We investigate the general property of the energy fluctuation for the canonical ensemble in Tsallis statistics and the ensemble equivalence. By taking the ideal gas and the non-interacting harmonic oscillators as examples, we show that, when the particle number N is large enough, the relative fluctuation of the energy is proportional to 1/N in the new statistics, instead of square root of 1/N in Boltzmann-Gibbs statistics. Thus the equivalence between the microcanonical and the canonical ensemble still holds in Tsallis statistics.
We show that the latest thermostatistical formalism based on the Havrda & Charvat-Daróczy-Tsallis entropy $S_q [ ρ] = (q-1)^{-1}(1- tr (ρ^q))$ proposed by Tsallis, Mendes and Plastino is {\em equivalent} to the first one proposed by Tsallis in 1988. Here, equivalent means: {\em the ``equilibrium'' state predicted by either formalism using $q$ leads to the same expectation values for all observables as that predicted by the other formalism using $1/q$''}. We also point out once again that the basic property of {\em transitivity of equilibrium} (e.g., the $0^{th}$ Law of Thermodynamics) fails in…
In a recent paper [Phys. Lett. A {\bf335}, 351 (2005)] the authors discussed the equivalence among the various probability distribution functions of a system in equilibrium in the Tsallis entropy framework. In the present letter we extend these results to a system which is out of equilibrium and evolves to a stationary state according to a nonlinear Fokker-Planck equation. By means of time-scale conversion, it is shown that there exists a ``correspondence'' among the self-similar solutions of the nonlinear Fokker-Planck equations associated with the different Tsallis formalisms. The time-scale…
We study the energy and entropies for $N$ independent harmonic oscillators in the microcanonical and the canonical ensembles in the Tsallis classical and the Tsallis quantum statistics of entropic parameter $q$, where $N$ is the number of the oscillators and the value of $q$ is larger than one. The energy and entropies are represented with the physical temperature, and the well-known expressions are obtained for the energy and Rényi entropy. The difference between the microcanonical and the canonical ensembles is the existence of the condition for $N$ and $q$ in the canonical ensemble: $N(q-1)…
A comprehensive investigation is carried out on the class of energy based ensembles. The eight ensembles are divided into two main classes. In the isothermal class of ensembles the individual members are at the same temperature. A unified framework is evolved to describe the four isothermal ensembles. Such a description is provided both in the second and the third constraint formalisms. The isothermal- isobaric, grandcanonical and the generalized ensembles are illustrated through a study of the classical nonrelativistic and the extreme relativistic ideal gas models. In the adiabatic class of e…
In spite of its undeniable success, there are still open questions regarding Tsallis non-extensive statistical formalism, whose founding stone was laid in 1988 in JSTAT. Some of them are concerned with the so-called normalization problem of just how to evaluate expectation values. The Jaynes MaxEnt approach for deriving statistical mechanics is based on the adoption of (1) a specific entropic functional form S and (2) physically appropriate constraints. The literature on non-extensive thermostatistics has considered, in its historical evolution, four possible choices for the evaluation of expe…
We show that Tsallis ensemble of power-law distributions provides a mechanical model of nonextensive equilibrium thermodynamics for small interacting Hamiltonian systems, i.e., using Boltzmann's original nomenclature, we prove that it is an exact orthode. This means that the heat differential admits the inverse average kinetic energy as an integrating factor. One immediate consequence is that the logarithm of the normalization function can be identified with the entropy, instead of the q-deformed logarithm. It has been noted that such entropy coincides with Renyi entropy rather than Tsallis en…
Description using equilibrium temperature in the canonical ensemble within the framework of the Tsallis statistics employing the conventional expectation value
In the present paper the conditions for the validity of the Tsallis' Statistics are analyzed. The same has been done following the analogy with the traditional case: starting from the microcanonical description of the systems and taking into account their self-similarity scaling properties in the thermodynamic limit, it is analyzed the necessary conditions for the equivalence of microcanonical ensemble with the Tsallis' generalization of the canonical ensemble. It is shown that the Tsallis' Statistics is appropriate for the macroscopic description of systems with potential scaling laws of the …
The equivalence between Tsallis Thermodynamics and Hill Nanothermodynamics is established. The correct thermodynamic forces in Tsallis thermodynamics are pointed out. Through this connection we also find a general expression for the entropic index $q$ which we illustrate with two physical examples, allowing in both cases to relate $q$ to the underlying dynamics of the Hamiltonian systems.
