We use speckle-visibility spectroscopy to measure the time-dependence of bubble rearrangement events that are driven by coarsening in an aqueous foam. This technique gives the time-trace for the average scattering site speed within a prescribed volume of the sample. Results are analyzed in terms of distributions of event times, event speeds, and event displacements. The distribution of rest times between successive events is also measured; comparison with diffusing-wave spectroscopy results shows that the spatial structure of a typical event consists of a core of only a few bubbles which undergo topology change plus a surrounding halo of bubbles which shift by an amount that decays to one wavelength at four to five bubbles away. No correlations are found between the durations, speeds, and rest times between successive events.
Aqueous foams are an important model system that displays coarsening dynamics. Coarsening in dispersions and foams is well understood in the dilute and dry limits, where the gas fraction tends to zero and one, respectively. However, foams are known to undergo a jamming transition from a fluid-like to a solid-like state at an intermediate gas fraction,$ϕ_c$. Much less is known about coarsening dynamics in wet foams near jamming, and the link to mechanical response, if any, remains poorly understood. Here, we probe coarsening and mechanical response using numerical simulations of a variant of th…
Foams are unstable jammed materials. They evolve over timescales comparable to their "time of use", which makes the study of their destabilisation mechanisms crucial for applications. In practice, many foams are made from viscoelastic fluids, which are observed to prolong their lifetimes. Despite their importance we lack understanding of the coarsening mechanism in such systems. We probe the effect of continuous phase viscoelasticity on foam coarsening with foamed emulsions. We show that bubble size evolution is strongly slowed down and foam structure hugely impacted. The main mechanisms respo…
We report on the statistics of bubble size, topology, and shape and on their role in the coarsening dynamics for foams consisting of bubbles compressed between two parallel plates. The design of the sample cell permits control of the liquid content, through a constant pressure condition set by the height of the foam above a liquid reservoir. We find that in the scaling state, all bubble distributions are independent not only of time but also of liquid content. For coarsening, the average rate decreases with liquid content due to the blocking of gas diffusion by Plateau borders inflated with li…
We use differential dynamic microscopy and particle tracking to determine the dynamical characteristics of a coarsening foam in reciprocal and direct space. At all wavevectors $q$ investigated, the intermediate scattering function exhibits a compressed exponential decay. However, the access to unprecedentedly small $q$s highlights the existence of two distinct regimes for the $q$-dependence of the foam relaxation rate $Γ(q)$. At any given foam age, $Γ(q)\sim q$ at high $q$, consistent with directionally-persistent and intermittent bubble displacements. At low $q$, we find $Γ(q) \sim q^{1.6}$. …
In this paper we report on bubble growth rates and on the statistics of bubble topology for the coarsening of a dry foam contained in the narrow gap between two hemispheres. By contrast with coarsening in flat space, where six-sided bubbles neither grow nor shrink, we observe that six sided bubbles grow with time at a rate that depends on their size. This result agrees with the modification to von Neumann's law predicted by J.E. Avron and D. Levine. For bubbles with a different number of sides, except possibly seven, there is too much noise in the growth rate data to demonstrate a difference w…
Under steady shear, a foam relaxes stress through intermittent rearrangements of bubbles accompanied by sudden drops in the stored elastic energy. We use a simple model of foam that incorporates both elasticity and dissipation to study the statistics of bubble rearrangements in terms of energy drops, the number of nearest neighbor changes, and the rate of neighbor-switching (T1) events. We do this for a two-dimensional system as a function of system size, shear rate, dissipation mechanism, and gas area fraction. We find that for dry foams, there is a well-defined quasistatic limit at low shear…
We study the topology and geometry of two dimensional coarsening foams with arbitrary liquid fraction. To interpolate between the dry limit described by von Neumann's law, and the wet limit described by Marqusee equation, the relevant bubble characteristics are the Plateau border radius and a new variable, the effective number of sides. We propose an equation for the individual bubble growth rate as the weighted sum of the growth through bubble-bubble interfaces and through bubble-Plateau borders interfaces. The resulting prediction is successfully tested, without adjustable parameter, using e…
