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arXiv 0812.2747cond-mat.mtrl-sci
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富锶镍酸盐La2-xSrxNiO4 -δ(x = 1和1.4)的高温氧非化学计量、电导率和结构

High-temperature oxygen non-stoichiometry, conductivity and structure in strontium-rich nickelates La2-xSrxNiO4-δ(x = 1 and 1.4)

Leonid V. Makhnach, Vladimir V. Pankov, Pierre Strobel

摘要:

在20-1050 ℃温度范围内,研究了高Sr取代量(1 =< x =< 1.4)的La_(2-x)Sr_xNiO_(4-δ)相在空气和氧气气氛中的氧非化学计量比、电导率和热膨胀。这些相保留了La 2NiO 4的K2 NiF 4型结构(四重晶系,空间群I4/mmm)。的氧空位分数的测定独立于热重和中子衍射实验,并发现加热时大大增加。其电阻率、热膨胀系数和晶胞参数随温度的变化具有特殊的规律,与La_2NiO_4 $\pm$ δ有明显的区别。这些变化与镍氧化态的演变有关,镍氧化态在加热时从Ni 3 +/Ni 4+过渡到Ni 2 +/Ni 3+平衡。

英文摘要:

Oxygen nonstoichiometry, electrical conductivity and thermal expansion of La2 xSrxNiO4-δphases with high levels of strontium substitution (1 =< x =< 1.4) have been investigated in air and oxygen atmosphere in the temperature range 20-1050 degrees C. These phases retain the K2NiF4-type structure of La2NiO4 (tetragonal, space group I4/mmm). The oxygen vacancy fraction was determined independently from thermogravimetric and neutron diffraction experiments, and is found to increase considerably on heating. The electrical resistivity, thermal expansion and cell parameters with temperature show peculiar variations with temperature, and differ notably from La2NiO4$\pm$δin this respect. These variations are tentatively correlated with the evolution of nickel oxidation state, which crosses from a Ni3+/Ni4+ to a Ni2+/Ni3+ equilibrium on heating.

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