Competition of magnetism and superconductivity in underdoped (Ba1-xKx)Fe2As2
Marianne Rotter, Marcus Tegel, Inga Schellenberg, Falko M. Schappacher, Rainer Poettgen, Joachim Deisenhofer, Axel Guenther, Florian Schrettle, Alois Loidl, Dirk Johrendt
Polycrystalline samples of underdoped (Ba1-xKx)Fe2As2 (x<=0.4) were synthesized and studied by x-ray powder diffraction, magnetic susceptibility, specific heat and 57Fe-Moessbauer-spectroscopy. The structural phase transition from tetragonal to orthorhombic lattice symmetry shifts towards lower temperatures, becomes less pronounced at x = 0.1-0.2 and is no longer present at x = 0.3. Bulk superconductivity is observed in all samples except (Ba0.9K0.1)Fe2As2 by resistivity and magnetic susceptibility measurements. Specific heat data show a broad SDW phase transition in (Ba0.9K0.1)Fe2As2, which is hardly discernible in (Ba0.8K0.2)Fe2As2. No SDW anomaly is found in the specific heat of optimally doped (Ba0.6K0.4)Fe2As2, where C changes by 0.1 J/K at Tc = 37.3 K. 57Fe-Moessbauer-spectra show full magnetic hyperfine field splitting, indicative of antiferromagnetic ordering at 4.2 K in samples with x = 0-0.2, but zero magnetic hyperfine field in samples with x = 0.3. The spectra of (Ba0.9K0.1)Fe2As2 and (Ba0.8K0.2)Fe2As2 in the phase transition regions are temperature-dependent superpositions of magnetic and non-magnetic components, caused by inhomogeneous potassium distribution. Our results suggest the co-existence of AF magnetic ordering and superconductivity without mesoscopic phase separation in the underdoped region and show unambiguously homogeneous superconducting phases close to optimal doping. This is in contrast to recently reported results about single crystal (Ba1-xKx)Fe2As2.
It is widely believed that, in contrast to its electron doped counterparts, the hole doped compound Ba1-xKxFe2As2 exhibits a mesoscopic phase separation of magnetism and superconductivity in the underdoped region of the phase diagram. Here, we report a combined high-resolution x-ray powder diffraction and volume sensitive muon spin rotation study of underdoped Ba1-xKxFe2As2 (0 \leq x \leq 0.25) showing that this paradigm is wrong. Instead we find a microscopic coexistence of the two forms of order. A competition of magnetism and superconductivity is evident from a significant reduction of the …
The thermal conductivity kappa of the iron-arsenide superconductor Ba1-xKxFe2As2 was measured for heat currents parallel and perpendicular to the tetragonal c axis at temperatures down to 50 mK and in magnetic fields up to 15 T. Measurements were performed on samples with compositions ranging from optimal doping (x = 0.34; Tc = 39 K) down to dopings deep into the region where antiferromagnetic order coexists with superconductivity (x = 0.16; Tc = 7 K). In zero field, there is no residual linear term in kappa(T) as T goes to 0 at any doping, whether for in-plane or inter-plane transport. This s…
We have synthesized the polycrystalline samples of Eu1-xKxFe2As2 (x = 0-1) and carried out systematic characterization using x-ray diffraction, ac & dc magnetic susceptibility, and electrical resistivity measurements. We have seen a clear signature of the coexistence of superconducting transition (Tc = 5.5 K) with SDW ordering in our under doped sample viz. x = 0.15. The spin density wave transition observed in EuFe2As2 get completely suppressed at x = 0.3 and superconductivity arises below 20 K. Superconducting transition temperature Tc increases with increase in K content and a maximum Tc = …
Using muon spin rotation and infrared spectroscopy we study the relation between magnetism and superconductivity in Ba$ _{1-x} $K$ _{x} $Fe$ _{2} $As$ _{2} $ single crystals from the underdoped to the slightly overdoped regime. We find that the Fe magnetic moment is only moderately suppressed in most of the underdoped region where it decreases more slowly than the Néel-temperature, $ T^{\mathrm{N}} $. This applies for both the total Fe moment obtained from muon spin rotation and for the itinerant component that is deduced from the spectral weight of the spin-density-wave pair breaking peak in …
