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arXiv 0903.0029physics.ao-ph
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用粒子分辨气溶胶模式估算黑碳老化时间尺度

Estimating black carbon aging time-scales with a particle-resolved aerosol model

N. Riemer, M. West, R. A. Zaveri, R. C. Easter

摘要:

了解气溶胶粒子的老化过程对于评估其化学反应性、云凝结核活动、辐射特性和健康影响具有重要意义。在这项研究中,我们研究了老化的黑碳颗粒在一个理想化的城市羽流使用一种新的方法,颗粒分辨气溶胶模型PartMC-MOSAIC。我们提出了一种使用基于云凝结核激活的老化标准来估计老化时间尺度的方法。结果表明,分离成白天的制度,冷凝占主导地位,凝结占主导地位的夜间制度。对于所选的城市烟羽情景,取决于过饱和阈值,老化时间尺度的值在白天在0.06小时和10小时之间变化,在夜间在6小时和20小时之间变化。

英文摘要:

Understanding the aging process of aerosol particles is important for assessing their chemical reactivity, cloud condensation nuclei activity, radiative properties and health impacts. In this study we investigate the aging of black carbon containing particles in an idealized urban plume using a new approach, the particle-resolved aerosol model PartMC-MOSAIC. We present a method to estimate aging time-scales using an aging criterion based on cloud condensation nuclei activation. The results show a separation into a daytime regime where condensation dominates and a nighttime regime where coagulation dominates. For the chosen urban plume scenario, depending on the supersaturation threshold, the values for the aging time-scales vary between 0.06 hours and 10 hours during the day, and between 6 hours and 20 hours during the night.

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