The energy distribution and the energy fluctuation in the Tsallis canonical ensemble are studied with the OLM formalism but following a new way. The resulting formula for the energy fluctuation is not the same as that in previous work [Liu L.Y. and Du J.L., Physica A 387(2008)5417]. In discussing the application of an ideal gas, we find that the energy fluctuation can not be negligible in the thermodynamic limit, showing the ensemble nonequivalence for this case in Tsallis statistics. We investigate the energy fluctuation with a Tsallis generalized canonical distribution studied by Plastino an…
For non-equilibrium systems in a steady state we present two necessary and sufficient conditions for the emergence of $q$-canonical ensembles, also known as Tsallis statistics. These conditions are invariance requirements over the definition of subsystem and environment, and over the joint rescaling of temperature and energy. Our approach is independent of, but complementary to, the notions of Tsallis non-extensive statistics and Superstatistics.
In the present paper, the Tsallis statistics in the grand canonical ensemble was reconsidered in a general form. The thermodynamic properties of the nonrelativistic ideal gas of hadrons in the grand canonical ensemble was studied numerically and analytically in a finite volume and the thermodynamic limit. It was proved that the Tsallis statistics in the grand canonical ensemble satisfies the requirements of the equilibrium thermodynamics in the thermodynamic limit if the thermodynamic potential is a homogeneous function of the first order with respect to the extensive variables of state of the…
We show that the function beta(E) derived from the density of states of a constant heat capacity reservoir coupled to some system of interest is not identical to the physically measurable (transitive) temperature. There are, however, connections between the two quantities as well as with the Tsallis parameter q. We exemplify these connections using the one-dimensional Ising model in the "dynamical ensemble".
Tsallis has proposed a generalisation of the standard entropy, which has since been applied to a variety of physical systems. In the canonical ensemble approach that is mostly used, average energy is given by an unnromalised, or normalised, $q$-expectation value. A Lagrange multiplier $β$ enforces the energy constraint whose physical interpretation, however, is lacking. Here, we use a microcanonical ensemble approach and find that consistency requires that only normalised $q$-expectation values are to be used. We then present a physical interpretation of $β$, relating it to a physical temperat…
The microscopic foundation of the generalized equilibrium statistical mechanics based on the Tsallis entropy is given by using the Gibbs idea of statistical ensembles of the classical and quantum mechanics. The equilibrium distribution functions are derived by the thermodynamic method based upon the use of the fundamental equation of thermodynamics and the statistical definition of the functions of the state of the system. It is shown that if the entropic index $ξ=1/(q-1)$ in the microcanonical ensemble is an extensive variable of the state of the system, then in the thermodynamic limit $\tild…
We investigate a two-parameter entropy introduced by Schwämmle and Tsallis and obtain its probability distribution in the canonical ensemble. The probability distribution is given in terms of the Lambert W-function which has been used in many branches of physics, especially in fractal structures. Also, extensivity of $S_{q,q'}$ is discussed and a relationship is found to exist between the probabilities of a composite system and its subsystems so that the two-parameter entropy, $S_{q,q'}$, is extensive.
We compute the internal energy of different Ising type models, both long-range and short-range, under Tsallis statistics using the microcanonical and the canonical ensembles and we discuss under which conditions both ensembles give equivalent results.