Like emulsions, pastes and many other forms of soft condensed matter, aqueous foams present slow mechanical relaxations when subjected to a stress too small to induce any plastic flow. To identify the physical origin of this viscoelastic behaviour, we have simulated how dry disordered coarsening 2D foams respond to a small applied stress. We show that the mechanism of long time relaxation is driven by coarsening induced rearrangements of small bubble clusters. These findings are in full agreement with a scaling law previously derived from experimental creep data for 3D foams. Moreover, we find…
For dry foams, the transport of gas from small high-pressure bubbles to large low-pressure bubbles is dominated by diffusion across the thin soap films separating neighboring bubbles. For wetter foams, the film areas become smaller as the Plateau borders and vertices inflate with liquid. So-called "border-blocking" models can explain some features of wet-foam coarsening based on the presumption that the inflated borders totally block the gas flux, however, this approximation dramatically fails in the wet/unjamming limit where the bubbles become close-packed spheres and coarsening proceeds even…
We investigate the mechanical response of an aqueous foam, and its relation to the microscopic rearrangement dynamics of the bubble-packing structure. At rest, even though the foam is coarsening, the rheology is demonstrated to be linear. Under flow, shear-induced rearrangements compete with coarsening-induced rearrangements. The macroscopic consequences are captured by a novel rheological method in which a step-strain is superposed on an otherwise steady flow.
Using 2D numerical simulations as well as analytical modelling, we show how slow viscoelastic dynamics of aqueous foam are linked to coarsening induced intermittent bubble rearrangements. The macroscopic strain rate is expressed in terms of mesoscopic dynamics where local rearrangements are represented by strain fields induced by force dipoles. We relate these dipoles quantitatively to local geometrical features of the corresponding bubble rearrangements. We also explain how applying a small macroscopic stress biases the outcome of coarsening induced rearrangements.
We study diamagnetically levitated foams with widely different liquid fractions. Due to the levitation, drainage is effectively suppressed and the dynamics is driven by the coarsening of the foam bubbles. For dry foams, the bubble size increases as the square root of foam age, as expected from a generalized von Neumann law. At higher liquid content, the behavior changes to that of Ostwald ripening where the bubbles grow with the 1/3 power of the age. Using Diffusing Wave Spectroscopy we study the local dynamics in the different regimes and find diffusive behavior for dry foams and kinetic beha…
Foams are ideal model systems to study stress-driven dynamics, as stress-imbalances within the system are continuously generated by the coarsening process, which unlike thermal fluctuations, can be conveniently quantified by optical means. However, the high turbidity of foams generally hinders the detailed study of the temporal and spatial distribution of rearrangement events, such that definite assessments regarding their contribution to the overall dynamics could not be made so far. In this paper, we use novel light scattering techniques to measure the frequency and position of events within…
In wet liquid foams, slow diffusion of gas through bubble walls changes bubble pressure, volume and wall curvature. Large bubbles grow at the expenses of smaller ones. The smaller the bubble, the faster it shrinks. As the number of bubbles in a given volume decreases in time, the average bubble size increases: i.e. the foam coarsens. During coarsening, bubbles also move relative to each other, changing bubble topology and shape, while liquid moves within the regions separating the bubbles. Analyzing the combined effects of these mechanisms requires examining a volume with enough bubbles to pro…
Coarsening in foams made from the pure liquid crystal, 8CB, has been studied. The foam was made in the nematic phase ($\textrm{T} = 35 ^{\circ}\textrm{C}$) by bubbling nitrogen through the pure liquid crystal. The coarsening behavior was investigated at three temperatures; at $\textrm{T} = 22 ^{\circ}\textrm{C}$ and $33^{\circ}\textrm{C}$ in the smectic phase and at $\textrm{T} = 34^{\circ}\textrm{C}$ in the nematic phase. In smectic and nematic phases the mean bubble radius $<R>$ has been measured as a function of time $<R > \sim t^λ$. In classical wet soap foams the growth exponent is typica…
All prior applications of Diffusing-Wave Spectroscopy (DWS) to aqueous foams rely upon the assumption that the electric field of the detected light is a Gaussian random variable and that, hence, the Siegert relation applies. Here we test this crucial assumption by simultaneous measurement of both second and third-order temporal intensity correlations. We find that the electric field is Gaussian for typical experimental geometries equivalent to illumination and detection with a plane wave, both for backscattering and transmission through an optically-thick slab. However, we find that the Gaussi…
