我们研究了$A_2$ CoSi $_2$ O $_7$($A$ =Ca,Sr,Ba)晶体的磁性和介电性能,该晶体由CoO $_4$和SiO $_4$四面体通过角部相互连接而成二维网络.在Ca $_2$ CoSi $_2$ O $_7$中,在5.7 K下发生弱铁磁转变,其中平行于c轴的介电常数显示伴随的异常。在5.7 K以下观察到大的磁电容效应,在5.1 K时$Δ\varepsilon (H)/\varepsilon (0) \equiv [\varepsilon (H)-\varepsilon (0)]/\varepsilon (0)$达到13%.这些结果表明在Ca $_2$ CoSi $_2$ O $_7$中磁性和介电性之间存在强耦合。Sr $_2$ CoSi $_2$ O $_7$表现出与Ca $_2$ CoSi $_2$ O $_7$类似的磁电行为。相反,在Ba $_2$ CoSi $_2$ O $_7$中,其具有与Ca $_2$ CoSi $_2$ O $_7$不同的SiO $_4$和CoO $_4$四面体排列,几乎观察不到磁电容。$A_2$ CoSi $_2$ O $_7$的准二维晶体结构是其磁电容效应的关键。
英文摘要:
We have investigated the magnetic and dielectric properties of $A_2$CoSi$_2$O$_7$ ($A$=Ca, Sr, and Ba) crystals with a two-dimensional network of CoO$_4$ and SiO$_4$ tetrahedra connected with each other through the corners. In Ca$_2$CoSi$_2$O$_7$, a weak ferromagnetic transition occurs at 5.7 K, where the dielectric constant parallel to the c axis shows a concomitant anomaly. The large magnetocapacitance effect is observed below 5.7 K; $Δ\varepsilon (H)/\varepsilon (0) \equiv [\varepsilon (H)-\varepsilon (0)]/\varepsilon (0)$ reaches 13 % at 5.1 K\@. These results indicate a strong coupling between the magnetism and dielectricity in Ca$_2$CoSi$_2$O$_7$. Sr$_2$CoSi$_2$O$_7$ shows a similar magnetoelectric behavior to that of Ca$_2$CoSi$_2$O$_7$. In contrast, in Ba$_2$CoSi$_2$O$_7$, which has the different arrangement of SiO$_4$ and CoO$_4$ tetrahedra from that of Ca$_2$CoSi$_2$O$_7$, the magnetocapacitance is hardly observed. The key for the magnetocapacitance effect of $A_2$CoSi$_2$O$_7$ lies in the quasi-two-dimensional crystal structure.
Magnetic and dielectric investigations of $γ$ - Fe${_2}$WO${_6}$
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