arXivDaily arXiv每日学术速递 周一至周五更新
arXiv 0909.2947cond-mat.soft
收藏

润湿性对质子交换膜燃料电池(PEMFC)气体扩散层中液态水传输的影响

Influence of wettability on liquid water transport in gas diffusion layer of proton exchange membrane fuel cells (PEMFC)

Hamza Chraibi, L. Ceballos, M. Prat, Michel Quintard, Alexandre Vabre

摘要:

水管理是限制PEFC性能的关键因素。我们展示了如何深入了解这个问题,可以从孔隙尺度的模拟模型纤维介质中的水入侵。我们探讨了接触角对水侵入模式和水饱和度的影响,并显示了一个戏剧性的变化,在入侵模式,从分形紧凑,发生系统从疏水性到亲水性的变化。然后,我们探讨的情况下,混合润湿性的系统,即包含亲水性和疏水性孔。突破时的饱和度作为亲水性孔隙分数的函数进行了研究。讨论了与水管理问题,GDL的优化设计和燃料电池性能退化机制的关系的结果。我们概述了如何研究可以扩展到3D系统,特别是从二进制图像的GDL获得的X射线显微断层扫描。

英文摘要:

Water management is a key factor that limits PEFC's performance. We show how insights into this problem can be gained from pore-scale simulations of water invasion in a model fibrous medium. We explore the influence of contact angle on the water invasion pattern and water saturation at breakthrough and show that a dramatic change in the invasion pattern, from fractal to compact, occurs as the system changes from hydrophobic to hydrophilic. Then, we explore the case of a system of mixed wettability, i.e. containing both hydrophilic and hydrophobic pores. The saturation at breakthrough is studied as a function of the fraction of hydrophilic pores. The results are discussed in relation with the water management problem, the optimal design of a GDL and the fuel cell performance degradation mechanisms. We outline how the study could be extended to 3D systems, notably from binarised images of GDLs obtained by X ray microtomography.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

↑