没有光谱学，催化研究在错误的方向上进行了100多年
Without Spectroscopy at the Beginning, Catalysis Research Proceeded in the Wrong Direction for More Than 100 Years
摘要：
通过对催化剂物理吸附区的红外光谱研究表明，催化中间体以二维气体形式存在于表面。原子能级表中的数据表明，在表中列出的数千个正离子中，只有大约一百个具有低激发态，这些低激发态产生带有分数电荷的表面电场。用于反应的特定催化剂具有带分数电荷的电场，当该电场被施加到两种反应物时，改变了每个反应物上反应位点处的场的频率，使得它们谐波相等，即它们的比率是2的幂。当两种反应物在催化剂的电场中相遇时，发生共振。正是在共振过程中，电子被共享、配对和交换，键被打破和形成。这种对催化作用的分析解释了一个最不寻常的观察，即催化剂在使用时不会被消耗，因为催化剂是电场。这些发现被应用于解释诸如一氧化碳的氧化和氯化以及汽车尾气中一氧化氮的破坏等多种反应。利用电场产生反应不仅在化学上有应用，而且在生物学和力学上也有应用。
英文摘要：
A study by infrared spectroscopy of the physisorbed region of catalysis demonstrated that the intermediates of catalysis exist on the surface as a two dimensional gas. Data in the Atomic Energy Level tables show that of the thousands of positive ions tabulated only approximately one hundred have the low-lying excited states that produce surface electric fields with a fractional charge. The specific catalyst for a reaction has the electric field with the fractional charge which when imparted to the two reactants changes the frequency of the fields at the sites of reaction on each so that they are harmonically equal, that is their ratio is a power of two. When the two reactants meet in the electric field of the catalyst resonance occurs. It is during resonance that electrons are shared, paired and exchanged and bonds are broken and made. This analysis of catalysis explains the most extraordinary observation that a catalyst is Not consumed when used because the catalyst is the electric fields. These discoveries are applied to explain such diverse reactions as the oxidation and chlorination of carbon monoxide and the destruction of nitric oxide in automobile exhaust. The use of electric fields to produce reactions may have application not only in chemistry but in biology and mechanics as well.
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