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arXiv 0909.3794cond-mat.dis-nn
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无序介质中聚合物的结构交叉

Structural crossover of polymers in disordered media

Roni Parshani, Lidia A. Braunstein, Shlomo Havlin

摘要:

我们提出了一个统一的标度理论的结构行为的聚合物嵌入在一个无序的能量基板。最佳聚合物构型被定义为使单体与基底之间的相互作用能之和最小化的聚合物构型。在强无序极限(SD)的最佳聚合物的分形维数被发现较早大于在弱无序(WD)的分形维数。我们介绍了WD和SD限制之间的交叉的标度理论。对于在相同无序基质中的不同尺寸的聚合物,我们表明具有少量单体的聚合物,N << N*,将表现为SD,而长度N >> N* 的大聚合物将表现为WD。这意味着即使在相同的基底中,与大聚合物相比,小聚合物将相对更紧凑。交叉长度N* 是ν和α的函数,其中ν是渗流相关长度指数,α是控制无序宽度的参数。此外,我们的研究结果表明,交叉之间的强和弱的无序限制,甚至可以看到在相同的聚合物配置。如果关注长聚合物(N >> N*)内尺寸为n << N* 的片段,则该片段与尺寸为n >> N* 的片段相比将具有更高的分形维数。

英文摘要:

We present a unified scaling theory for the structural behavior of polymers embedded in a disordered energy substrate. An optimal polymer configuration is defined as the polymer configuration that minimizes the sum of interacting energies between the monomers and the substrate. The fractal dimension of the optimal polymer in the limit of strong disorder (SD) was found earlier to be larger than the fractal dimension in weak disorder (WD). We introduce a scaling theory for the crossover between the WD and SD limits. For polymers of various sizes in the same disordered substrate we show that polymers with a small number of monomers, N << N*, will behave as in SD, while large polymers with length N >> N* will behave as in WD. This implies that small polymers will be relatively more compact compared to large polymers even in the same substrate. The crossover length N* is a function of νand a, where νis the percolation correlation length exponent and a is the parameter which controls the broadness of the disorder. Furthermore, our results show that the crossover between the strong and weak disorder limits can be seen even within the same polymer configuration. If one focuses on a segment of size n << N* within a long polymer (N >> N*) that segment will have a higher fractal dimension compared to a segment of size n >> N*.

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