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arXiv 0902.0343cond-mat.str-el
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由EXAFS和中子PDF研究确定的La1-xSrxCoO3的局部结构

Local Structure of La1-xSrxCoO3 determined from EXAFS and neutron PDF studies

N. Sundaram, Y. Jiang, I. E. Anderson, D. P. Belanger, C. H. Booth, F. Bridges, J. F. Mitchell, Th. Proffen, H. Zheng

摘要:

在4 <= T <= 330 K的温度下,采用扩展X射线吸收精细结构(EXAFS)和中子对分布函数分析相结合的局域结构技术,排除了La_(1-x)Sr_xCoO_3中Co位的大部分Co键的Jahn-Teller(JT)畸变(x <= 0.35),表明存在很少的JT活性的、单占据的e_g Co位。

英文摘要:

The combined local structure techniques, extended x-ray absorption fine structure (EXAFS) and neutron pair distribution function analysis, have been used for temperatures 4 <= T <= 330 K to rule out a large Jahn-Teller (JT) distortion of the Co-O bond in La1-xSrxCoO3 for a significant fraction of Co sites (x <= 0.35), indicating few, if any, JT-active, singly occupied e_g Co sites exist.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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