We show that the configurational probability distribution of a classical gas always belongs to the q-exponential family. Hence, the configurational subsystem is non-extensive in the sense of Tsallis. One of the consequences of this observation is that the thermodynamics of the configurational subsystem is uniquely determined up to a scaling function. As an example we consider a system of non-interacting harmonic oscillators. In this example, the scaling function can be determined from the requirement that in the limit of large systems the microcanonical temperature of the configurational subsy…
The original canonical ensemble formalism for the nonextensive entropy thermostatistics is reconsidered. It is shown that the unambiguous connection of the statistical mechanics with the equilibrium thermodynamics is provided if the entropic parameter $1/(q-1)$ is an extensive variable of the state. Based on a particular example of the perfect gas, it is proved that the Tsallis thermostatistics meets all the requirements of equilibrium thermodynamics in the thermodynamic limit. In particular, the entropy of the system is extensive and the temperature is intensive. However, for finite systems b…
Realistic scenario can be represented by general canonical ensemble way better than the ideal one, with proper parameter sets involved. We study the Bose-Einstein condensation phenomena of liquid helium within the framework of Tsallis statistics. With a comparatively high value of the deformation parameter $q(\sim 1.4)$, the theoretically calculated value of the critical temperature($T_c$) of the phase transition of liquid helium is found to agree with the experimentally determined value ($T_c = 2.17~\rm{K}$), although they differs from each other for $q=1$ (undeformed scenario). This throws a…
In this paper, we show that 1) additive energy is not appropriate for discussing the validity of Tsallis or Rényi statistics for nonextensive systems at meta-equilibrium; 2) $N$-body systems with nonadditive energy or entropy should be described by generalized statistics whose nature is prescribed by the existence of thermodynamic stationarity. 3) the equivalence of Tsallis and Rényi entropies is in general not true.
We investigate the limiting cases of Tsallis statistics. The viewpoint adopted is not the standard information-theoretic one, where one derives the distribution from a given measure of information. Instead the mechanical approach recently proposed in [M. Campisi, G.B. Bagci, Phys. Lett. A (2006), doi:10.1016/j.physleta.2006.09.081], is adopted, where the distribution is given and one looks for the associated physical entropy. We show that, not only the canonical ensemble is recovered in the limit of $q$ tending to one, as one expects, but also the microcanonical ensemble is recovered in the li…
The non-extensive canonical ensemble theory is reconsidered with the method of Lagrange multipliers by maximizing Tsallis entropy, with the constraint that the normalized term of Tsallis' $q-$average of physical quantities, the sum $\sum p_j^q$, is independent of the probability $p_i$ for Tsallis parameter $q$. The self-referential problem in the deduced probability and thermal quantities in non-extensive statistics is thus avoided, and thermodynamical relationships are obtained in a consistent and natural way. We also extend the study to the non-extensive grand canonical ensemble theory and o…
The critique against using Boltzmann's microcanonical entropy, an "ensemble measure", as foundation of statistics is rebuffed. The confusion of the microcanonical distribution with the exponential Boltzmann-Gibbs (``BG'') distribution is pointed out. Boltzmann's principle is clearly superior over any Tsallis q-statistics in describing the equilibrium of small systems like nuclei and even self-gravitating systems as paradigm of non-extensive Hamiltonian systems.
We discuss the meaning of Tsallis functional in astrophysics. The energy functional of a polytropic star is similar to Tsallis free energy and the H-function associated with a stellar polytrope is similar to Tsallis entropy. More generally, the energy functional of a barotropic star is similar to a generalized free energy and the H-function associated with a spherical stellar system is similar to a generalized entropy. Their optimization under appropriate constraints determines a condition of nonlinear dynamical stability, not a condition of thermodynamical stability. The criterion of dynamica…
Dynamical ensembles have been introduced to study constrained stochastic processes. In the microcanonical ensemble, the value of a dynamical observable is constrained to a given value. In the canonical ensemble a bias is introduced in the process to move the mean value of this observable. The equivalence between the two ensembles means that calculations in one or the other ensemble lead to the same result. In this paper, we study the physical conditions associated with ensemble equivalence and the consequences of non-equivalence. For continuous time Markov jump processes, we show that ergodici…
We show that the contact process in an ensemble with conserved total particle number, as simulated recently by Tome and de Oliveira [Phys. Rev. Lett. 86 (2001) 5463], is equivalent to the ordinary contact process, in agreement with what the authors assumed and believed. Similar conserved ensembles and equivalence proofs are easily constructed for other models.
Shortened abstract: Given a constrained minimization problem, under what conditions does there exist a related, unconstrained problem having the same minimum points? This basic question in global optimization motivates this paper, which answers it from the viewpoint of statistical mechanics. In this context, it reduces to the fundamental question of the equivalence and nonequivalence of ensembles, which is analyzed using the theory of large deviations and the theory of convex functions.
