We show that the chirality of artificial media, made of a planar periodic arrangement of three-dimensional metallic meta-atoms, can be tailored. The meta-atoms support localized plasmon polaritons and exhibit a chirality exceeding that of pseudo-planar chiral metamaterials by an order of magnitude. Two design approaches are investigated in detail. The first is the referential example for a chiral structure, namely a Moebius strip. The second example is a cut wire - split-ring resonator geometry that can be manufactured with state-of-the-art nanofabrication technologies. Driven into resonance these meta-atoms evoke a polarization rotation of $30^\circ$ per unit cell.
Intrinsic chirality of dielectric metasurfaces unlocked by resonant chiral modes
Australian National University（澳大利亚国立大学）；Indian Institute of Technology Bombay（印度理工学院孟买分校）；University of Wisconsin-Madison（威斯康星大学麦迪逊分校）；Istanbul University（伊斯坦布尔大学）
Chirality is a ubiquitous phenomenon in the natural world. Many biomolecules without inversion symmetry such as amino acids and sugars are chiral molecules. Measuring and controlling molecular chirality at a high precision down to the atomic scale are highly desired in physics, chemistry, biology, and medicine, however, have remained challenging. Herein, we achieve all-optical reconfigurable chiral meta-molecules experimentally using metallic and dielectric colloidal particles as artificial atoms or building blocks to serve at least two purposes. One is that the on-demand meta-molecules with s…
Optical metasurfaces with high-Q chiral resonances can boost light-matter interaction for various applications of chiral response for ultrathin, active, and nonlinear metadevices. Usually, such metasurfaces require sophisticated depth-resolved nanofabrication to realize subwavelength stereo-nanostructures, posing overwhelming challenges, especially in the short-wavelength range. Here, we suggest a novel planar design for chiral metasurfaces supporting bound states in the continuum (BICs) and demonstrate experimentally chiroptical responses with record-high Q-factors (Q=390) and near-perfect ci…
The combination of gain and loss in optical systems that respect parity-time (PT)-symmetry has pointed recently to a variety of novel optical phenomena and possibilities. Many of them can be realized by combining the PT-symmetry concepts with metamaterials. Here we investigate the case of chiral metamaterials, showing that combination of chiral metamaterials with PT-symmetric gain-loss enables a very rich variety of phenomena and functionalities. Examining a simple one-dimensional chiral PT-symmetric system, we show that with normally incident waves the PT-symmetric and the chirality-related c…
Electromagnetic response of metallic rod dimers is theoretically calculated for arbitrary planar arrangement of rods in the dimer. It is shown that dimers without an in-plane symmetry axis exhibit elliptical dichroism and act as "atoms" in planar chiral metamaterials. Due to a very simple geometry of the rod dimer, such planar metamaterials are much easier in fabrication than conventional split-ring or gammadion-type structures, and lend themselves to a simple analytical treatment based on coupled dipole model. Dependencies of metamaterial's directional asymmetry on the dimer's geometry are es…
We present the new planar extrinsic chirality metamaterial (ECM) design that manifests giant circular dichroism (CD) in the visible spectrum range rather than usual near-infrared and terahertz range. Effects of incident beam angles and meta-molecules unit sizes on the CD spectrums were theoretically analyzed; Physical mechanism was illustrated in new figures of asymmetrical current excitation in neighboring unit cells.
Homogenization of metamaterials is a crucial issue as it allows to describe their optical response in terms of effective wave parameters as e.g. propagation constants. In this paper we consider the possible homogenization of chiral metamaterials. We show that for meta-atoms of a certain size a critical density exists above which increasing coupling between neighboring meta-atoms prevails a reasonable homogenization. On the contrary, a dilution in excess will induce features reminiscent to photonic crystals likewise prevailing a homogenization. Based on Bloch mode dispersion we introduce an ana…
Artificial magnetism, negative permeability and negative refractive index are demonstrated in 3D-chiral metamaterial that shows giant polarization rotation and circular dichroism.
