量$\varepsilon_H$可以由栅极电势$V_G$控制。为了证明线性依赖性$\varepsilon_H-V_G$,实验数据已被解释通过建模的分子作为跨越空间源极-漏极区域的分子结的能量势垒。如本研究所示,由于该原始模型不能定量描述测量的$I$ - $V$ -特性,因此重要的是得到$\varepsilon_H$对$V_G$的线性依赖性的进一步支持。这里提出的结果,这已经获得了一个点样分子的模型内,证实了这种线性依赖。由于这两个模型依赖于互补的描述,目前的结果表明,解释的实验结果作为门控HOMO的证据是足够普遍的。

英文摘要:

Recently, Song et al [Nature 462, 1039 (2009)] employed transition-voltage spectroscopy to demonstrate that the energy $\varepsilon_H$ of the highest occupied molecular orbital (HOMO) of single-molecule transistors can be controlled by a gate potential $V_G$. To demonstrate the linear dependence $\varepsilon_H-V_G$, the experimental data have been interpreted by modeling the molecule as an energy barrier spanning the spatial source-drain region of molecular junctions. Since, as shown in this work, that crude model cannot quantitatively describe the measured $I$-$V$-characteristics, it is important to get further support for the linear dependence of $\varepsilon_H$ on $V_G$. The results presented here, which have been obtained within a model of a point-like molecule, confirm this linear dependence. Because the two models rely upon complementary descriptions, the present results indicate that the interpretation of the experimental results as evidence for a gate controlled HOMO is sufficiently general.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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