A unified framework to describe the adiabatic class of ensembles in the generalized statistical mechanics based on Schwammle-Tsallis two parameter (q, q') entropy is proposed. The generalized form of the equipartition theorem, virial theorem and the adiabatic theorem are derived. Each member of the class of ensembles is illustrated using the classical nonrelativistic ideal gas and we observe that the heat functions could be written in terms of the Lambert's W-function in the large N limit. In the microcanonical ensemble we study the effect of gravitational field on classical nonrelativistic id…
The equivalence of thermodynamic results in the canonical and the microcanonical ensembles has been questioned in some calculations for spin models with long-range interactions. We show that these claims of inequivalence are related to an inadequate definition of the independent (density) variables in the microcanonical ensemble. We illustrate this point with the example of a simple spin-1 ideal paramagnet, and then revisit the original calculations of Barré, Mukamel, and Ruffo, for a mean-field spin-1 Blume-Capel model. If the microcanonical ensemble is defined in terms of adequate density va…
The phenomenon of partial equivalence of statistical ensembles is illustrated by discussing two examples, the mean-field XY and the mean-field spherical model. The configurational parts of these systems exhibit partial equivalence of the microcanonical and the canonical ensemble. Furthermore, the configurational microcanonical entropy is a smooth function, whereas a nonanalytic point of the configurational free energy indicates the presence of a phase transition in the canonical ensemble. In the presence of a standard kinetic energy contribution, partial equivalence is removed and a nonanalyti…
Generalizations of the microcanonical and canonical ensembles for paths of Markov processes have been proposed recently to describe the statistical properties of nonequilibrium systems driven in steady states. Here we propose a theory of these ensembles that unifies and generalizes earlier results, and show how it is fundamentally related to the large deviation properties of nonequilibrium systems. Using this theory, we provide conditions for the equivalence of nonequilibrium ensembles, generalizing those found for equilibrium systems, construct driven physical processes that generate these en…
Using the theory of large deviations, we analyze the phase transition structure of the Curie-Weiss-Potts spin model, which is a mean-field approximation to the Potts model. This analysis is carried out both for the canonical ensemble and the microcanonical ensemble. Besides giving explicit formulas for the microcanonical entropy and for the equilibrium macrostates with respect to the two ensembles, we analyze ensemble equivalence and nonequivalence at the level of equilibrium macrostates, relating these to concavity and support properties of the microcanonical entropy. The Curie-Weiss-Potts mo…
The framework of non-extensive statistical mechanics, proposed by Tsallis, has been used to describe a variety of systems. The non-extensive statistical mechanics is usually introduced in a formal way, using the maximization of entropy. In this article we investigate the canonical ensemble in the non-extensive statistical mechanics using a more traditional way, by considering a small system interacting with a large reservoir via short-range forces. The reservoir is characterized by generalized entropy instead of the Boltzmann-Gibbs entropy. Assuming equal probabilities for all available micros…
Statistics of distinguishable particles has become relevant in systems of colloidal particles and in the context of applications of statistical mechanics to complex networks. When studying these type of systems with the standard textbook formalism, non-physical results such as non-extensive entropies are obtained. In this paper, we will show that the commonly used expression for the partition function of a system of distinguishable particles leads to huge fluctuations of the number of particles in the grand canonical ensemble and, consequently, to non-equivalence of statistical ensembles. We w…
In this article we show that the inhomogeneous density obtained from a density-functional theory of classical fluids in the canonical ensemble (CE), recently presented by White et al [Phys. Rev. Lett. 84 (2000) 1220], is equivalent to first order to the result of the series expansion of the CE inhomogeneous density introduced by Gonzalez et al [Phys. Rev. Lett. 79 (1997) 2466].
The general formalisms of the $q$-dual statistics, the Boltzmann-Gibbs statistics, and three versions of the Tsallis statistics known as Tsallis-1, Tsallis-2, and Tsallis-3 statistics have been considered in the canonical ensemble. We have rigorously proved that the probability distribution of the Tsallis-1 statistics is invariant under the uniform energy spectrum translation at a fixed temperature. This invariance demonstrates that the formalism of the Tsallis-1 statistics is consistent with the fundamentals of the equilibrium statistical mechanics. The same results we have obtained for the p…
We discuss the possibility of using generalized canonical distributions, i.e. using other factors than $\exp(-βE)$, in order to compute the equilibrium properties of physical systems. It will be show that some other choices can, in certain cases, lead to a simpler calculation of those properties. The corresponding equivalence between the canonical and the generalized canonical distributions is derived using well-known principles of Statistical Mechanics and we exemplify the method by deriving in a simple way the equilibrium properties of the long--range Ising model.
