In the interstellar clouds, molecular hydrogens are formed from atomic hydrogen on grain surfaces. An atomic hydrogen hops around till it finds another one with which it combines. This necessarily implies that the average recombination time, or equivalently, the effective grain surface area depends on the relative numbers of atomic hydrogen influx rate and the number of sites on the grain. Our aim is to discover this dependency. We perform a numerical simulation to study the recombination of hydrogen on grain surfaces in a variety of cloud conditions. We use a square lattice (with a periodic boundary condition) of various sizes on two types of grains, namely, amorphous carbon and olivine. We find that the steady state results of our simulation match very well with those obtained from a simpler analytical consideration provided the `effective' grain surface area is written as $\sim S^α$, where, $S$ is the actual physical grain area and $α$ is a function of the flux of atomic hydrogen which is determined from our simulation. We carry out the simulation for various astrophysically relevant accretion rates. For high accretion rates, small grains tend to become partly saturated with $H$ and $H_2$ and the subsequent accretion will be partly inhibited. For very low accretion rates, the number of sites to be swept before a molecular hydrogen can form is too large compared to the actual number of sites on the grain, implying that $α$ is greater than unity.
Molecular hydrogen has an important role in the early stages of star formation as well as in the production of many other molecules that have been detected in the interstellar medium. In this review we show that it is now possible to study the formation of molecular hydrogen in simulated astrophysical environments. Since the formation of molecular hydrogen is believed to take place on dust grains, we show that surface science techniques such as thermal desorption and time-of-flight can be used to measure the recombination efficiency, the kinetics of reaction and the dynamics of desorption. The…
Identification by the Ulysses spacecraft of interstellar grains inside the planetary system provides a new window for the study of diffuse interstellar matter. Dust particles observed by Ulysses and confirmed by Galileo are more massive ($\geq 10^{-13} {\rm g}$) than the 'classical' interstellar grains. Even bigger grains ($\approx 10^{-7} {\rm g}$) were observed in form of interstellar meteors. We analyze the consequences of the plentiful existence of massive grains in the diffuse interstellar medium. Astronomically observed 'classical' interstellar grains can be described by a size distribut…
Our current understanding of interstellar dust is summarized at an introductory level. Submicron-sized interstellar dust grains absorb and scatter light, and reradiate the absorbed energy in the infrared. The grain population spans a range of sizes, from molecules containing only tens of atoms, to particles containing 10^{10} atoms. Most of the grain mass appears to be due to two types of solid, in approximately equal amounts: amorphous silicate mineral, and carbonaceous material. Approximately 2/3 of the interstellar carbon in diffuse clouds is in solid form. Interstellar grains are important…
We use an updated self-consistent kinetic/gasdynamic model of the solar wind/interstellar flow interaction to compute the Lyman-alpha absorption by hydrogen atoms of both interstellar and solar origin generated in the heliospheric interface. We apply this model to the direction of the star Sirius. We show that the neutralized, compressed solar wind from the heliosheath explains the extra absorption at positive redshifts observed in the Lyman-alpha line with the HST/GHRS. This removes the need for the interstellar hot gas previously proposed to explain this extra absorption. We also show that e…
This review surveys the observed properties of interstellar dust grains: the wavelength-dependent extinction of starlight, including absorption features, from UV to IR; optical luminescence; IR emission; microwave emission; optical, UV, and X-ray scattering by dust; and polarization of starlight and of infrared emission. The relationship between presolar grains in meteorites and the interstellar grain population is discussed. Candidate grain materials and abundance constraints are considered. A dust model consisting of amorphous silicate grains, graphite grains, and PAHs is compared with obser…
We review the literature and present new experimental data to determine the amount of carbon likely to be locked in form of solid hydrogenated amorphous carbon (HAC) grains. We conclude on the basis of a thorough analysis of the intrinsic strength of the C-H stretching band at 3.4 micron that between 10 and 80 ppM H of carbon is in the form of HAC grains. We show that it is necessary to know the level of hydrogenation (H/C) of the interstellar HAC to determine more precisely the amount of carbon it ties up. We present optical constants, photoluminescence spectroscopy, and IR absorption spectro…
During the second flight of the ORFEUS-SPAS mission in November/December 1996, the Echelle spectrometer was used extensively by the Principal and Guest Investigator teams as one of the two focal plane instruments of the ORFEUS telescope. The spectrum of HD 93521 was obtained during this mission with a total integration time of 1740 s. This spectrum shows numerous sharp interstellar absorption lines. We identified 198 lines of molecular hydrogen including at least 7 lines with a high velocity component. Also most of the 67 identified interstellar metal lines are visible with a high velocity com…
This review summarizes the observational characteristics of those interstellar grains which are prevented from entering the solar system by interactions with the heliopause. Such grains are typically less tha 100nm in radius, and they reveal their presence by interstellar absorption at ultraviolet wavelengths and by non-equilibrium emissions in the red and near-infrared portions of the spectrum.