We review the recent developments in the field of cuprate superconductors with the special focus on the recently observed charge order in the underdoped compounds. We introduce new theoretical developments following the study of the antiferromagnetic (AF) quantum critical point (QCP) in two dimensions, in which preemptive orders in the charge and superconducting (SC) sectors emerged, that are in turn related by an SU(2) symmetry. We consider the implications of this proliferation of orders in the underdoped region, and provide a study of the type of fluctuations which characterize the SU(2) sy…
The response of superconductors to controlled introduction of point-like disorder is an important tool to probe their microscopic electronic collective behavior. In the case of iron-based superconductors (IBS), magnetic fluctuations presumably play an important role in inducing high temperature superconductivity. In some cases, these two seemingly incompatible orders coexist microscopically. Therefore, understanding how this unique coexistence state is affected by disorder can provide important information about the microscopic mechanisms involved. In one of the most studied pnictide family, h…
Understanding the overall features of magnetic excitation is essential for clarifying the mechanism of Cooper pair formation in iron-based superconductors. In particular, clarifying the relationship between magnetism and superconductivity is a central challenge because magnetism may play a key role in their exotic superconductivity. BaFe2As2 is one of ideal systems for such investigation because its superconductivity can be induced in several ways, allowing a comparative examination. Here we report a study on the spin fluctuations of the hole-overdoped iron-based superconductors Ba1-xKxFe2As2 …
Evidence for Static Magnetism in the Vortex Cores of Ortho-II YBa$_2$Cu$_3$O$_{6.50}$
报道了欠掺杂$_2$ O $_{6+x}$涡旋芯中存在静态交变磁场的证据。在$H = 1$ T和$H = 4$ T的外加磁场中测量了YBa $_2$ Cu $_3$ O $_{6.50}$涡旋态的内部磁场分布，发现了高场尾部磁场分布的一个特征，这一特征在最佳掺杂的YBa $_2$ Cu $_3$ O $_{6.95}$中不存在，并且很好地符合涡旋核中具有静态磁场的模型。场的大小估计为18（2）G，并在$T = 10$ K以上减小。我们在现有理论的背景下讨论了额外的涡核磁性的可能起源。
The iron-based superconductor FeSe offers a unique possibility to study the interplay of superconductivity with purely nematic as well magnetic-nematic order by pressure (p) tuning. By measuring specific heat under p up to 2.36GPa, we study the multiple phases in FeSe using a thermodynamic probe. We conclude that superconductivity is bulk across the entire p range and competes with magnetism. Our analysis suggests that superconducting and magnetic fluctuations exist over a wide temperature range above the respective bulk transition temperatures, whenever magnetism is present. These observation…
The connection between superconducting phase correlations and spin excitations in YBa$_2$Cu$_3$O$_{6.6}$: A magnetic field study
高转变温度（高- $T_c$）超导体最引人注目的普遍性质之一是它们都是由其绝缘反铁磁（AF）母体化合物的空穴掺杂衍生的。从一开始，这些铜氧化物中磁性和超导性之间的密切关系就引起了研究人员的兴趣。这种联系的证据来自中子散射实验，表明在铜氧化物超导体中存在明确的短程AF相关性（激发）。即便如此，这种激发在配对机制和超导性中的作用仍然是一个有争议的话题。对于$_2$ Cu $_3$ O $_{6+x}$，其中$x$控制空穴掺杂水平，磁激发谱中最突出的特征是"共振“。在这里，我们表明，对于欠掺杂的YBa $_2$铜$_3$ O $_{6.6}$，其中$x$和$T_c$低于最佳值，适度的磁场抑制共振显着，更是如此的领域近似垂直，而不是平行于CuO $_2$平面。我们的结果表明，共振措施配对和相位相干，表明磁性在铜酸盐的超导电性中起着重要的作用。高于$T_c$的场效应的持久性有利于在低掺杂铜酸盐的正常状态下具有预形成对的机制。
The structural, electronic, magnetic, and vibrational properties of LaFeSiH$_x$ for $x$ between 0 and 1 are investigated using density functional calculations. We find that the electronic and magnetic properties are strongly controlled by the hydrogen concentration $x$ in LaFeSiH$_x$. While fully hydrogenated LaFeSiH has a striped antiferromagnetic ground state, the underdoped LaFeSiH$_x$ for $x\leq0.75$ is not magnetic within the virtual crystal approximation or with explicit doping of supercells. The antiferromagnetic configuration breaks the symmetry of Fe $d$ orbitals and increases electro…
We measured the optical conductivity of superconducting single crystals of Ba$_{1-x}$K$_{x}$Fe$_{2}$As$_{2}$ with $x$ ranging from 0.40 (optimal doping, $T_c = 39$ K) down to 0.20 (underdoped, $T_c = 16$ K), where a magnetic order coexists with superconductivity. In the normal state, the low-frequency optical conductivity can be described by an incoherent broad Drude component and a coherent narrow Drude component: the broad one is doping-independent, while the narrow one shows strong scattering in the heavily underdoped compound. In the superconducting state, the formation of the condensate l…