We present high-precision data for the time evolution of bubble area $A(t)$ and circularity shape parameter $C(t)$ for quasi-2d foams consisting of bubbles squashed between parallel plates. In order to fully compare with predictions by Roth et al. [Phys. Rev. E 87 2013] and Schimming et al. [Phys. Rev. E 96 2017], foam wetness is systematically varied by controlling the height of the sample above a liquid reservoir which in turn controls the radius $r$ of the inflation of the Plateau borders. For very dry foams, where the borders are very small, classic von Neumann behavior is observed where a…
We utilize total-internal reflection to isolate the two-dimensional `surface foam' formed at the planar boundary of a three-dimensional sample. The resulting images of surface Plateau borders are consistent with Plateau's laws for a truly two-dimensional foam. Samples are allowed to coarsen into a self-similar scaling state where statistical distributions are independent of time, except for an overall scale factor. There we find that statistical measures of side number distributions, size-topology correlations, and bubble shapes, are all very similar to those for two-dimensional foams. However…
In this paper, I study the coarsening dynamics of two-dimensional dry foam sandwiched by deformable membranes. The time-varying deformation of the confining membranes gives rise to a significant alteration in the evolution of polygonal cells of bubbles when compared to the case of rigid membranes. This alteration is attributed to the correlation between the rate of inter-cell gas transfer and temporal fluctuation in surface curvature within a cell domain. The existing material constants are referred to understand the utility of the correlation effect toward the artificial control of the coarse…
We used coherent light scattering in a multi-speckle detection scheme to investigate the mesoscale dynamics in aqueous foam. Time-resolved correlation of the scattered speckle intensities reveals the details of foam dynamics during aging. We introduce Temporal Contrast Analysis, a novel statistical tool that can be effective in characterizing structural rearrangements. Using Temporal Contrast Analysis we were able to detect two distinct dynamical components present during foam aging: spontaneous and intermittent, avalanche-like events and continuous, flow-like rearrangements in the foam struct…
Ultrastable foams with an optimal foamability have been obtained using hydroxyl fatty acids tubes. The stabilization results from the adsorption of monomers at the air-water interface preventing coalescence and coarsening and from the presence of tubes in the Plateau borders limiting the drainage. Upon heating, tubes transit to micelles, which induces foam destabilization. Such foams are thus the first to have a temperature tunable stability.
Many physical systems exhibit plastic flow when subjected to slow steady shear. A unified picture of plastic flow is still lacking; however, there is an emerging theoretical understanding of such flows based on irreversible motions of the constituent ``particles'' of the material. Depending on the specific system, various irreversible events have been studied, such as T1 events in foam and shear transformation zones (STZ's) in amorphous solids. This paper presents an experimental study of the T1 events in a model, two-dimensional foam: bubble rafts. In particular, I report on the connection be…
Plastic rearrangements play a crucial role in the characterization of soft-glassy materials, such as emulsions and foams. Based on numerical simulations of soft-glassy systems, we study the dynamics of plastic rearrangements at the hydrodynamic scales where thermal fluctuations can be neglected. Plastic rearrangements require an energy input, which can be either provided by external sources, or made available through time evolution in the coarsening dynamics, in which the total interfacial area decreases as a consequence of the slow evolution of the dispersed phase from smaller to large drople…
In the absence of coalescence, coarsening of emulsions (and foams) is controlled by molecular diffusion of dispersed phase between droplets/bubbles. Studies of dilute emulsions have shown how the osmotic pressure of a trapped species within droplets can ``osmotically stabilise'' the emulsion. Webster and Cates (Langmuir, 1998, 14, 2068-2079) gave rigorous criteria for osmotic stabilisation of mono- and polydisperse emulsions, in the dilute regime. We consider here whether analogous criteria exist for the osmotic stabilisation of mono- and polydisperse concentrated emulsions and foams, and sugg…
We simulate the shape relaxation of foam clusters and compare them with the time exponential expected for Newtonian fluid. Using two-dimensional Potts Model simulations, we artificially create holes in a foam cluster and shuffle it by applying shear strain cycles. We reproduce the experimentally observed time exponential relaxation of cavity shapes in the foam as a function of the number of strain steps. The cavity rounding up results from local rearrangement of bubbles, due to the conjunction of both a large applied strain and local bubble wall fluctuations.