Radiative torques on irregular dust grains, in addition to producing superthermal rotation, play a direct dynamical role in the alignment of interstellar dust with the local magnetic field. The equations governing the orientation of spinning, precessing grains are derived; H_2 formation torques and paramagnetic dissipation are included in the dynamics. Stationary solutions (constant alignment angle and spin rate) are found; these solutions may be stable ("attractors") or unstable ("repellors"). The equations of motion are numerically integrated for three exemplary irregular grain geometries, e…
The year of 2005 marks the 75th anniversary since Trumpler (1930) provided the first definitive proof of interstellar grains by demonstrating the existence of general absorption and reddening of starlight in the galactic plane. This article reviews our progressive understanding of the nature of interstellar dust.
The in-situ detection of interstellar dust grains in the Solar System by the dust instruments on-board the Ulysses and Galileo spacecraft as well as the recent measurements of hyperbolic radar meteors give information on the properties of the interstellar solid particle population in the solar vicinity. Especially the distribution of grain masses is indicative of growth and destruction mechanisms that govern the grain evolution in the interstellar medium. The mass of an impacting dust grain is derived from its impact velocity and the amount of plasma generated by the impact. Because the initia…
The solar system is moving through the partially ionized local interstellar cloud (LIC). The ionized matter of the LIC interacts with the expanding solar wind forming the heliospheric interface. The neutral component (interstellar atoms) penetrates through the heliospheric interface into the heliosphere, where it is measured directly "in situ" as pick-up ions and neutral atoms (and as anomalous cosmic rays) or indirectly through resonant scattering of solar Ly-alpha. When crossing the heliospheric interface, interstellar atoms interact with the plasma component through charge exchange. This in…
A knowledge of the recombination time on the grain surfaces has been a major obstacle in deciding the production rate of molecular hydrogen and other molecules in the interstellar medium. We present a numerical study to compute this time for molecular hydrogen for various cloud and grain parameters. We also find the time dependence, particularly when a grain is freshly injected into the system. Apart from the fact that the recombination times seem to be functions of the grain parameters such as the activation barrier energy, temperature etc, our result also shows the dependence on the number o…
Interstellar medium is turbulent and this induces relative motions of dust grains. We calculate relative velocities of charged grains in a partially ionized magnetized gas. We account for anisotropy of magnetohydrodynamic (MHD) turbulence, grain coupling with magnetic field, and the turbulence cutoff arising from the ambipolar drag. We obtain grain velocities for turbulence with parameters consistent with those in HI and dark clouds. Those velocities are smaller than those in earlier papers, where MHD effects were disregarded. Finally, we compare grain velocities arising from photoelectric emi…
We have developed a model for molecular hydrogen formation under astrophysically relevant conditions. This model takes fully into account the presence of both physisorbed and chemisorbed sites on the surface, allows quantum mechanical diffusion as well as thermal hopping for absorbed H-atoms, and has been benchmarked versus recent laboratory experiments on H2 formation on silicate surfaces. The results show that H2 formation on grain surface is efficient in the interstellar medium up to some 300K. At low temperatures (<100K), H2 formation is governed by the reaction of a physisorbed H with a c…
A model of spheroidal particles is used to calculate the steady-state temperature of dust grains immersed in the interstellar radiation field. It is found that the temperature of non-spherical grains with the aspect ratios a/b <= 2 deviates from that of spheres less than 10%. More elongated or flattened particles are usually cooler than spheres of the same mass and in some cases the temperatures may differ by even about a factor of 2. The shape effects increase with the infrared absorptivity of the grain material and seem to be more important in dark interstellar clouds.