In this paper we point out that the generalized statistics of Tsallis-Havrda-Charvát can be conveniently used as a conceptual framework for statistical treatment of random chains. In particular, we use the path-integral approach to show that the ensuing partition function can be identified with the partition function of a fluctuating oriented random loop of arbitrary length and shape in a background scalar potential. To put some meat on the bare bones, we illustrate this with two statistical systems; Schultz-Zimm polymer and relativistic particle. Further salient issues such as the $PSL(2;R)$ …
We study the counterion condensation on a two dimensional charged disc in the limit of infinite dilution, and compare the energy-temperature relation obtained from the canonical free energy and microcanonical entropy. The microcanonical entropy is piecewise linear in energy, and is shown to be concave for all energies. As a result, even though the interactions are long-ranged, the energy-temperature relation and hence the counterion condensation transition points are identical in both the ensembles.
We study the problem of ensemble equivalence in spin systems with short-range interactions under the existence of a first-order phase transition. The spherical model with nonlinear nearest-neighbour interactions is solved exactly both for canonical and microcanonical ensembles. The result reveals apparent ensemble inequivalence at the first-order transition point in the sense that the microcanonical entropy is non-concave as a function of the energy and consequently the specific heat is negative. In order to resolve the paradox, we show that an unconventional saddle point should be chosen in t…
Shortened abstract: Microcanonical equilibrium macrostates are characterized as the solutions of a constrained minimization problem, while canonical equilibrium macrostates are characterized as the solutions of a related, unconstrained minimization problem. In Ellis, Haven, and Turkington (J. Stat. Phys. 101, 999, 2000) the problem of ensemble equivalence was completely solved at two separate, but related levels: the level of equilibrium macrostates, which focuses on relationships between the corresponding sets of equilibrium macrostates, and the thermodynamic level, which focuses on when the …
Borrowing ideas from open quantum systems, we describe a formalism to encode ensembles of trajectories of classical stochastic dynamics in terms of continuous matrix product states (cMPSs). We show how to define in this approach "biased" or "conditioned" ensembles where the probability of trajectories is biased from that of the natural dynamics by some condition on trajectory observables. In particular, we show that the generalised Doob transform which maps a conditioned process to an equivalent "auxiliary" or "driven" process (one where the same conditioned set of trajectories is generated by…
In systems with long-range interactions, since energy is a non-additive quantity, ensemble inequivalence can arise: it is possible that different statistical ensembles lead to different equilibrium descriptions, even in the thermodynamic limit. The microcanonical ensemble should be considered the physically correct equilibrium distribution as long as the system is isolated. The canonical ensemble, on the other hand, can always be defined mathematically, but it is quite natural to wonder to which physical situations it does correspond. We show numerically and, in some cases, analytically, that …
I comment on the relation between two sampling methods for absorbing state models. It is shown that a certain ensemble without external field conditional to activity coincides with the unconditional ensemble for sufficiently small external field. The actual physical processes involved are identical and the derivation of the identity of the scaling behaviour relies on a single (established) scaling law. While the conditional ensemble by construction does not contain information about the system with large external field, it contains all information about the limit of vanishing external field an…
We present general and rigorous results showing that the microcanonical and canonical ensembles are equivalent at all three levels of description considered in statistical mechanics - namely, thermodynamics, equilibrium macrostates, and microstate measures - whenever the microcanonical entropy is concave as a function of the energy density in the thermodynamic limit. This is proved for any classical many-particle systems for which thermodynamic functions and equilibrium macrostates exist and are defined via large deviation principles, generalizing many previous results obtained for specific cl…
The relation between two versions of so called non-equilibrium statistical operator method (NESOM), NESOM-1 due to Zubarev (1961) and NESOM-2 due to Zubarev and Kalashnikov (1970), is considered. It is proved that, once the balance equations of NESOM-2 are satisfied, those of NESOM-1 will be satisfied with the same set of the macro-parameters. The proof uses the convexity-type inequalities, and does not involve any assumptions additional to the rationales behind NESOM. However, converse statement cannot be proved within this technique. An extension of the proof to overall equivalence of the tw…
