由EXAFS和中子PDF研究确定的La1-xSrxCoO3的局部结构
Local Structure of La1-xSrxCoO3 determined from EXAFS and neutron PDF studies
摘要:
在4 <= T <= 330 K的温度下,采用扩展X射线吸收精细结构(EXAFS)和中子对分布函数分析相结合的局域结构技术,排除了La_(1-x)Sr_xCoO_3中Co位的大部分Co键的Jahn-Teller(JT)畸变(x <= 0.35),表明存在很少的JT活性的、单占据的e_g Co位。
英文摘要:
The combined local structure techniques, extended x-ray absorption fine structure (EXAFS) and neutron pair distribution function analysis, have been used for temperatures 4 <= T <= 330 K to rule out a large Jahn-Teller (JT) distortion of the Co-O bond in La1-xSrxCoO3 for a significant fraction of Co sites (x <= 0.35), indicating few, if any, JT-active, singly occupied e_g Co sites exist.
机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。