In interstellar dust grains, internal processes dissipate rotational kinetic energy. The dissipation is accompanied by thermal fluctuations, which transfer energy from the vibrational modes to rotation. Together, these processes are known as internal relaxation. For the past several years, internal relaxation has been thought to give rise to thermal flipping, with profound consequences for grain alignment theory. I show that thermal flipping is not possible in the limit that the inertia tensor does not vary with time.
By reevaluating a 13-month stretch of Ulysses SWICS H pickup ion measurements near 5 AU close to the ecliptic right after the previous solar minimum, this paper presents a determination of the neutral interstellar H density at the solar wind termination shock and implications for the density and ionization degree of hydrogen in the LIC. The density of neutral interstellar hydrogen at the termination shock was determined from the local pickup ion production rate as obtained close to the cut-off in the distribution function at aphelion of Ulysses. As shown in an analytical treatment for the upwi…
Observations of interstellar extinction and polarization indicate that the interstellar medium consists of aligned non-spherical dust grains which show variation in the interstellar extinction curve for wavelengths ranging from NIR to UV. To model the extinction and polarization, one cannot use the Mie theory which assumes the grains as solid spheres. We have used a T-matrix based method for computing the extinction efficiencies of spheroidal silicate and graphite grains of different shapes (axial ratios) and sizes and used these efficiencies to evaluate the interstellar extinction curve in th…
In this paper, we study heliospheric Ly-$α$ absorption toward nearby stars in different lines of sight. We use the Baranov-Malama model of the solar wind interaction with a two-component (charged component and H atoms) interstellar medium. Interstellar atoms are described kinetically in the model. The code allows us to separate the heliospheric absorption into two components, produced by H atoms originating in the hydrogen wall and heliosheath regions, respectively. We study the sensitivity of the heliospheric absorption to the assumed interstellar proton and H atom number densities. These the…
In the interstellar medium of the Milky Way, certain elements -- e.g., Mg, Si, Al, Ca, Ti, Fe -- reside predominantly in interstellar dust grains. These grains absorb, scatter, and emit electromagnetic radiation, heat the interstellar medium by photoelectric emission, play a role in the ionization balance of the gas, and catalyze the formation of molecules, particularly H2. I review the state of our knowledge of the composition and sizes of interstellar grains, including what we can learn from spectral features, luminescence, scattering, infrared emission, and observed gas-phase depletions. Th…
Our current understanding of the absorption and emission properties of interstellar grains are reviewed. The constraints placed by the Kramers-Kronig relation on the wavelength-dependence and the maximum allowable quantity of the dust absorption are discussed. Comparisons of the opacities (mass absorption coefficients) derived from interstellar dust models with those directly estimated from observations are presented.
The composite grain is made up of a host silicate spheroid and graphite inclusions. The extinction efficiencies of the composite spheroidal grains for three axial ratios are computed using the discrete dipole approximation (DDA). The interstellar extinction curve is evaluated in the spectral region 3.40--0.10$μm$ using the extinction efficiencies of the composite spheroidal grains. The model extinction curves are then compared with the average observed interstellar extinction curve. We also calculate the linear polarization for the spheroidal composite grains at three orientation angles and fi…
A photon of wavelength lambda ~1 micron interacting with a dust grain of radius a_p ~ 1 mm (a "pebble") undergoes scattering in the forward direction, largely within a small characteristic diffraction angle theta_s ~ lambda/a_p ~ 100". Though mm-size dust grains contribute negligibly to the interstellar medium's visual extinction, the signal they produce in scattered light may be detectable, especially for variable sources. Observations of light scattered at small angles allows for the direct measurement of the large grain population; variable sources can also yield tomographic information of …
Several mechanisms have been proposed to explain the alignment of grains with the interstellar magnetic field, including paramagnetic dissipation, radiative torques, and supersonic gas-grain streaming. These must compete with disaligning processes, including randomly directed torques arising from collisions with gas atoms. I describe a novel disalignment mechanism for grains that have a time-varying electric dipole moment and that drift across the magnetic field. Depending on the drift speed, this mechanism may yield a much shorter disalignment timescale than that associated with random gas at…