Sheared wet foam, which stores elastic energy in bubble deformations, relaxes stress through bubble rearrangements. The intermittency of bubble rearrangements in foam leads to effectively stochastic drops in stress that are followed by periods of elastic increase. We investigate global characteristics of highly disordered foams over three decades of strain rate and almost two decades of system size. We characterize the behavior using a range of measures: average stress, distribution of stress drops, rate of stress drops, and a normalized fluctuation intensity. There is essentially no dependenc…
We detail the statistical distribution of bubble rearrangements in a sheared two-dimensional foam. Such rearrangements, known as T1 events, are vital to mechanisms resulting in flow through microscopic mechanical yielding. We find that at a constant rate of shear, the rate of occurrence of T1 events shows only small fluctuations. This rate is however seen to vary significantly with a variation in the initial configuration of bubbles constituting the foam. In addition, we detail the spatial and orientational distribution of T1 events and relate them to the distribution of stresses in the bulk o…
The macroscopic behaviour of foams is deeply related to rearrangements occurring at the bubble scale, which dynamics depends on the mobility of the interstitial phase. In this paper, we resort to drainage experiments to quantify this mobility in particulate foams, where a particle suspension is confined between foam bubbles. Results show a strong dependence on each investigated parameter, i.e. bubble size, particle size and gas volume fraction for a given particle volume fraction. A combination of these parameters has been identified as the control parameter λ, which compares the particle size…
The paper reports on the quasi-static steady flow of a dry liquid foam around a fixed spherical bead, few times larger than the typical bubble size. The force exerted on the bead is recorded with a precision and a time resolution large enough to show the succession of elastic loading of the foam, separated by sudden force drops. The foam structure is observed by direct light transmission, synchronized with the force measurement, thus allowing to correlate the plastic events with the force variations. Scaling laws for the force signal as a function of the bubble size are detailed and interprete…
We study the coarsening dynamics of a two dimensional system via lattice Boltzmann numerical simulations. The system under consideration is a biphasic system consisting of domains of a dispersed phase closely packed together in a continuous phase and separated by thin interfaces. Such system is elastic and typically out of equilibrium. The equilibrium state is attained via the coarsening dynamics, wherein the dispersed phase slowly diffuses through the interfaces, causing domains to change in size and eventually rearrange abruptly. The effect of rearrangements is propagated throughout the syst…
Many two-phase materials suffer from grain-growth due to the energy cost which is associated with the interface that separates both phases. While our understanding of the driving forces and the dynamics of grain growth in different materials is well advanced by now, current research efforts address the question of how this process may be slowed down, or, ideally, arrested. We use a model system of two bubbles to explore how the presence of a finite surface elasticity may interfere with the coarsening process and the final grain size distribution. Combining experiments and modelling in the anal…
We show by means of experiments, theory and simulations, that the slow dynamics of coarsening systems displays dynamic heterogeneity similar to that observed in glass-forming systems. We measure dynamic heterogeneity via novel multi-point functions which quantify the emergence of dynamic, as opposed to static, correlations of fluctuations. Experiments are performed on a coarsening foam using Time Resolved Correlation, a recently introduced light scattering method. Theoretically we study the Ising model, and present exact results in one dimension, and numerical results in two dimensions. For al…
The paper describes a study of wet foams in microgravity whose bubble size distribution evolves due to diffusive gas exchange. We focus on the comparison between the size of bubbles determined from images of the foam surface and the size of bubbles in the bulk foam, determined from Diffuse Transmission Spectroscopy (DTS). Extracting the bubble size distribution from images of a foam surface is difficult so we have used three different procedures : manual analysis, automatic analysis with a customized Python script and machine learning analysis. Once various pitfalls were identified and taken i…
