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arXiv 0902.3708physics.plasm-phphysics.gen-ph
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零温极限下气态等离子体的热力学性质

Thermodynamic properties of gaseous plasmas in zero-temperature limit

Igor Iosilevskiy

摘要:

在低温和低密度条件下,考虑了气体等离子体热力学函数的极限结构。这是一个明显的趋势,这是以前声称[高温。1979年(1981年),他走到了极端。在所讨论的极限范围内,当温度和密度趋于零,电子化学势恒定时,两种状态方程(热态和热态)在其特殊形式暴露出来时,即热态方程为PV/RT,热态方程为(U - 3/2 PV)时,得到几乎相同的阶梯结构(“电离阶梯”)。同时,所有热力学微分参数(热容,压缩性等)获得其显著的δ状结构(“热力学谱”)。这种限制性结构出现在电子化学势(“固有能量标度”)的固定(负)范围内,该范围由主电离势的值限制,由与物质的升华能相关的值限制。所有可能的复合物(原子、分子和离子)在其基态的结合能是唯一的量,它在这个限制性的画面中表现为每一步的位置和值的有意义的细节。气态零开尔文等温线的极限阶梯结构是低温非理想条件下气态等离子体状态方程中著名的“壳层振荡”的一般原型。与此同时,等离子体热力学的这种极限形式可以作为一个自然的基础,在这个参考系周围的渐近展开(温度,但不是密度)的框架中,严格推导众所周知的准化学方法(“化学图像”)。

英文摘要:

Limiting structure of thermodynamic functions of gaseous plasmas is under consideration in the limit of low temperature and density. The remarkable tendency, that was claimed previously [High Temp. 19, 799 (1981)], is carried to extreme. In the limit discussed, when temperature and density tend to zero at constant value of electron chemical potential, both equations of state (thermal and caloric) obtain almost identical stepped structure ("ionization stairs") when their special forms being exposed i.e. PV/RT for thermal EOS and (U - 3/2PV) for caloric EOS. At the same time all thermodynamic differential parameters (heat capacity, compressibility, etc.) obtain their remarkable delta-like structures ("thermodynamic spectrum"). This limiting structure appears within a fixed (negative) range of electron chemical potential ("intrinsic energy scale") that is bounded below by value of major ionization potential and above by the value connected with sublimation energy of substance. Binding energies of all possible complexes (atomic, molecular and ionic) in its ground state are the only quantities that manifest itself in meaningful details of this limiting picture as location and value of every step. The limiting stepped structure of gaseous zero-Kelvin isotherm is generic prototype of well-known "shell oscillations" in EOS of gaseous plasmas at low, but finite temperatures and non-idealities. At the same time this limiting form of plasma thermodynamics could be used as a natural basis for rigorous deduction of well-known quasi-chemical approach ("chemical picture") in frames of asymptotic expansion (on temperature, but not density) around this reference system.

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