We study two-dimensional Heisenberg antiferromagnets with additional multi-spin interactions which can drive the system into a valence-bond solid state. For standard SU(2) spins, we consider both four- and six-spin interactions. We find continuous quantum phase transitions with the same critical exponents. Extending the symmetry to SU(N), we also find continuous transitions for N=3 and 4. In addition, we also study quantitatively the cross-over of the order-parameter symmetry from Z4 deep inside the valence-bond-solid phase to U(1) as the phase transition is approached.
Doped IrTe$_2$ is considered a platform for topological superconductivity and therefore receives currently a lot of interest. In addition, the superconductivity in these materials exists in close vicinity of electronic valence bond crystals, which we explore here by means of high-pressure single crystal x-ray diffraction in combination with density functional theory. Our crystallographic refinements provide unprecedented information about the structural evolution as a function of applied pressure up to 42 GPa. Using this structural information for density functional theory calculations, we sho…
Recent evidence from magnetic torque, electron spin resonance, and second harmonic generation indicate that the prototypical quantum spin liquid candidate, herbertsmithite, has a symmetry lower than its x-ray refined trigonal space group. Here, we consider known and possible distortions of this mineral class, along with related copper kagome oxides and fluorides, relate these to possible valence bond patterns, and comment on their relevance to the physics of these interesting materials.
Using large-scale quantum Monte Carlo simulations, we exactly solve a model of Fermions hopping on the honeycomb lattice with cluster charge interactions, which has been proposed as an effective model with possible application to twisted bilayer graphene near half-filling. We find an interaction driven semimetal to insulator transition to an insulating phase consisting of a valence bond solid with Kekulé pattern. Finite size scaling reveals that the phase transition of the semimetal to Kekulé valence bond solid phase is continuous and belongs to chiral XY universality class.
On the basis of a Berry-phase analysis, we study the ground state of the $J_1$-$J_2$ Heisenberg chain for $S=2,3,4$. We find that changes of the Berry phase occur $S$ times for spin-$S$ systems, indicating the sequential phase transitions. The sequential phase transitions are associated with the change of valence-bond configurations of the ground states. To demonstrate this numerically, we connect the $J_1$-$J_2$ Heisenberg Hamiltonian with the generalized Affleck-Kennedy-Lieb-Tasaki model, and show that the different phases are connected to the different valence-bond-solid states.
We propose and study an SU(3) trimer resonating-valence-bond (tRVB) state with $C_{4v}$ point-group symmetry on the square lattice. By devising a projected entangled-pair state representation, we show that all (connected) correlation functions between local operators in this SU(3) tRVB state decay exponentially, indicating its gapped nature. We further calculate the modular $S$ and $T$ matrices by constructing all nine topological sectors on a torus and establish the existence of $\mathbb{Z}_3$ topological order in this SU(3) tRVB state.
A molecular Mott insulator $κ$-(ET)$_2$B(CN)$_4$ [ET = bis(ethylenedithio)tetrathiafulvalene] with a distorted triangular lattice exhibits a quantum disordered state with gapped spin excitation in the ground state. $^{13}$C nuclear magnetic resonance, magnetization, and magnetic torque measurements reveal that magnetic field suppresses valence bond order and induces long-range magnetic order above a critical field $\sim 8$ T. The nuclear spin-lattice relaxation rate $1/T_1$ shows persistent evolution of antiferromagnetic correlation above the transition temperature, highlighting a quantum spin…
We propose resonating valence bond wave functions for a spin-1 system on the torus that realize a non-Abelian chiral spin liquid. The wave functions take the form of infinite dimensional matrix product states constructed from conformal blocks of the $\mathrm{SO}(3)_{1}$ Wess-Zumino-Witten model. This means that they are lattice analogues of the bosonic Moore-Read state introduced in fractional quantum Hall systems. The topological order of this system is revealed by explicit construction of three-fold degenerate ground states and analytical computation of the modular S and T matrices.
We use exact quantum Monte Carlo simulations to demonstrate that the Néel ground state of an antiferromagnetic SU(2) spin-$\frac{1}{2}$ Heisenberg model on the honeycomb lattice can be destroyed by a coupling to quantum phonons. We find a clear first-order transition to a valence-bond-solid state with Kekulé order instead of a deconfined quantum critical point. However, quantum lattice fluctuations can drive the transition towards weakly first-order, revealing a tunability of the transition by the retardation of the interaction. In contrast to the one-dimensional case, our phase diagram in the…
We consider a model Hamiltonian with two SU(4) fermions per site on a square lattice, showing a competition between bilinear and biquadratic interactions. This model has generated interest due to possible realizations in ultracold atom experiments and existence of spin liquid ground states. Using a basis transformation, we show that part of the phase diagram is amenable to quantum Monte Carlo simulations without a sign problem. We find evidence for spin nematic and valence bond crystalline phases, which are separated by a weak first order phase transition. A U(1) symmetry is found to emerge in…
Generalization of the singlet sector valence bond loop algorithm to antiferromagnetic ground states with total spin $S_{tot}=1/2$
我们推广了Sandvik、Beach和Evertz（A. W. Sandvik，Phys. Rev. 95，207203（2005）; K. S. D.海滩和A. W. Sandvik，Nucl.Phys.B750，142（2006）; A. W. Sandvik和H. G. Evertz，arXiv：0807.0682，unpublished.）反铁磁哈密顿量的基态在有限尺寸系统中具有总自旋$S_{tot} = 1/2$的情况。我们解释了各种基态的期望值可以通过在单重态的情况下开发的估计的泛化计算，并说明了该方法的功率通过计算基态的自旋纹理和键能在一个$L \times L$海森堡反铁磁体与$L$奇数和自由边界。