Chiroptical effects, characterized by different optical responses for left- (LCP) and right- handed circularly polarized light (RCP), are powerful and valuable tools in optics with wide applications in polarization resolved imaging and sensing. Previously observed strong chiroptical effects are limited to metamaterials with complex three-dimensional chiral structures at the sub-wavelength scale. Although asymmetrical transmission of LCP and RCP have been investigated in planar chiral metasurfaces, the observed weak chiroptical effects result from anisotropic Ohmic dissipation of the metal cons…
We develop, from first principles, a general and compact formalism for predicting the electromagnetic response of a metamaterial with non-magnetic inclusions in the long wavelength limit, including spatial dispersion up to the second order. Specifically, by resorting to a suitable multiscale technique, we show that medium effective permittivity tensor and the first and second order tensors describing spatial dispersion can be evaluated by averaging suitable spatially rapidly-varying fields each satysifing electrostatic-like equations within the metamaterial unit cell. For metamaterials with ne…
Designing broadband enhanced chirality is of strong interest to the emerging fields of chiral chemistry and sensing, or to control the spin orbital momentum of photons in recently introduced nanophotonic chiral quantum and classical optical applications. However, chiral light-matter interactions have an extremely weak nature, are difficult to be controlled and enhanced, and cannot be made tunable or broadband. In addition, planar ultrathin nanophotonic structures to achieve strong, broadband, and tunable chirality at the technologically important visible to ultraviolet spectrum still remain el…
Single-photon transport in non-ideal chiral photon-atom interaction structures generally contains information backflow and thus limits the capabilities to transfer information between distant emitters in cascaded quantum networks. Here, in the non-ideal chiral case, a V -type atom coupled to a waveguide is proposed to realize completely unidirectional transmission of the single photons in a superposition state of different frequencies. A microwave field is introduced to drive the two excited states of the atom and results in photon conversion between two transitions. By adjusting the Rabi freq…
The solution of a boundary-value problem formulated for a modified Kretschmann configuration shows that the phase speed of a surface-plasmon wave guided by the planar interface of a sufficiently thin metal film and a chiral sculptured thin film (STF) depends on the vapor incidence angle used while fabricating the chiral STF by physical vapor depoistion. Therefore, it may be possible to engineer the phase speed quite simply by selecting an appropriate value of the vapor deposition angle (in addition to the metal and the evaporant species).
Chiral nanophotonic devices are promising candidates for chiral molecules sensing, polarization diverse nanophotonics and display technologies. Active chiral nanophotonic devices, where the optical chirality can be controlled by an external stimulus has triggered great research interest. However, efficient modulation of the optical chirality has been challenging. Here, we demonstrate switching of the extrinsic chirality by applied magnetic fields in a magneto-plasmonic metasurface device based on a magneto-optical oxide material, Ce1Y2Fe5O12 (Ce:YIG). Thanks to the low optical loss and strong …
We suggest that electromagnetic chirality, generally displayed by 3D or 2D complex chiral structures, can occur in 1D patterned composites whose components are achiral. This feature is highly unexpected in a 1D system which is geometrically achiral since its mirror image can always be superposed onto it by a 180 deg rotation. We analytically evaluate from first principles the bi-anisotropic response of multilayered metamaterials and we show that the chiral tensor is not vanishing if the system is geometrically one-dimensional chiral, i.e. its mirror image can not be superposed onto it by using…
We theoretically investigate the electromagnetic response of a novel class of multi-layered metamaterials obtained by alternating graphene sheets and dielectric layers, the whole structure not exhibiting a plane of reflection symmetry along the stacking direction. We show that the electromagnetic response of the structure is characterized by a magneto-electric coupling described by an effective chiral parameter. Exploiting the intrinsic tunability of the graphene-light coupling, we prove that one can tune both the dielectric and the chiral electromagnetic response by varying the graphene chemi…
Atoms are usually thought of as achiral objects. However, one can construct superpositions of atomic states that are chiral [1]. Here we show how to excite such superpositions with tailored light fields both in the weak-field and strong-field regimes, using realistic laser parameters. First, we use time-dependent Schrodinger equation (TDSE) simulations to demonstrate the creation of a time-dependent bound chiral wavepacket in sodium atoms. Second, we show how the time-dependent handedness of this wavepacket can be probed by photoelectron circular dichroism, in spite of the central symmetry of …
Optical systems with gain and loss that respect Parity-Time (PT) symmetry can have real eigenvalues despite their non-Hermitian character. Chiral systems impose circularly polarized waves which do not preserve their handedness under the combined space- and time- reversal operations and, as a result, seem to be incompatible with systems possessing PT symmetry. Nevertheless, in this work we show that in certain configurations, PT symmetric permittivity, permeability and chirality is possible; in addition, real eigenvalues are maintained even if the chirality goes well beyond PT symmetry. By obta…
The planar interface of a metal and a hyperbolic, dielectric, structurally chiral material can support the propagation of none, one, or multiple surface-plasmon-polariton (SPP) waves, at a specified frequency and along a specified direction in the interface plane. When multiple SPP waves can exist, they differ in phase speed, propagation length, degree of localization to the interface, and spatial profiles of the associated electromagnetic fields.