Nearby interstellar clouds with high (|v| >/= 10 km/s) random velocities although easily detected in NaI and CaII lines have hitherto not been detected (in emission or absorption) in the HI 21cm line. We describe here deep Giant Metrewave Radio Telescope (GMRT) HI absorption observations toward radio sources with small angular separation from bright O and B stars whose spectra reveal the presence of intervening high random velocity CaII absorbing clouds. In 5 out of the 14 directions searched we detect HI 21cm absorption features from these clouds. The mean optical depth of these detections is…
This Comment is in response to an Erratum to the paper entitled "The shape and composition of interstellar silicate grains" (Min et al., A&A, 462, 667-676 (2007). The Erratum corrects erroneously cited data but upholds the paper's original conclusions that GEMS are not remnant interstellar grains and that most GEMS formed in the early solar system. In our Comment, we show that the correct data in fact strengthen the relationship between GEMS and interstellar silicates, contrary to the conclusions of Min et al. in their Erratum. We also explore the validity of the isotopic and bulk chemical bas…
Recent observations with dust detectors on board the interplanetary spacecraft Ulysses and Galileo have recorded a substantial flux of large interstellar grains with radii between 0.25 and 2.0 mu entering the solar system from the local interstellar cloud. The most commonly used interstellar grain size distribution is characterized by a a^-3.5 power law in grain radii a, and extends to a maximum grain radius of 0.25 mu. The extension of the interstellar grain size distribution to such large radii will have a major effect on the median grain size, and on the amount of mass needed to be tied up …
In this paper we discuss the propagation of dust through the interstellar medium (ISM), and describe the destructive effects of stellar winds, jets, and supernova shock waves on interstellar dust. We review the probability that grains formed in stellar outflows or supernovae survive processing in and propagation through the ISM, and incorporate themselves relatively unprocessed into meteoritic bodies in the solar system. We show that very large (radii >= 5 micron) and very small grains (radii <= 100 Angstrom) with sizes similar to the pre-solar SiC and diamond grains extracted from meteorites,…
Irregular dust grains are subject to radiative torques when irradiated by interstellar starlight. It is shown how these radiative torques may be calculated using the discrete dipole approximation. Calculations are carried out for one irregular grain geometry, and three different grain sizes. It is shown that radiative torques can play an important dynamical role in spinup of interstellar dust grains, resulting in rotation rates which may exceed even those expected from H_2 formation on the grain surface. Because the radiative torque on an interstellar grain is determined by the overall grain g…
The temperatures of interstellar dust grains are analyzed using stochastic simulations, taking into account the grain composition and size and the discreteness of the photon flux. [...] The distribution of grain temperatures is calculated for a broad range of grain sizes and for different intensities of the interstellar radiation field, relevant to diffuse clouds and to PDRs. The dependence of the average grain temperature on its size is shown for different irradiation intensities. It is found that the average temperatures of grains with radii smaller than about 0.02 $μ$m are reduced due to th…
A solid-state feature was detected at around 2175 cm-1 towards 30 embedded young stellar objects in spectra obtained using the ESO VLT-ISAAC. We present results from laboratory studies of CO adsorbed at the surface of Zeolite wafers, where absorption bands were detected at 2177 and 2168 cm-1 (corresponding to CO chemisorbed at the Zeolite surface), and 2130 cm-1 (corresponding to CO physisorbed at the Zeolite surface), providing an excellent match to the observational data. We propose that the main carrier of the 2175-band is CO chemisorbed at bare surfaces of dust grains in the interstellar m…
The abundance of both amorphous and crystalline silicates in very small grains is limited by the fact that the 10 micron silicate emission feature is not detected in the diffuse ISM. On the basis of the observed IR emission spectrum for the diffuse ISM, the observed ultraviolet extinction curve, and the 10 micron silicate absorption profile, we obtain upper limits on the abundances of ultrasmall (a < 15 Angstrom) amorphous and crystalline silicate grains. Contrary to previous work, as much as ~20% of interstellar Si could be in a < 15 Angstrom silicate grains without violating observational co…
Semi-empirical molecular dynamics is used to simulate several gaseous atomic hydrogen interactions with hydrocarbon grains in space: recoil, adsorption, diffusion, chemisorption and recombination into molecular hydrogen. Their probabilities are determined by multiple numerical experiments, as a function of initial velocity of gas atoms. The equilibrium hydrogen coverage of free grains is then derived. These data can be used in calculations of material and energy balance as well as rates of hydrogen recombination on grains. The role of grain temperature is also considered.
