楔形中的有向路径
Directed Paths in a Wedge
摘要:
有向路径在科学文献中被广泛用作线性聚合物的模型。这种路径模型特别是线性聚合物的构象熵及其对自由能的影响。这些定向模型是自避免行走的简化版本,但它们仍然可以洞察聚合物的相行为,并且也可以作为研究线性聚合物行为中构象自由度的影响的工具。在本文中,我们研究了有向路径模型的线性聚合物在一个封闭的几何形状(楔)。我们关注的主要焦点是$c_n$,长度为$n$步的有向晶格路径的数量,这些路径在东北和东南方向上采取步骤,并且被限制在楔形$Y=\pm X/p$中,其中$p$是整数。在本文中,我们研究的情况下,$p=2$详细,我们确定的生成函数使用迭代核方法。我们还研究了$c_n$的对称性。特别是,我们表明,$$ c_n = [0.67874...]\times 2^{n-1}(1+(-1)^n) + O((4/3^{3/4})^{n+o(n)}) + o((4/3^{3/4})^n) $$在这里,我们可以确定常数$0.67874...$,以任意精度,很少的努力。
英文摘要:
Directed paths have been used extensively in the scientific literature as a model of a linear polymer. Such paths models in particular the conformational entropy of a linear polymer and the effects it has on the free energy. These directed models are simplified versions of the self-avoiding walk, but they do nevertheless give insight into the phase behaviour of a polymer, and also serve as a tool to study the effects of conformational degrees of freedom in the behaviour of a linear polymer. In this paper we examine a directed path model of a linear polymer in a confining geometry (a wedge). The main focus of our attention is $c_n$, the number of directed lattice paths of length $n$ steps which takes steps in the North-East and South-East directions and which is confined to the wedge $Y=\pm X/p$, where $p$ is an integer. In this paper we examine the case $p=2$ in detail, and we determine the generating function using the iterated kernel method. We also examine the asymtotics of $c_n$. In particular, we show that $$ c_n = [0.67874...]\times 2^{n-1}(1+(-1)^n) + O((4/3^{3/4})^{n+o(n)}) + o((4/3^{3/4})^n) $$ where we can determine the constant $0.67874...$ to arbitrary accuracy with little effort.
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