Chiral edge currents play an important role in characterizing topological matter. In atoms, they have been observed at such a low temperature that the atomic motion can be measured. Here we report the first experimental observation of chiral edge currents in atoms at room temperature. Staggered magnetic fluxes are induced by the spatial phase difference between two standing-wave light fields, which couple atoms to form a momentum-space zigzag superradiance lattice. The chiral edge currents have been measured by comparing the directional superradiant emissions of two timed Dicke states in the l…
We demonstrate that rotationally symmetric chiral metasurfaces can support arbitrarily sharp resonances with the maximum optical chirality determined by precise shaping of bound states in the continuum (BICs). Being uncoupled from one circular polarisation of light and resonantly coupled to its counterpart, a metasurface hosting the chiral BIC resonance exhibits a narrow peak in the circular dichroism spectrum. We propose a realization of such chiral BIC metasurfaces based on pairs of dielectric bars and validate the concept of maximum chirality by numerical simulations
Electromagnetic waves impinging on three-dimensional helical metallic metamaterials have been shown to exhibit chiral effects of large magnitude both theoretically and in experimental realizations. Chirality here describes different responses of scatterers, materials, or metamaterials to left and right circularly polarized electromagnetic waves. These differences can be quantified in terms of electromagnetic chirality measures. In this work we consider the optimal design of thin metallic free-form nanowires that possess measures of electromagnetic chirality as large as fundamentally possible. …
We consider the optical dipole potential energy, which arises from the interaction of a two-level atom with a circularly polarized Laguerre-Gaussian laser beam of small waist. The beam is characterized by the existence of a longitudinal electric field component which is responsible for the appearance of a chiral term in the optical dipole potential energy. This term reverses sign if either the winding number or the wave polarization of the beam reverses sign. We propose a scheme of a bi-chromatic vortex interaction with the two-level atom in which the resulting optical dipole potential is full…
We demonstrate a superconducting artificial atom with strong unidirectional coupling to a microwave photonic waveguide. Our artificial atom is realized by coupling a transmon qubit to the waveguide at two spatially separated points with time-modulated interactions. Direction-sensitive interference arising from the parametric couplings in our scheme results in a non-reciprocal response, where we measure a forward/backward ratio of spontaneous emission exceeding 100. We verify the quantum nonlinear behavior of this artificial chiral atom by measuring the resonance fluorescence spectrum under a s…
Chiral surface plasmon polaritons (SPPs) can be generated by linearly polarized light incident at the end of a nanowire, exciting a coherent superposition of three specific nanowire waveguide modes. Images of chiral SPPs on individual nanowires obtained from quantum dot fluorescence excited by the SPP evanescent field reveal the chirality predicted in our theoretical model. The handedness and spatial extent of the helical periods of the chiral SPPs depend on the input polarization angle and nanowire diameter as well as the dielectric environment. Chirality is preserved in the free-space output…
Fine control of the chiral light-matter interaction at the nanoscale, by exploiting designed metamaterial architecture, represents a cutting-edge craft in the field of biosensing, quantum and classic nanophotonics. Recently, artificially engineered 3D nanohelices have demonstrated programmable wide chiroptical properties by tuning materials and architecture, but fundamental diffractive aspects that are to the origin of chiral resonances still remain elusive. Here, we proposed a novel concept of three-dimensional chiral MetaCrystal, where the chiroptical properties are finely tuned by in-plane …
Emitter ensembles interact collectively with the radiation field. In the case of a one-dimensional array of atoms near a nanofiber, this collective light-matter interaction does not only lead to an increased photon coupling to the guided modes within the fiber, but also to a drastic enhancement of the chirality in the photon emission. We show that near-perfect chirality is already achieved for moderately-sized ensembles, containing 10 to 15 atoms. This is of importance for developing an efficient interface between atoms and waveguide structures with unidirectional coupling, with applications i…
Kirigami-based Flexible Metasurface with Reconfigurable Intrinsic Chirality from Zero to Near-unity
The Hong Kong University of Science and Technology (Guangzhou)（香港科技大学（广州））；Low Altitude Systems and Economy Research Institute, The Hong Kong University of Science and Technology (Guangzhou)（香港科技大学（广州）低空经济与系统研究院）；Wuhan University of Technology（武汉理工大学）
The solution of a boundary-value problem formulated for a modified Kretschmann configuration shows that a surface-plasmon wave can be excited at the planar interface of a sufficiently thin metal film and a nondissipative structurally chiral medium, provided the exciting plane wave is p-polarized. An estimate of the wavenumber of the surface-plasmon wave also emerges thereby.