In a pioneer work, John Nagle has shown that an Ising chain with competing short and long-range interactions displays second and first-order phase transitions separated by a tricritical point. More recently, it has been claimed that Nagle's model provides an example of the inequivalence between canonical and microcanonical calculations. We then revisit Nagle's original solution, as well as the usual formulation of the problem in a canonical ensemble, which lead to the same results. Also, in contrast to recent claims, we show that an alternative formulation in the microcanonical ensemble, with …
The so-called $χ^{2}$-superstatistics of Beck and Cohen (BC) is employed to investigate the infinite-range Blume-Capel model, a well-known representative system displaying inequivalence of canonical and microcanonical phase diagrams. While not being restricted to any of those particular thermodynamic limits, our analytical result can smoothly recover both canonical and microcanonical ensemble solutions as its nonextensive parameter $q$ is properly tuned. Additionally, we compare our findings to ones previously obtained from a generalized canonical framework named Extended Gaussian ensemble (EG…
This paper is a companion article to our previous paper (J. Stat. Phys. 119, 1283 (2005), cond-mat/0408681), which introduced a generalized canonical ensemble obtained by multiplying the usual Boltzmann weight factor $e^{-βH}$ of the canonical ensemble with an exponential factor involving a continuous function $g$ of the Hamiltonian $H$. We provide here a simplified introduction to our previous work, focusing now on a number of physical rather than mathematical aspects of the generalized canonical ensemble. The main result discussed is that, for suitable choices of $g$, the generalized canonic…
The statistical mechanics of a cloud of particles interacting via their gravitational potentials is an old problem which encounters some issues when the traditional Boltzmann-Gibbs statistics is applied. In this article, we consider the generalized statistics of Tsallis and analyze the statistical and thermodynamical implications for a self-gravitating gas, obtaining analytical and convergent expressions for the equation of state and specific heat in the canonical as well as microcanonical ensembles. Although our results are comparable in both ensembles, it turns out that only in the canonical…
Previous results on Renyi and Wang's formalism of the Tsallis thermostatics are founded by using an extensive variable z connected to the entropic parameter q. It is shown that in the thermodynamical limit both the Tsallis and Renyi entropies are extensive functions of state and the temperature of the system is intensive. In this limit Wang's incomplete nonextensive statistics resembles the Tsallis one, but the Renyi thermostatics is reduced to the usual Boltzmann-Gibbs one. The principle of additivity and the zeroth law of thermodynamics in the canonical ensemble are demonstrated on the parti…
Superstatistics is a generalization of equilibrium statistical mechanics that describes systems in nonequilibrium steady states. Among the possible superstatistical distributions, the $q$-canonical ensemble (also known as Tsallis' statistics, and in plasma physics as Kappa distributions) is probably the most widely used, however the current explanations of its origin are not completely consistent. In this work it is shown that, under a Bayesian interpretation of superstatistics, the origin of the $q$-canonical ensemble can be explained as the superstatistical distribution with maximum Shannon-…
We consider the relation between the Boltzmann temperature and the Lagrange multipliers associated with energy average in the nonextensive thermostatistics. In Tsallis' canonical ensemble, the Boltzmann temperature depends on energy through the probability distribution unless $q=1$. It is shown that the so-called 'physical temperature' introduced in [Phys. Lett. A \textbf{281} (2001) 126] is nothing but the ensemble average of the Boltzmann temperature.
Due to the equivalence of the statistical ensembles thermostatic properties of physical systems with short-range interactions can be calculated in different ensembles leading to the same physics. In particular, the ensemble equivalence holds for systems that undergo a continuous phase transition in the infinite volume limit so that the properties of the transition can also be investigated in the microcanonical approach. Considering as example the spherical model the ensemble equivalence is explicitly demonstrated by calculating the critical properties in the microcanonical ensemble and compari…
It is well known that long-range interactions pose serious problems for the formulation of statistical mechanics. We show in this paper that ensemble equivalence is violated in a simple mean-field model of N fully coupled classical rotators with repulsive interaction (antiferromagnetic XY model). While in the canonical ensemble the rotators are randomly dispersed over all angles, in the microcanonical ensemble a bi-cluster of rotators separated by angle $π$, forms in the low energy limit. We attribute this behavior to the extreme degeneracy of the ground state: only one harmonic mode is presen…