Interstellar dust grains exhibit complex dynamics which is essential for understanding many key interstellar processes that involve dust, including grain alignment, grain growth, grain shattering etc. Grain rotational and translational motions are affected not only by gaseous collisions, but also by interactions with ions, photons, magnetic fields etc. Some of those interactions, e.g. interactions of ions with the dipole electric moment of dust grains, require the quantum nature of the process to be accounted for. Similarly, coupling of rotational and vibrational degrees of freedom in a grain …
We report the first detection of interstellar hydrogen fluoride. Using the Long Wavelength Spectrometer (LWS) of the Infrared Space Observatory (ISO), we have detected the 121.6973 micron J = 2 - 1 line of HF in absorption toward the far-infrared continuum source Sagittarius B2. The detection is statistically significant at the 13 sigma level. On the basis of our model for the excitation of HF in Sgr B2, the observed line equivalent width of 1.0 nm implies a hydrogen fluoride abundance of 3E-10 relative to H2. If the elemental abundance of fluorine in Sgr B2 is the same as that in the solar sy…
We study the evolution of molecular hydrogen on the grain surfaces and in the gas phase using both the rate equation (which tracks the average number of molecules) and the master equation (which tracks the expectation values of molecules). We show that above a certain critical accretion rate of $H$ on the grains, the results from these two methods become identical. We used this result to follow the collapse of a dense interstellar cloud and studied the formation of molecular hydrogen for two different temperatures (T=10K and 12K) and two different masses ($1M_\odot$ and $10M_\odot$) of the clo…
Spatial associations have been found between interstellar neutral hydrogen (HI) emission morphology and small-scale structure observed by the Wilkinson Microwave Anisotropy Probe (WMAP) in an area bounded by l = 60 & 180 deg, b = 30 & 70 deg, which was the primary target for this study. This area is marked by the presence of highly disturbed local HI and a preponderance of intermediate- and high-velocity gas. The HI distribution toward the brightest peaks in the WMAP Internal Linear Combination (ILC) map for this area is examined and by comparing with a second area on the sky it is demonstrate…
The interaction of dust grains originating from the local interstellar cloud with the environment inside the heliosphere is investigated. As a consequence of this interaction the spatial distribution of interstellar dust grains changes with time. Since dust grains are charged in the interplanetary plasma and radiation environment, the interaction of small grains with the heliosphere is dominated by their coupling to the solar wind magnetic field. The change of the field polarity with the solar cycle imposes a temporal variation of the spatial distribution and the flux of small (radius smaller …
We consider the depletion of elements from the interstellar gas onto a population of very small dust grains. Adopting a grain model in which of order 4% of the cosmic C abundance is in grains with radii <= 10 Angstroms, we find that the rate of accretion onto these grains is adequately fast to account for the observed large depletions of elements like Ti, without invoking unreasonably high rates of mass transfer between interstellar phases or low grain destruction rates. If these grains are composed of arene rings, then only a limited number of metal atoms can be locked up in them. The depleti…
The formation of molecular hydrogen in the interstellar medium takes place on the surfaces of dust grains. Hydrogen molecules play a role in gas-phase reactions that produce other molecules, some of which serve as coolants during gravitational collapse and star formation. Thus, the evaluation of the roduction rate of hydrogen molecules and its dependence on the physical conditions in the cloud are of great importance. Interstellar dust grains exhibit a broad size distribution in which the small grains capture most of the surface area. Recent studies have shown that the production efficiency st…
Interstellar shock waves can erode and destroy grains present in the shocked gas, primarily as the result of sputtering and grain-grain collisions. Uncertainties in current estimates of sputtering yields are reviewed. Results are presented for the simple case of sputtering of fast grains being stopped in cold gas. An upper limit is derived for sputtering of refractory grains in C-type MHD shocks: shock speeds $v_s \gtrsim 50 \kms$ are required for return of more than 30\% of the silicate to the gas phase. Sputtering can also be important for removing molecular ice mantles from grains in two-fl…
Although still poorly understood, the chemistry that occurs on the surfaces of interstellar dust particles profoundly affects the growth of molecules in the interstellar medium. An important set of surface reactions produces icy mantles of many monolayers in cold and dense regions. The monolayers are dominated by water ice, but also contain CO, CO_{2}, and occasionally methanol as well as minor constituents. In this paper, the rate of production of water-ice dominated mantles is calculated for different physical conditions of interstellar clouds and for the first time images of the morphology …