Chiral response is of tremendous importance to many fields, such as analytical chemistry, polarization manipulation and biological sensing. Here, a chiral metasurface based on rectangular holes is systematically investigated. The results show that the chirality is closely related to the size and the orientation of resonance unit. It is found that the period of the structure is always smaller than the wavelength at which chirality appears, which will provide a good basis for the design of chiral structures. More importantly, the CD is highly sensitive to the orientation of resonance unit. By ad…
Metasurfaces, the two-dimensional analogues of metamaterials, are ideal platforms for sensing molecular chirality at the nanoscale, e.g. of inclusions of natural optically active molecules, as they offer large accessible areas (they are essentially surfaces) and can accommodate the necessary strong resonances for coupling the probing radiation with the chiral inclusions. Here, we examine theoretically achiral isotropic metasurfaces, and we treat them as polarizable surfaces that support resonant electric and magnetic currents, which are coupled via the chiral inclusions. We derive analytically…
Recently, we proposed a metasurface design for chiral sensing that (i) results in enhanced chiroptical signals by more than two orders of magnitude for ultrathin, subwavelength, chiral samples over a uniform and accessible area, (ii) allows for complete measurements of the total chirality (magnitude and sign of both its real and imaginary part), and (iii) offers the possibility for a crucial signal reversal (excitation with reversed polarization) that enables chirality measurements in an absolute manner, i.e., without the need for sample removal. Our design is based on the anisotropic response…
We present the design of a chiral photonic quantum link, where distant atoms interact by exchanging photons propagating in a single direction in free-space. This is achieved by coupling each atom in a laser-assisted process to an atomic array acting as a quantum phased-array antenna. This provides a basic building block for quantum networks in free space, i.e. without requiring cavities or nanostructures, which we illustrate with high-fidelity quantum state transfer protocols. Our setup can be implemented with neutral atoms using Rydberg-dressed interactions.
The radiation of optically active (chiral) molecule placed near chiral nanoparticle is investigated. The optimal conditions for engineering of radiation of optically active (chiral) molecules with the help of chiral nanoparticles are derived. It is shown that for this purpose, the substance of the chiral particle must have both ε_and μ_negative (double negative material (DNG)) or negative μ_and positive ε_(μ_negative material (MNG)). Our results pave the way to an effective engineering of radiation of "left" and "right" molecules and to creating pure optical devices for separation of drugs ena…
We theoretically investigate measurement-based feedback control of a laser-driven one-dimensional atomic chain interfaced with a nanofiber. The interfacing leads to all-to-all interactions among the atomic emitters and induces chirality, i.e. the directional emission of photons into a preferred guided mode of the nanofiber. In the setting we consider, the measurement of guided light -- conducted either by photon counting or through homodyne detection of the photocurrent quadratures -- is fed back into the system through a modulation of the driving laser field. We investigate how this feedback …
A chiral metastructure composed of spatially separated double semi-periodic helices is proposed and investigated theoretically and experimentally in this Letter. Chirality-dependent electromagnetically induced transparency (EIT) and a slow light effect in the microwave region are observed from a numerical parameter study, while experimental results from the 3D printing sample yield good agreement with the theoretical findings. The studied EIT phenomenon arises as a result of destructive interference by coupled resonances, and the proposed chiral metastructure can be applied in areas such as po…
