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arXiv 0704.2170cond-mat.str-el
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CeRuPO:铁磁近藤晶格的一个罕见例子

CeRuPO: A rare example of a Ferromagnetic Kondo lattice

C. Krellner, N. S. Kini, E. M. Bruning, K. Koch, H. Rosner, M. Nicklas, M. Baenitz, C. Geibel

摘要:

通过磁化率chi(T)、比热C(T)、电阻率rho(T)和热电势S(T)的测量,确定了CeRuPO和CeOsPO的基态物理性质。chi(T)揭示了两种化合物中的三价4f1铈态。对于CeRuPO,rho(T)在50K以下的显著降低指示相干近藤散射的开始,这通过增强的S(T)来证实。在TC= 15 K时,chi(T)和C(T)随温度和磁场的变化表明了铁磁(FM)有序.因此,CeRuPO似乎是FM近藤晶格的罕见例子之一。相反,CeOsPO显示反铁磁秩序在TN=4.4K,尽管只有微小的变化,晶格参数和电子配置。额外的31P NMR结果支持这些情况。LSDA+U计算证明了准二维电子能带结构,反映了CeO和RuP层内的强共价键和层间的弱离子键。

英文摘要:

We have determined the physical ground state properties of the compounds CeRuPO and CeOsPO by means of magnetic susceptibility chi(T), specific heat C(T), electrical resistivity rho(T), and thermopower S(T) measurements. chi(T) reveals a trivalent 4f1 cerium state in both compounds. For CeRuPO a pronounced decrease of rho(T) below 50K indicates the onset of coherent Kondo scattering which is confirmed by enhanced S(T). The temperature and magnetic field dependence of chi(T) and C(T) evidence ferromagnetic (FM) order at TC=15K. Thus, CeRuPO seems to be one of the rare example of a FM Kondo lattice. In contrast, CeOsPO shows antiferromagnetic order at TN=4.4K despite only minor changes in lattice parameters and electronic configuration. Additional 31P NMR results support these scenarios. LSDA+U calculations evidence a quasi two dimensional electronic band structure, reflecting a strong covalent bonding within the CeO and RuP layers and a weak ionic like bonding between the layers.

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