Radiative torques, due to the absorption and scattering of starlight, are thought to play a major role in the alignment of grains with the interstellar magnetic field. The absorption of radiation also gives rise to recoil torques, associated with the photoelectric effect and photodesorption. The recoil torques are much more difficult to model and compute than the direct radiative torque. Here, we consider the relatively simple case of a spheroidal grain. Given our best estimates for the photoelectric yield and other relevant grain physical properties, we find that the recoil torques contribute…
In the previous papers in this series, we found that radiative torques can play a major role in the alignment of grains with the interstellar magnetic field. Since the radiative torques can drive the grains to suprathermal rotational speeds, in previous work we made the simplifying assumption that the grain principal axis of greatest moment of inertia is always parallel to the grain angular momentum. This enabled us to describe many of the features of the grain dynamics. However, this assumption fails when the grains enter periods of thermal rotation, which occur naturally in the radiative tor…
Scattering and absorption of X-rays by interstellar dust is calculated for a model consisting of carbonaceous grains and amorphous silicate grains. The calculations employ realistic dielectric functions with structure near X-ray absorption edges, with resulting features in absorption, scattering, and extinction. Differential scattering cross sections are calculated for energies between 0.3 and 10 keV. The median scattering angle is given as a function of energy, and simple but accurate approximations are found for the X-ray scattering properties of the dust mixture, as well as for the angular …
The carrier of the 2175 Angstrom interstellar extinction feature remains unidentified since its first detection over 40 years ago. In recent years carbon buckyonions have been proposed as a carrier of this feature, based on the close similarity between the electronic transition spectra of buckyonions and the 2175 Angstrom interstellar feature. We examine this hypothesis by modeling the interstellar extinction with buckyonions as a dust component. It is found that dust models containing buckyonions (in addition to amorphous silicates, polycyclic aromatic hydrocarbon molecules, graphite) can clo…
We model the photoelectric emission from and charging of interstellar dust and obtain photoelectric gas heating efficiencies as a function of grain size and the relevant ambient conditions. Using realistic grain size distributions, we evaluate the net gas heating rate for various interstellar environments, and find less heating for dense regions characterized by R_V=5.5 than for diffuse regions with R_V=3.1. We provide fitting functions which reproduce our numerical results for photoelectric heating and recombination cooling for a wide range of interstellar conditions. In a separate paper we w…
Grains exposed to anisotropic radiation fields are subjected to forces due to the asymmetric photon-stimulated ejection of particles. These forces act in addition to the ``radiation pressure'' due to absorption and scattering. Here we model the forces due to photoelectron emission and the photodesorption of adatoms. The ``photoelectric'' force depends on the ambient conditions relevant to grain charging. We find that it is comparable to the radiation pressure when the grain potential is relatively low and the radiation spectrum is relatively hard. The calculation of the ``photodesorption'' for…
Semi-empirical molecular dynamics is used to simulate hydrocarbon grain sputtering and collisions which are extremely difficult to study experimentally. This microscopic and dynamic approach is particularly suited to high velocity impacts, where target destruction occurs far from equilibrium. A wide variety of processes are encountered, depending on grain size and velocity: vaporization, fragmentation, atomic implantation, sticking, elastic recoil, atomic chemisorption, H abstraction and H2 formation, etc. The impact-velocity threshold is about 10 km/s but complete grain destruction requires m…
As pointed out by Lingenfelter and Ramaty (1977), the shapes of some gamma-ray lines produced by cosmic-ray interactions with the interstellar medium potentially contain valuable information on the physical properties of dust grains, including their compositions and size distributions. The most promising of such lines are at 847, 1369, 1779 and 6129 keV, from 56-Fe*, 24-Mg*, 28-Si* and 16-O*, respectively. We performed detailed calculations of their profiles using, in particular, available laboratory measurements combined with optical model calculations to evaluate the energy distributions of …
The results of experiments on the formation of molecular hydrogen on low density and high density amorphous ice surfaces are analyzed using a rate equation model. The activation energy barriers for the relevant diffusion and desorption processes are obtained. The more porous morphology of the low density ice gives rise to a broader spectrum of energy barriers compared to the high density ice. Inserting these parameters into the rate equation model under steady state conditions we evaluate the production rate of molecular hydrogen on ice-coated interstellar dust grains.
