arXivDaily arXiv每日学术速递 周一至周五更新
arXiv周末暂无论文更新,休息一下吧,周末愉快~~
arXiv 0803.1957cond-mat.str-el
收藏

RCoO_3(R = La,Pr,Nd,Eu)中Co自旋态跃迁引起的反常膨胀和声子阻尼

Anomalous expansion and phonon damping due to the Co spin-state transition in RCoO_3 with R = La, Pr, Nd and Eu

K. Berggold, M. Kriener, P. Becker, M. Benomar, M. Reuther, C. Zobel, T. Lorenz

摘要:

本文研究了钙钛矿系列RCoO_3(R = La,Nd,Pr,Eu)的热膨胀和热导率。LaCoO_3中的自旋态转变受到R离子交换的强烈影响,这是由于它们的离子半径不同,即化学压不同。这可以通过测量热膨胀来详细监测,热膨胀是用于检测自旋状态转变的高灵敏度探针。处于高自旋态的Co离子作为声子的附加散射中心,从而抑制声子热导率。基于自旋态跃迁和热输运之间的相互作用的分析,我们提出了整个系列的热导率的定量模型。在PrCoO_3中,在低温下,一个附加的散射效应是活跃的。这种效应源于4f多重态的晶体场分裂,它允许各种4f能级之间的声子共振散射。

英文摘要:

We present a combined study of the thermal expansion and the thermal conductivity of the perovskite series RCoO_3 with R = La, Nd, Pr and Eu. The well-known spin-state transition in LaCoO_3 is strongly affected by the exchange of the R ions due to their different ionic radii, i.e. chemical pressure. This can be monitored in detail by measurements of the thermal expansion, which is a highly sensitive probe for detecting spin-state transitions. The Co ions in the higher spin state act as additional scattering centers for phonons, therefore suppressing the phonon thermal conductivity. Based on the analysis of the interplay between spin-state transition and heat transport, we present a quantitative model of the thermal conductivity for the entire series. In PrCoO_3, an additional scattering effect is active at low temperatures. This effect arises from the crystal field splitting of the 4f multiplet, which allows for resonant scattering of phonons between the various 4f levels.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

↑