We introduce a new dynamic light scattering method, termed photon correlation imaging, which enables us to resolve the dynamics of soft matter in space and time. We demonstrate photon correlation imaging by investigating the slow dynamics of a quasi two-dimensional coarsening foam made of highly packed, deformable bubbles and a rigid gel network formed by dilute, attractive colloidal particles. We find the dynamics of both systems to be determined by intermittent rearrangement events. For the foam, the rearrangements extend over a few bubbles, but a small dynamical correlation is observed up t…
We study the flow of a pressure-driven foam through a straight channel using numerical simulations, and examine the effects of a tuneable attractive potential between bubbles. This potential, which accounts for the effects of disjoining pressure in the liquid films between separating bubbles, is shown here to introduce jamming and stick-slip flow in a straight channel. We report on the behaviour of these new regimes by varying the strength of the attractive potential. It is seen that there is a force threshold below which the flow jams, and on increasing the driving force, a cross over from in…
Large-scale tissue deformation during biological processes such as morphogenesis requires cellular rearrangements. The simplest rearrangement in confluent cellular monolayers involves neighbor exchanges among four cells, called a T1 transition, in analogy to foams. But unlike foams, cells must execute a sequence of molecular processes, such as endocytosis of adhesion molecules, to complete a T1 transition. Such processes could take a long time compared to other timescales in the tissue. In this work, we incorporate this idea by augmenting vertex models to require a fixed, finite time for T1 tr…
Key features of the mechanical response of amorphous particulate materials, such as foams, emulsions, and granular media, to applied stress are determined by the frequency and size of particle rearrangements that occur as the system transitions from one mechanically stable state to another. This work describes coordinated experimental and computational studies of bubble rafts, which are quasi-two dimensional systems of bubbles confined to the air-water interface. We focus on small mechanically stable clusters of four, five, six, and seven bubbles with two different sizes with diameter ratio $σ…
Measurements of average velocity profiles in a bubble raft subjected to slow, steady-shear demonstrate the coexistence between a flowing state and a jammed state similar to that observed for three-dimensional foams and emulsions [Coussot {\it et al,}, Phys. Rev. Lett. {\bf 88}, 218301 (2002)]. For sufficiently slow shear, the flow is generated by nonlinear topological rearrangements. We report on the connection between this short-time motion of the bubbles and the long-time averages. We find that velocity profiles for individual rearrangement events fluctuate, but a smooth, average velocity is…
A fundamental difference between fluids and solids is their response to applied shear. Solids possess static shear moduli, while fluids do not. Complex fluids such as foams display an intermediate response to shear with nontrivial frequency-dependent shear moduli. In this manuscript, we conduct coordinated experiments and numerical simulations of model foams subjected to boundary-driven oscillatory, planar shear. Our studies are performed on bubble rafts (experiments) and the bubble model (simulations) in 2D. We focus on the low-amplitude flow regime in which T1 bubble rearrangement events do …
Discrete rearranging patterns include cellular patterns, for instance liquid foams, biological tissues, grains in polycrystals; assemblies of particles such as beads, granular materials, colloids, molecules, atoms; and interconnected networks. Such a pattern can be described as a list of links between neighbouring sites. Performing statistics on the links between neighbouring sites yields average quantities (hereafter "tools") as the result of direct measurements on images. These descriptive tools are flexible and suitable for various problems where quantitative measurements are required, whet…
We describe a multispeckle dynamic light scattering technique capable of resolving the motion of scattering sites in cases that this motion changes systematically with time. The method is based on the visibility of the speckle pattern formed by the scattered light as detected by a single exposure of a digital camera. Whereas previous multispeckle methods rely on correlations between images, here the connection with scattering site dynamics is made more simply in terms of the variance of intensity among the pixels of the camera for the specified exposure duration. The essence is that the speckl…