We report on laboratory measurements of molecular hydrogen formation and recombination on an olivine slab as a function of surface temperature under conditions relevant to those encountered in the interstellar medium. On the basis of our experimental evidence, we recognize that there are two main regimes of H coverage that are of astrophysical importance; for each of them we provide an expression giving the production rate of molecular hydrogen in interstellar clouds.
The deuterium abundance evaluation in the direction of Capella has for a long time been used as a reference for the local interstellar medium (ISM) within our Galaxy. We show here that broad and weak HI components could be present on the Capella line of sight, leading to a large new additional systematic uncertainty on the N(HI) evaluation. The D/H ratio toward Capella is found to be equal to 1.67 (+/-0.3)x10^-5 with almost identical chi^2 for all the fits (this range includes only the systematic error; the 2 sigma statistical one is almost negligible in comparison). It is concluded that D/H e…
The gas-to-dust mass ratios found for interstellar dust within the Solar System, versus values determined astronomically for the cloud around the Solar System, suggest that large and small interstellar grains have separate histories, and that large interstellar grains preferentially detected by spacecraft are not formed exclusively by mass exchange with nearby interstellar gas. Observations by the Ulysses and Galileo satellites of the mass spectrum and flux rate of interstellar dust within the heliosphere are combined with information about the density, composition, and relative flow speed and…
We study the influence of the non-flat shape of the solar Lyman-alpha line on the distribution of neutral interstellar hydrogen in the inner heliosphere and assess importance of this effect for interpretation of heliospheric in situ measurements. Based on available data, construct a model of evolution of the solar Lyman-alpha line profile with solar activity. Modify an existing test-particle code calculating distribution of neutral interstellar hydrogen in the inner heliosphere to take into account the dependence of radiation pressure on radial velocity. Discrepancies between the classical and…
Observations of the weak polarization of light from nearby stars, reported by Tinbergen (1982), are consistent with polarization by small, radius <0.14 microm, interstellar dust grains entrained in the magnetic wall of the heliosphere. The direction of maximum polarization is offset by ~35 deg from the heliosphere nose, and extends to low ecliptic latitudes. An offset is found between the direction of the best aligned dust grains, and the upwind direction of the undeflected large interstellar grains seen by Ulysses and Galileo. In the aligned-grain region, the strength of polarization anti-cor…
We identify a new mechanism of internal dissipation of rotational kinetic energy in spinning dust grains, arising from the reorientation of nuclear angular momentum, e.g., spins of protons. Grain rotation induces magnetization of the nuclear spin system, with net alignment of nuclear spins parallel to the grain angular velocity. When the grain does not rotate around a principal axis, the nuclear magnetization vector precesses in grain body coordinates, resulting in dissipation of energy. The analogous process involving electron spins was discovered by Purcell and termed ``Barnett relaxation''.…
Networks of reactions on dust grain surfaces play a crucial role in the chemistry of interstellar clouds, leading to the formation of molecular hydrogen in diffuse clouds as well as various organic molecules in dense molecular clouds. Due to the sub-micron size of the grains and the low flux, the population of reactive species per grain may be very small and strongly fluctuating. Under these conditions rate equations fail and the simulation of surface-reaction networks requires stochastic methods such as the master equation. However, the master equation becomes infeasible for complex networks …
Experimental results on the formation of molecular hydrogen on amorphous silicate surfaces are presented for the first time and analyzed using a rate equation model. The energy barriers for the relevant diffusion and desorption processes are obtained. They turn out to be significantly higher than those obtained earlier for polycrystalline silicates, demonstrating the importance of grain morphology. Using these barriers we evaluate the efficiency of molecular hydrogen formation on amorphous silicate grains under interstellar conditions. It is found that unlike polycrystalline silicates, amorpho…