We report results of a muon spin relaxation study of slow magnetic fluctuations in the pseudogap phase of underdoped single-crystalline YBa$_{2}$Cu$_{3}$O$_{y}$, $y = 6.77$ and 6.83. The dependence of the dynamic muon spin relaxation rate on applied magnetic field yields the rms magnitude~$B\mathrm{_{loc}^{rms}}$ and correlation time~$τ_c$ of fluctuating local fields at muon sites. The observed relaxation rates do not decrease with decreasing temperature~$T$ below the pseudogap onset at $T^\ast$, as would be expected for a conventional magnetic transition; both $B\mathrm{_{loc}^{rms}}$ and $τ_…
Using polarized neutron diffraction and x-ray resonant magnetic scattering (XRMS) techniques, multiple phase transitions were revealed in an underdoped, non-superconducting Eu(Fe$_{1-x}$Ir$_{x}$)$_{2}$As$_{2}$ ($\mathit{x}$ = 0.06) single crystal. Compared with the parent compound EuFe$_{2}$As$_{2}$, the tetragonal-to-orthorhombic structural phase transition and the antiferromagnetic order of the Fe$^{2+}$ moments are significantly suppressed to $\mathit{T_{S}}$ = 111 (2) K and $\mathit{T_{N,Fe}}$= 85 (2) K by 6% Ir doping, respectively. In addition, the Eu$^{2+}$ spins order within the $\math…
Zn-induced wipeout effect on Cu NQR spectra in La$_{2-x}$Sr$_x$Cu$_{1-y}$Zn$_y$O$_4$
本文系统地研究了Zn取代对高$T_c$超导体La $_{2-x}$ Sr $_x$ Cu $_{1-y}$ Zn $_y$ O $_4$从载流子欠掺杂到过掺杂的NQR谱的影响（多晶样品，$x$ =0.10、0.15和0.20）。我们没有观察到明显的wipeout效应的过掺杂的样品，一个渐进的和部分的wipeout效应低于约80 K的最佳掺杂的，和非常突然的和完全的wipeout效应低于约40 K的欠掺杂的。擦除效应表明在低频率下的Cu自旋波动的高度增强的光谱权重。我们将擦除效应与远高于40 K的Zn诱导局部磁性和低于40 K的局部化效应相关联。
We present $^{75}$As Nuclear Magnetic and Quadrupole Resonance results (NMR, NQR) on a new set of LaFeAsO$_{1-x}$F$_x$ polycrystalline samples. Improved synthesis conditions led to more homogenized samples with better control of the fluorine content. The structural$\equiv$nematic, magnetic, and superconducting transition temperatures have been determined by NMR spin-lattice relaxation rate and AC susceptibility measurements. The so-determined phase diagram deviates from the published one especially for low F-doping concentrations. However, if the doping level is determined from the NQR spectra…
Despite decades of intense researches, the enigmatic pseudo-gap (PG) phase of superconducting cuprates remains an unsolved mystery. In the last 15 years, various symmetry breakings in the PG state have been discovered, spanning an intra-unit cell (IUC) magnetism, preserving the lattice translational (LT) symmetry but breaking time-reversal symmetry and parity, and an additional incipient charge density wave breaking the LT symmetry upon cooling. However, none of these states can (alone) account for the partial gapping of the Fermi surface. Here we report a hidden LT-breaking magnetism uisng po…
Cu Nuclear Quadrupole Resonance Study of La_{2-x}Sr_xCu_{1-y}Zn_yO_4 (x=0.10, 0.15 and 0.20): Zn-induced Wipeout Effect near the Magnetic and Electric Instability
Emergent Coherence at the Edge of Magnetism: Low-Doped La2-xSrxCuO4+delta Revisited
B. Verkin Institute for Low Temperature Physics and Engineering of the Nat. Acad. of Sciences of Ukraine（乌克兰国家科学院低溫物理與工程B·維爾金研究所）；Smart Materials Group, Mads Clausen Institute, University of Southern Denmark, Sønderborg（南丹麦大学马茨·克拉斯恩学院智能材料组）；National Technical University «Kharkiv Polytechnic Institute», Kharkiv, Ukraine（乌克兰哈尔科夫国立技术大学（哈尔科夫理工学院））
Understanding the interplay between nematicity, magnetism and superconductivity is pivotal for elucidating the physics of iron-based superconductors. Here we use neutron scattering to probe magnetic and nematic orders throughout the phase diagram of NaFe$_{1-x}$Ni$_x$As, finding that while both static antiferromagnetic and nematic orders compete with superconductivity, the onset temperatures for these two orders remain well-separated approaching the putative quantum critical points. We uncover local orthorhombic distortions that persist well above the tetragonal-to-orthorhombic structural tran…
